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Pyrolytic behavior of lignocellulosic-based polysaccharides

2018

The thermochemical behavior of cellulose, glucomannan, and xylan was investigated by pyrolysis–gas chromatographymass spectrometry (Py-GC/MS). In each case, major GC-amenable condensable products were classified into several compound groups, and the formation of these monomer-related fragments from the model substance samples was determined at 500, 600, and 700 C with a residence time of 5 s and 20 s. The results revealed that despite some general formation trends, no compound group was selectively formed at certain temperatures. Of the 11 product groups, the primary ones, including lactone, furan, and cyclopentenone derivatives, accounted for 72–85% (from cellulose), 86–90% (from glucomann…

pyrolysis–gas chromatographyselluloosaGlucomannan02 engineering and technologythermogravimetrykuivatislausPolysaccharidecondensable productspolysakkaridit01 natural sciencesxylanchemistry.chemical_compoundOrganic chemistryHemicellulosePhysical and Theoretical ChemistryCelluloseglucomannanchemistry.chemical_classificationksylaanitChemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsBiorefineryXylan010406 physical chemistry0104 chemical sciencesmannaanitkromatografia0210 nano-technologyEnergy sourcePyrolysis
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