Search results for "polymer"
showing 10 items of 10504 documents
Two-phase dielectric polar structures in 0.1NBT-0.6ST-0.3PT solid solutions
2018
Abstract In this work we address the peculiarities of the macroscopic responses in ternary 0.1Na0·5Bi0·5TiO3-0.6SrTiO3-0.3PbTiO3 (0.1NBT-0.6ST-0.3PT) solid solutions. These solid solutions exhibit a spontaneous first order relaxor to normal ferroelectric phase transition. The phase transition is accompanied by a broad dielectric relaxation which expands over 10 orders of magnitude in frequency just above the phase transition temperature. The temperature dependence of polarization shows that non-zero net polarization persists above the phase transition temperature. Below the phase transition temperature, it is not possible to describe the temperature dependence of polarization with a power l…
Study of the thermochromic phase transition in CuMo1−xWxO4 solid solutions at the W L3-edge by resonant X-ray emission spectroscopy
2021
Abstract Polycrystalline CuMo 1 − x W x O 4 solid solutions were studied by resonant X-ray emission spectroscopy (RXES) at the W L 3 -edge to follow a variation of the tungsten local atomic and electronic structures across thermochromic phase transition as a function of sample composition and temperature. The experimental results were interpreted using ab initio calculations. The crystal-field splitting parameter Δ for the 5d(W)-states was obtained from the analysis of the RXES plane and was used to evaluate the coordination of tungsten atoms. Temperature-dependent RXES measurements were successfully employed to determine the hysteretic behaviour of the structural phase transition between t…
Interface evolution during magnetic pulse welding under extremely high strain rate collision: mechanisms, thermomechanical kinetics and consequences
2020
Abstract Magnetic pulse welding enables to produce perplexing interfacial morphologies due to the complex material response during the high strain rate collision. Thus, a thermomechanical model is used in this study to investigate the formation mechanism of the wake, vortex, swirling and mesoscale cavities with the increase of the impact intensity at the interface. The formation of these interfacial features are difficult to characterize by insitu methods, thus the origin of phenomena still remain a subject of open discussion. Our studies identify the governing mechanisms and the associated thermomechanical kinetics, which are responsible for the formation mechanism of interfacial features.…
Synergistic effect of fiber content and length on mechanical and water absorption behaviors of Phoenix sp. fiber-reinforced epoxy composites
2016
Phoenix sp. fiber-reinforced epoxy composites have been manufactured using compression molding technique. The effect of reinforcement volume content (0%, 10%, 20%, 30%, 40%, and 50%) and size (300 µm particles, 10 mm, 20 mm, and 30 mm fibers) on quasi-static and dynamic mechanical properties was investigated. Moreover, the water absorption properties of composites were analyzed at different environmental conditions (10℃, 30℃, and 60℃). For each reinforcement size, composites loaded with 40% in volume show highest tensile and flexural properties. Furthermore, composites with 300 µm particles present the best impact properties and the lowest water absorption, regardless of the environmental …
Correlation between surface engineering and deformation response of some natural polymer fibrous systems
2018
Surfaces of bamboo derived cellulosic fibrous systems have been modified by air-plasma treatment. Their deformational response was studied to establish the relationship between their three-dimensional profile and permanent deformation as a measure of their comfort properties since the fibrous system made of natural polymer comes into contact with the skin. The composite should have a permanent deformation close to zero, in order to be, in terms of dimensions, as stable as possible. By analyzing the area of 1 cm2 using a Universal Surface Tester (UST), different 3D surface diagrams and surface roughness values were obtained. This type of surface investigation provides relevant information a…
Electrochemical deposition of aniline derivatives for conductometric gas sensors
2019
International audience; Polymer film of poly(2,3,5,6-tetrafluoroaniline) (PTFA) were electroplated on ITO substrate from acidic medium by chronoamperometry. Electrochemical and morphological characterizations were performed and compared to polyaniline properties similarly coated. It seemed that PTFA film had an irreversible redox response with poor conductivity due to the absence of acid-base doping. This film were then incorporated in a patented device called MSDI heterojunction to perform ammonia sensing in humid atmosphere.
The impact of temperature on electrical properties of polymer-based nanocomposites
2020
This work was supported by National Research Foundation of Ukraine, project 2020.02/0217. IK would also like to thank VIAA, State Education Development Agency for Latvian state fellowship. HK would like to thank Ministry of Education and Science of Ukraine, project for young researchers No. 0119U100435. In addition, SP and AAP are thankful for financial support from Latvian Council of Science via grant lzp-2018/2-0083. HK and AAP are grateful for the support from the COST Action CA17126.
pKa at Quartz/Electrolyte Interfaces.
2016
Acidity of silanol sites at the crystalline quartz/aqueous electrolyte (NaCl, NaI, KCl) interfaces are calculated from ab initio molecular dynamics simulations. pKa’s are found to follow a combination of the cationic and anionic Hofmeister series in the order pKa(neat solution) < pKa(NaCl) < pKa(NaI) < pKa(KCl), in agreement with experimental measurements. Rationalization of this ranking is achieved in terms of the microscopic local solvation of the protonated silanols and their conjugated bases, the silanolates SiO–. The change in the pKa is the result of both water destructuring by alkali halides, as well as of the specific cation/SiO– interaction, depending on the electrolyte. M…
Phosphasalen group IV metal complexes: synthesis, characterization and ring opening polymerization of lactide.
2020
International audience; We report the synthesis of a series of Zr and Ti complexes bearing phosphasalen which differs from salen by the incorporation of two P atoms in the ligand backbone. The reaction of phosphasalen proligands (1a-1c)H2 with Zr(CH2Ph)4 led to different products depending on the nature of the N,N-linker in the ligand. In case of ethylene-linked phosphasalen, octahedral Zr complex 2a formed as a single stereoisomer in trans geometry. With the phenylene linker, it was shown by dynamic NMR spectroscopy that complex 2b exists as a mixture of trans and cis-β isomers in solution, both enantiomers (Δ and Λ) of the cis-β isomer being in fast equilibrium with respect to the NMR tim…
Cooperative N–H bond activation by amido-Ge(ii) cations
2020
N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N-H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…