Search results for "pluto"
showing 10 items of 90 documents
Geochemistry, zircon ages and whole-rock Nd isotopic systematics for Palaeoproterozoic A-type granitoids in the northern part of the Delhi belt, Raja…
2006
Determination of zircon ages as well as geochemical and Sm–Nd isotope systematics of granitoids in the Khetri Copper Belt of the Aravalli mountains, NW India, constrain the late Palaeoproterozoic crustal evolution of the Aravalli craton. The plutons are typical A-type within-plate granites, derived from melts generated in an extensional tectonic environment. They display REE and multi-element patterns characterized by steep LREE-enriched and almost flat HREE profiles and distinct negative anomalies for Sr, P and Ti. Initial εNd values range from −1.3 to −6.2 and correspond to crustal sources with mean crustal residence ages of 2.5 to 2.1 Ga. A lower mafic crustal anatectic origin is envisag…
Zircon ages of late Palaeoproterozoic (ca. 1.72–1.70Ga) extension-related granitoids in NE Rajasthan, India: Regional and tectonic significance
2011
Abstract The Khetri region forms a late Palaeoproterozoic igneous–metamorphic complex in NE Rajasthan, India. Seven granitoid plutons of the Khetri complex have been studied for zircon U–Pb and Pb–Pb dating along with whole-rock and Nd–Sr isotope geochemistry to provide new constraints on the Palaeoproterozoic magmatic activity in the Aravalli orogen of northwestern India. Most intrusives show evidence of moderate to extreme albitisation forming microcline–albite granite and albite granite, respectively. The rocks are metaluminous to weakly peraluminous, largely ferroan and intraplate A-type granites. The U–Pb zircon ages for four plutons cover a time span of 1732–1682 Ma, whereas Pb–Pb zir…
Flame foliation: Evidence for a schistosity formed normal to the extension direction
2007
Abstract Foliations are normally thought to develop approximately parallel to the XY-plane of the finite strain ellipsoid, i.e., perpendicular to the main shortening direction. We present a new type of schistosity named “flame foliation” that forms orthogonal to the main extension direction, approximately parallel to the YZ-plane of finite strain. Flame foliation consists of anastomosing biotite-rich selvedges overprinting S1 in pelitic layers of metaturbitites in NW Namibia. The biotite crystals in the selvedges are peculiar because they are oriented oblique or orthogonal to the flame foliation itself and parallel to the previous S1 cleavage, a feature no other foliation shows. In some cas…
Separation of plutonium and neptunium species by capillary electrophoresis-inductively coupled plasma-mass spectrometry and application to natural gr…
2003
Capillary electrophoresis (CE) was coupled to ICPMS in order to combine the good performance of this separation technique with the high sensitivity of the ICPMS for the analysis of plutonium and neptunium oxidation states. The combination of a fused-silica capillary with a MicroMist AR 30-I-FM02 nebulizer and a Cinnabar small-volume cyclonic spray chamber yielded the best separation results. With this setup, it was possible to separate a model element mixture containing neptunium (NpO2(+)), uranium (UO2(2+)), lanthanum (La3+), and thorium (Th4+) in 1 M acetic acid. The same conditions were also suitable for the separation of various oxidation states of plutonium and neptunium in different a…
Trace analysis of plutonium in environmental samples by resonance ionization mass spectroscopy (RIMS)
1998
Resonance ionization mass spectroscopy (RIMS) is well suited for trace analysis of long-lived radioisotopes in environmental, biological and technical samples. By multiple resonant laser excitation and ionization of the elemental atoms under investigation, an extremely high element selectivity can be achieved. In addition, isotope selectivity is obtained by subsequent mass analysis. The excellent sensitivity results from the large atomic cross-sections in the excitation–ionization process and the good detection efficiency for ions. The element selectivity of RIMS allows a simplified procedure for the chemical preparation of the samples compared to the requirements of thin sources for α-spec…
Ultratrace analysis and isotope ratio measurements of long-lived radioisotopes by resonance ionization mass spectrometry (RIMS).
2003
Resonance Ionization Mass Spectrometry (RIMS) is a sensitive and selective method for ultratrace analysis of long-lived radioisotopes and isotope ratio measurements. It provides extremely high isobaric suppression and good overall efficiency. The experimental limits of detection are as low as 10(6) atoms per sample and isotopic selectivities of 5x10(12) have been obtained. The widespread potential of RIMS, using different experimental arrangements, is demonstrated for the determination of the radiotoxic isotopes Pu-238 to Pu-244 and Sr-89/Sr-90 in various environmental samples as well as for Ca-41 in nuclear reactor components and biomedical samples.
Resonance ionization mass spectrometry for ultratrace analysis of plutonium with a new solid state laser system
2004
Abstract Resonance ionization mass spectrometry (RIMS) is well-suited for isotope selective ultratrace analysis of long-lived radioactive isotopes due to its high element and isotope selectivity and good sensitivity. For the analysis of plutonium with a pulsed RIMS apparatus, a powerful, reliable and easy to handle Nd:YAG pumped titanium–sapphire laser system has been developed and combined with a time-of-flight mass spectrometer. Spectroscopic measurements led to an efficient three step excitation and ionization scheme for plutonium with λ1 = 420.76 nm, λ2 = 847.28 nm, and λ3 = 767.53 nm. The isotope shifts in this scheme for the plutonium isotopes 238 Pu through 244 Pu have been determine…
Isotope selective ultratrace analysis of plutonium by resonance ionisation mass spectrometry
2006
Abstract Resonance ionisation mass spectrometry (RIMS) is a sensitive and selective method for isotopically resolved ultratrace analysis of long-lived radionuclides. For the routine analysis of plutonium three titanium–sapphire lasers pumped by a pulsed Nd:YAG laser in combination with a time-of-flight mass spectrometer are used. The detection limit of this system is as low as 106–107 atoms for the plutonium isotopes 238Pu to 244Pu. The RIMS technique was applied to investigate the isotopic composition and the content of plutonium in a depleted uranium penetrator as used during the Balkan conflict delivering important information on the origin of the depleted uranium in this type of ammunit…
Geochemistry, tectonic setting and geodynamic significance of late orogenic dikes in the Melibocus Massif, Bergsträsser Odenwald
2001
The Melibocus Massif forms a tonalite pluton in the W’ Bergstrasser Odenwald, which is interpreted as part of a magmatic arc of Devonian to Carboniferous age. Dikes of various compositions intrude frequently this tonalite. Different dike-lithologies are associated with different strike directions. Most dikes show evidence of high-temperature shearing. A probable maximum paleostress direction of ca. 060° can be estimated, i.e. nearly parallel to the known Variscan subduction zone in the Northwest. Due to their ductile deformation under conditions around the Ar-closing temperature of amphibole, intrusion likely occurred during the Carboniferous (Mississippian). The gabbroic to dioritic dikes …
Laser resonant ionization of plutonium
1985
Resonance ionization mass spectrometry (RIMS) has been tested for the isotope-selective determination of trace amounts of plutonium. An atomic beam is formed by evaporating plutonium atoms from a rhenium-filament heated to 1800 °C. The radiation of a pulsed dye laser excites the atoms in a two-photon process (λ=595.2 nm) followed by photoionization of the excited atoms. Mass selectivity is obtained by use of a time-of-flight spectrometer. A resonant signal of239Pu was measured with 1013 atoms deposited on the filament.