Search results for "pluronics"

showing 3 items of 3 documents

Dispersions of nanosilica in biocompatible copolymers

2010

Dispersions of nanosilica in matrices of biocompatible copolymers were prepared by melt blending. Copolymers with variable molecular size at fixed hydrophilic/hydrophobic ratio and nanosilicas with different interfacial areas were studied. For comparison, a nanoclay was also investigated. The interfacial area played a relevant role in conferring peculiar properties on the nanohybrids. Amazingly, the macromolecule adsorbed on the nanosilica surface maintains some crystallinity which was quantitatively evaluated. In contrast, all the macromolecule anchored to the nanoclay surface is amorphous. The change of the crystalline state was reflected in the dielectric and the electrical conductivity …

Materials scienceNanocompositePolymers and PlasticsPoloxamerCondensed Matter PhysicsMicrostructureAmorphous solidCrystallinityPluronics Nanosilica Laponite RD Crystallinity Morphology Thermal stabilityMechanics of MaterialsMaterials ChemistryCopolymerThermal stabilityComposite materialMacromoleculeSettore CHIM/02 - Chimica Fisica
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Poloxamer/sodium cholate co-formulation for micellar encapsulation of Doxorubicin with high efficiency for intracellular delivery: an in-vitro bioava…

2020

Abstract Hypothesis Doxorubicin hydrochloride (DX) is widely used as a chemotherapeutic agent, though its severe side-effects limit its clinical use. A way to overcome these limitations is to increase DX latency through encapsulation in suitable carriers. However, DX has a high solubility in water, hindering encapsulation. The formulation of DX with sodium cholate (NaC) will reduce aqueous solubility through charge neutralization and hydrophobic interactions thus facilitating DX encapsulation into poloxamer (F127) micelles, increasing drug latency. Experiments DX/NaC/PEO-PPO-PEO triblock copolymer (F127) formulations with high DX content (DX-PMs) have been prepared and characterized by scat…

Biological AvailabilityPoloxamerbile salts; confocal microscopy; Doxorubicin hydrochloride; drug-delivery; PEO-PPO-PEO block copolymers; pluronics; tumour cell lines02 engineering and technologyconfocal microscopypluronics010402 general chemistry01 natural sciencesMicellePolyethylene GlycolsBiomaterialsHydrophobic effectColloid and Surface ChemistryPEO-PPO-PEO block copolymersbile saltsSolubilitySodium CholateMicellesChemistryDoxorubicin hydrochloridePoloxamerSodium Cholate021001 nanoscience & nanotechnologydrug-delivery0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDoxorubicinDrug deliveryBiophysicsDoxorubicin Hydrochloridetumour cell lines0210 nano-technologyIntracellular
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A fluorescence study of the loading and time stability of doxorubicin in sodium cholate/PEO-PPO-PEO triblock copolymer mixed micelles

2019

Abstract Hypothesis Doxorubicin hydrochloride (DX) is one of the most powerful anticancer agents though its clinical use is impaired by severe undesired side effects. DX encapsulation in nanocarrier systems has been introduced as a mean to reduce its toxicity. Micelles of the nonionic triblock copolymers of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) (PEO-PPO-PEO), are very promising carrier systems. The positive charge of DX confines the drug to the hydrophilic corona region of the micelles. The use of mixed micelles of PEO-PPO-PEO copolymers and a negatively charged bile salt should favour the solubilization of DX in the apolar core region of the micelles. Experiments We st…

small angle X-raymacromolecular substances02 engineering and technology010402 general chemistry01 natural sciencesMicelledoxorubicinFluorescence spectroscopyfluorescence; doxorubicin; pluronics bile salts; dynamic light scattering; small angle X-ray; scattering drug-deliveryPolyethylene GlycolsBiomaterialsColloid and Surface ChemistryDynamic light scatteringX-Ray DiffractionScattering Small AngleCopolymerMicellesDrug CarriersAqueous solutionAntibiotics AntineoplasticSmall-angle X-ray scatteringChemistrytechnology industry and agricultureWaterdynamic light scatteringPoloxamer021001 nanoscience & nanotechnologySodium Cholate0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialspluronics bile saltsSpectrometry FluorescenceChemical engineeringSolubilityPropylene Glycolsscattering drug-deliveryfluorescenceNanocarriers0210 nano-technology
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