Search results for "polymers"

Dynamic characterization for the dielectric electroactive polymer fundamental sheet

2012

Published version of an article published in the journal: International Journal of Advanced Manufacturing Technology. Also available from the publisher at: http://dx.doi.org/10.1007/s00170-012-4423-6 A study into the appropriateness of characterizing the dynamics of the dielectric electroactive polymer (DEAP) fundamental sheet has been performed. Whereby a model describing the dynamics of the DEAP fundamental sheet is developed, parameters of the models are determined using experimental/simulation results, and verification has been conducted to determine the precision of the dynamic model. The precision for the DEAP sheet-obtained dynamic model could not be verified unless some parameters c…

Polymer therapeutics: clinical applications and challenges for development.

2009

A methodology to assess the energetic valorization of bio-based polymers from the packaging industry: pyrolysis of reprocessed polylactide

2012

The energetic valorization process of bio-based polymers is addressed in this study, taking polylactide (PLA) as model. The pyrolysis of virgin and multiple-injected PLA was simulated by means of multi-rate linear-non-isothermal thermogravimetric experiments. A complete methodology, involving control of gases, thermal stability and thermal decomposition kinetics was proposed. The release of gases was monitored by Evolved Gas Analysis of the fumes of pyrolysis, by in-line FT-IR, with the aid of 2D-correlation IR characterization. A novel model to establish the thermal stability of PLAs under any linear heating profile was proposed. A kinetic strategy was methodically applied to assess the th…

Macromolecules in Microfluidics: A Synergy for Systems Engineering

2017

Material characteristics in the analysis of heated steel beams

1989

Beam fire tests are expensive and complicated. They may be replaced by calculations of the heated beam deflection by means of the method presented in this paper. The following material characteristics in the analysis of the deflection of beams during fire may be taken as fundamental: the steel creep characteristic at elevated temperatures, the modulus of elasticity and the coefficient of thermal expansion. According to the yield hinge theory, the yield stress is the criterion of failure of steel beams in fire. On the other hand, in the analysis of the deflection of the heated steel beams the influence of the yield stress is very small. The influence of the respective material characteristic…

The role of EPS concentration in MBR foaming: analysis of a submerged pilot plant.

2010

Foaming in Membrane BioReactor (MBR) is a frequently discussed topic. Some authors reported that the phenomenon is due to filamentous organisms, like at Conventional Activated Sludge (CAS) plants. However, in recent years, other authors reported that the Extra-cellular Polymer Substances (EPSs) concentration is an important factor for controlling foam as well. Nevertheless, even if a number of MBR plants are affected by foaming, presently there are no suitable methods to evaluate the phenomenon. To facilitate the study of this controversial phenomenon in an MBR system, certain foam tests proposed in the past for CASPs were investigated. The results of the tests were able to adequately measu…

The use of anthracene as a model compound in a comparative study of hydrous pyrolysis methods for industrial waste remediation

2011

Author's version of an article published in Chemosphere, 84 (4), 403-408. Also available from the publisher: http://dx.doi.org/10.1016/j.chemosphere.2011.03.061 Polycyclic aromatic hydrocarbons are very stable compounds and tend to bioaccumulate in the environment due to their high degree of conjugation and aromaticity. Hydrous pyrolysis is explored as a technique for the treatment of industrial water containing PAH, using anthracene as a model compound. The reactivity of anthracene under a range of temperatures and durations are studied in this paper. Aliquots of 1.0-10.0mg of anthracene in a range of 1.0-5.0 mL of H(2)O are subjected to hydrous pyrolysis under varied conditions of tempera…

Desulfurization: Critical step towards enhanced selenium removal from industrial effluents

2017

Abstract Selenium (Se) removal from synthetic solutions and from real Flue Gas Desulfurization (FGD) wastewater generated by a coal-fired power plant was studied for the first time using a commercial iron oxide impregnated strong base anion exchange resin, Purolite ® FerrIX A33E. In synthetic solutions, the resin showed high affinity for selenate and selenite, while sulfate exhibited a strong competition for both oxyanions. The FGD wastewater investigated is a complex system that contains Se (∼1200 μg L −1 ), SO 4 2− (∼1.1 g L −1 ), Cl − (∼9.5 g L −1 ), and Ca 2+ (∼5 g L −1 ), alongside a broad spectrum of toxic trace metals including Cd, Cr, Hg, Ni, and Zn. The resin performed poorly again…

Resistance of Conifer Needle Polyolefin Composites (CNPCs) Against Biodecomposition Caused by Fungi

2017

This study describes the resistance of composites filled with conifer needles to biodecomposition processes caused by a single strain of Aspergillus niger as well as by a consortium of microorganisms present in the compost substrates (forest or spent mushroom composts). The impact of various types of conifer needles on the growth of A. niger was studied to determine whether the filler can show the fungistatic effect. The changes in chemical composition of the composites surfaces were examined using attenuated total reflectance Fourier transform infrared spectroscopy (FTIR/ATR). The results showed that the fungistatic effects of conifer needles polyolefin composites (CNPCs) were associated w…

Processing and Properties of Biopolymer/Polyhydroxyalkanoates Blends

2011

In this paper, the processability and the performance of a biodegradable polymer, Mater-Bi, and of its blends with either a sample of poly (hydroxy alkanoates) (PHA) or with bacterial biomass containing PHAs were compared. Adding PHA or directly the biomass containing it allows improving the processability of the matrix. Moreover, the mechanical behaviour of the systems was compared considering two different preparation methods, namely compression and injection moulding. The injection moulded samples show poorer mechanical performances than those of the compression moulded systems. The impact strength significantly improves when PHA is added while it reduces when bacterial biomass is used i…