Search results for "pre"
showing 10 items of 50649 documents
Analysis of psychoactive substances in water by information dependent acquisition on a hybrid quadrupole time-of-flight mass spectrometer.
2016
Emerging drugs of abuse, belonging to many different chemical classes, are attracting users with promises of “legal” highs and easy access via internet. Prevalence of their consumption and abuse through wastewater-based epidemiology can only be realized if a suitable analytical screening procedure exists to detect and quantify them in water. Solid-phase extraction and ultra-high performance liquid chromatography quadrupole time-of-flight-mass spectrometry (UHPLC–QqTOF–MS/MS) was applied for rapid suspect screening as well as for the quantitative determination of 42 illicit drugs and metabolites in water. Using this platform, we were able to identify amphetamines, tryptamines, piperazines, p…
Computational Study of the Effect of Glyoxal–Sulfate Clustering on the Henry’s Law Coefficient of Glyoxal
2014
We have used quantum chemical methods to investigate the molecular mechanism behind the recently reported ( Kampf , C. J. ; Environ. Sci. Technol . 2013 , 47 , 4236 - 4244 ) strong dependence of the Henry's law coefficient of glyoxal (C2O2H2) on the sulfate concentration of the aqueous phase. Although the glyoxal molecule interacts only weakly with sulfate, its hydrated forms (C2O3H4 and C2O4H6) form strong complexes with sulfate, displacing water molecules from the solvation shell and increasing the uptake of glyoxal into sulfate-containing aqueous solutions, including sulfate-containing aerosol particles. This promotes the participation of glyoxal in reactions leading to secondary organic…
Joint interpretation of seismic refraction tomography and electrical resistivity tomography by cluster analysis to detect buried cavities
2020
Abstract In the last few years, the geophysical methods of seismic refraction tomography (SRT) and electrical resistivity tomography (ERT) are among the most used geophysical techniques for the reconstruction of subsoil geometries, for the investigation of underground cavities and also for the archaeological prospecting. However, the main disadvantage of each geophysical method is the difficulty of final interpretation of the data. In order to eliminate artifacts and generally improve the reliability and accuracy of geophysical interpretation, it is useful to perform a joint approach of different geophysical methods, also introducing the a priori information. In this work, it is shown the i…
The impact of climate change on extreme precipitation in Sicily, Italy
2018
Increasing precipitation extremes are one of the possible consequences of a warmer climate. These may exceed the capacity of urban drainage systems, and thus impact the urban environment. Because short-duration precipitation events are primarily responsible for flooding in urban systems, it is important to assess the response of extreme precipitation at hourly (or sub-hourly) scales to a warming climate. This study aims to evaluate the projected changes in extreme rainfall events across the region of Sicily (Italy) and, for two urban areas, to assess possible changes in Depth-Duration-Frequency (DDF) curves. We used Regional Climate Model outputs from Coordinated Regional Climate Downscalin…
Impact of internal variability on projections of Sahel precipitation change.
2017
12 pages; International audience; The impact of the increase of greenhouse gases on Sahelian precipitation is very uncertain in both its spatial pattern and magnitude. In particular, the relative importance of internal variability versus external forcings depends on the time horizon considered in the climate projection. In this study we address the respective roles of the internal climate variability versus external forcings on Sahelian precipitation by using the data from the CESM Large Ensemble Project, which consists of a 40 member ensemble performed with the CESM1-CAM5 coupled model for the period 1920–2100. We show that CESM1-CAM5 is able to simulate the mean and interannual variabilit…
Budyko’s Based Method for Annual Runoff Characterization across Different Climatic Areas: an Application to United States
2018
Runoff data knowledge is of fundamental importance for a wide range of hydrological, ecological, and socioeconomic applications. The reconstruction of annual runoff is a fundamental task for several activities related to water resources management, especially for ungauged basins. At catchment scales, the Budyko's framework provides an extremely useful and, in some cases, accurate estimation of the long-term partitioning of precipitation into evapotranspiration and runoff as a function of the prevailing climatic conditions. Recently the same long-term partitioning rules have been successfully used to describe water partitioning also at the annual scale and calculate the annual runoff distrib…
Pharmaceuticals and other urban contaminants threaten Amazonian freshwater ecosystems
2021
Abstract Urban areas in the Brazilian Amazon have grown at an unprecedented rate during the last years. About 90% of the wastewater produced by these urban areas are discharged untreated into Amazonian freshwater ecosystems, constituting a potential environmental pathway for pharmaceuticals and other chemicals consumed by modern societies (e.g. psychostimulants, personal-care products, hormones). The distribution of these chemicals into the Amazon River and their potential risks for freshwater biodiversity have not been evaluated so far. Here, we show the results of the largest chemical monitoring campaign conducted in the Amazon region. We assessed exposure patterns for 43 pharmaceuticals …
Aerosol Chemistry Resolved by Mass Spectrometry: Linking Field Measurements of Cloud Condensation Nuclei Activity to Organic Aerosol Composition.
2016
Aerosol hygroscopic properties were linked to its chemical composition by using complementary online mass spectrometric techniques in a comprehensive chemical characterization study at a rural mountaintop station in central Germany in August 2012. In particular, atmospheric pressure chemical ionization mass spectrometry ((-)APCI-MS) provided measurements of organic acids, organosulfates, and nitrooxy-organosulfates in the particle phase at 1 min time resolution. Offline analysis of filter samples enabled us to determine the molecular composition of signals appearing in the online (-)APCI-MS spectra. Aerosol mass spectrometry (AMS) provided quantitative measurements of total submicrometer or…
Neocomian to early Aptian syn-rift evolution of the normal to oblique-rifted North Gabon Margin (Interior and N'Komi Basins).
2009
18 pages; International audience; The North Gabon coastal rift basins consist of a set of 130–150 long-segment asymmetrically tilted half grabens (Interior Basin) and 000–020 short-segment en échelon half grabens (N'Komi Basin) separated by 040–060 major transverse faults. Tectono-sedimentary analysis of field and subsurface data reveals the control exerted by extensional tectonism over continental sedimentation. During Berriasian to early Barremian times, uniform uniaxial 040–060 extension was responsible for the stretching of the brittle upper crust over a 100-km wide domain. During late Barremian–early Aptian times, the main locus of extension stepped westward resulting in severe end-rif…
Modeling the Effects of Climate Change on the Supply of Phosphate-Phosphorus
2009
The transfer of phosphorus from terrestrial to aquatic ecosystems is a key route through which climate can influence aquatic ecosystems. A number of climatic factors interact in complex ways to regulate the transfer of phosphorus and modulate its ecological effects on downstream lakes and reservoirs. Processes influencing both the amount and timing of phosphorus export from terrestrial watersheds must be quantified before we can assess the direct and indirect effects of the weather on the supply and recycling of phosphorus. Simulation of the export of phosphorus from the terrestrial environment is complicated by the fact that it is difficult to describe seasonal and inter-annual variations …