Search results for "polymers"

An experimental method for the investigation of rigid polyurethane foams in shear

2018

Widespread applications of rigid polyurethane and plastic foams lead to shear deformations. Therefore, methods for ensuring shear using experimental investigations are necessary, including the possibility of determining the shear modulus, strength and limit angle. Therefore, a device that allows investigating the shear properties of highly porous plastic foams was developed. The proposed device comprises a clip-on extensometer, commonly exploited in uni-axial compression/tension tests, for the determination of the shear displacement directly on the foams’ sample, on a measurement zone of certain dimensions and location. An innovative construction of the extensometer’s legs is elaborated, p…

Processing, structure, property relationships and release kinetics of electrospun PLA/Carvacrol membranes

2018

Abstract In this work, polylactic acid (PLA) membranes at two different carvacrol (CRV) nominal concentration (i.e. 14 wt% and 28 wt%) were prepared via electrospinning technology. The membranes were characterized by scanning electron microscopy, ATR-FTIR and calorimetric measurements as well as tensile tests. Moreover, the release kinetics of CRV in phosphate buffered solution at 37 °C was monitored through UV–Vis measurements and the data were fitted with a power law model. Results indicated that the successful incorporation of CRV in the polymer matrix damaged the fibers morphology but increased all the mechanical parameters investigated (i.e. elastic modulus, tensile strength and elonga…

Modelling polycarbonate synthesis rates on the example of bulk heteropolyaddition of diphenyl carbonate and bisphenol A diglycidyl ether

2016

This paper investigates the effects of increased reaction mixture viscosity on the kinetics of linear polymer creation in a bulk polyaddition process of diphenyl carbonate and bisphenol A diglycidyl ether. The paper presents a method for solving a system of bulk polyaddition of diphenyl carbonate and bisphenol A diglycidyl ether process balance equations, allowing the determinatiof the process kinetic parameters. Determination of polymerisation reaction kinetic parameters was also made possible by the use of the so-called partial reaction rate constant. Such an approach enabled a significant simplification of the mathematical expressions describing the heteropolyaddition process and provide…

Long-term thermomechanical degradation of molten polystyrene

1985

Abstract Rheological data on polystyrene samples processed for long periods under various mechanical stresses are presented. The data indicate that thermomechanical degradation occurs and that the rate of thermal degradation is increased by the applied stress. Moreover degradation does not reach a limiting value even at high processing times.

Elongational behavior of low density/linear low density polyethylenes

1988

Rheological data have been collected in isothermal elongational flow for three different types of blends, made from one low density polyethylene and three linear low density samples. In addition to the transient curves, elongation at break data are also reported. The influence of the composition and of the molecular weight of the linear low density polyethylene is discussed.

High Optical Quality Films of Liquid Crystalline Cellulose Derivatives in Acrylates

2013

Liquid-Crystalline Elastomer Fibers Prepared in a Microfluidic Device

2014

Redox-Responsive and Thermoresponsive Supramolecular Nanosheet Gels with High Young's Moduli

2018

Supramolecular gels made from 2D building blocks are emerging as one of the novel multifunctional soft materials for various applications. This study reports on a class of supramolecular nanosheet gels formed through a reversible self-assembly process involving both intramolecular folding and intermolecular self-assembly of poly[oligo(ethylene glycol)-co-(phenyl-capped bithiophenes)]. Such hierarchical self-assembled structure allows the gels to switch between sol and gel states under either redox or thermostimulus. Moreover, the gels illustrate high Young's moduli, compared to their controls that are made from the same oligo(ethylene glycol) and phenyl-capped bithiophenes blocks but have h…

Interpolymer complex between hydroxypropyl cellulose and maleic acid-styrene copolymer: phase behavior of semi-dilute solutions.

2005

Summary: The phase behavior of a water/hydroxypropyl cellulose/maleic acid–styrene copolymer (H2O/HPC/MAc-S) system was investigated in the semi-dilute range by turbidimetry, rheology, and optical microscopy. The two polymers under investigation form interpolymer complexes via hydrogen bonding. In the case of a total polymer concentration of cpol = 5 mg · mL−1 a second phase segregates upon heating the homogeneous ternary system. By applying a constant shear rate ( = 50 s−1) the phase separation temperature of the system is 10–15 °C lower than for an unsheared one. For cpol = 10 mg · mL−1 phase separation has already occurred at room temperature when the two binary polymer solutions are mix…

Dynamic mechanical properties of semi-interpenetrating networks based on poly(styrene-co-maleic anhydride): 3. Poly(2,6-dimethyl-1,4-phenylene ether)…

1994

Semi-IPN's based on linear poly(2,6-dimethyl-1,4-phenylene ether) (PPE) and diamine crosslinked poly(styrene-co-maleic anhydride) (PScoMA) copolymers containing small amounts of maleic anhydride (PSA=4.7wt.-% MA, PSB=5.8 wt-% MA) are studied with respect to the influence of cross-linking on the phase behavior. Temperature-dependent dynamic mechanical analysis (DMA) and DSC show that the semi-IPN's prepared from concentrated solution show weak crystallinity of the PPE phase. After heating above the PPE melting transition the semi-IPN's remain amorphous and the relaxation in the glass transition region as well as the terminal relaxation of the free PPE chains in the network is studied as a fu…