Search results for "proPO"
showing 10 items of 1325 documents
CCDC 113545: Experimental Crystal Structure Determination
2000
Related Article: U.Stalmach, D.Schollmeyer, H.Meier|1999|Chem.Mater.|11|2103|doi:10.1021/cm990033h
CCDC 952664: Experimental Crystal Structure Determination
2013
Related Article: Naima Khiri-Meribout, Etienne Bertrand, Jérôme Bayardon, Marie-Joëlle Eymin, Yoann Rousselin, Hélène Cattey, Daniel Fortin, Pierre D. Harvey, and Sylvain Jugé|2013|Organometallics|32|2827|doi:10.1021/om400229p
CCDC 814708: Experimental Crystal Structure Determination
2011
Related Article: N.Khiri, E.Bertrand, M.-J.Ondel-Eymin, Y.Rousselin, J.Bayardon, P.D.Harvey, S.Juge|2010|Organometallics|29|3622|doi:10.1021/om100520u
Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
2016
The bimetallic copper(I) complex Cu2L2 (cis-1) is formed with high diasteroselectivity from [Cu(NCCH3)4][BF4] and HL (4-tert-butyl phenyl(pyrrolato-2-yl-methylene)amine) in a kinetically controlled reaction. cis-1 features a rather short Cu···Cu distance of 2.4756(6) A and is weakly emissive at room temperature in solution. Oxidatively triggered disproportionation of cis-1 yields elemental copper and the mononuclear copper(II) complex CuL2 (trans-2). One-electron reduction of trans-2 gives cuprate [2]– with a bent bis(pyrrolato) coordinated copper(I) entity. The imine donor atoms of [2]– can insert an additional copper(I) ion giving exclusively the bimetallic complex cis-1 closing the oxida…
Hydrothermalism in the Tyrrhenian Sea: Inorganic and microbial sulfur cycling as revealed by geochemical and multiple sulfur isotope data
2011
15 pages; International audience; The Palinuro volcanic complex and the Panarea hydrothermal field, both located in the Tyrrhenian Sea (Italy), are associated with island arc magmatism and characterized by polymetallic sulfide mineralization. Dissolved sulfide concentrations, pH, and Eh measured in porewaters at both sites reveal a variable hydrothermal influence on porewater chemistry. Multiple sulfur isotopic measurements for disseminated sulfides (CRS: chromium reducible sulfur) extracted from sediments at Palinuro yielded a broad range in δ34S range between −29.8 and +10.2‰ and Δ33S values between+0.015 and+0.134‰. In contrast, sediments at Panarea exhibit a much smaller range in δ34SCR…
Survival and gene expression under different temperature and humidity regimes in ants
2017
Short term variation in environmental conditions requires individuals to adapt via changes in behavior and/or physiology. In particular variation in temperature and humidity are common, and the physiological adaptation to changes in temperature and humidity often involves alterations in gene expression, in particular that of heat-shock proteins. However, not only traits involved in the resistance to environmental stresses, but also other traits, such as immune defenses, may be influenced indirectly by changes in temperature and humidity. Here we investigated the response of the ant F. exsecta to two temperature regimes (20 degrees C & 25 degrees C), and two humidity regimes (50% & 75%), for…
Aeration control in membrane bioreactor for sustainable environmental footprint
2020
In this study different scenarios were scrutinized to minimize the energy consumption of a membrane bioreactor system for wastewater treatment. Open-loop and closed-loop scenarios were investigated by two-step cascade control strategies based on dissolved oxygen, ammonia and nitrite concentrations. An integrated MBR model which includes also the greenhouse gas formation/emission processes was applied. A substantial energy consumption reduction was obtained for the closed-loop scenarios (32% for Scenario 1 and 82% for Scenario 2). The air flow control based on both ammonia and nitrite concentrations within the aerobic reactor (Scenario 2) provided excellent results in terms of reduction of o…
The efficacy of whole human genome capture on ancient dental calculus and dentin
2019
Objectives Dental calculus is among the richest known sources of ancient DNA in the archaeological record. Although most DNA within calculus is microbial, it has been shown to contain sufficient human DNA for the targeted retrieval of whole mitochondrial genomes. Here, we explore whether calculus is also a viable substrate for whole human genome recovery using targeted enrichment techniques. Materials and methods Total DNA extracted from 24 paired archaeological human dentin and calculus samples was subjected to whole human genome enrichment using in-solution hybridization capture and high-throughput sequencing. Results Total DNA from calculus exceeded that of dentin in all cases, and altho…
When less means more: evolutionary and developmental hypotheses in rodent molars.
2012
10 pages; International audience; Tooth number in rodents is an example of reduction in evolution. All rodents have a toothless diastema lacking canine and most premolars present in most other mammals. Whereas some rodent lineages retained one premolar (p4), many others lost it during evolution. Recently, an 'inhibitory cascade' developmental model (IC) has been used to predict how the first molar (m1) influences the number and relative sizes of the following distal molars (m2 and m3). The model does not, however, consider the presence of premolars, and here we examine whether the premolar could influence and constrain molar proportions during development and evolution. By investigating a l…
Distribution of sea urchins living near shallow water CO2 vents is dependent upon species acid-base and ion-regulatory abilities.
2013
To reduce the negative effect of climate change on Biodiversity, the use of geological CO2 sequestration has been proposed; however leakage from underwater storages may represent a risk to marine life. As extracellular homeostasis is important in determining species' ability to cope with elevated CO2, we investigated the acid-base and ion regulatory responses, as well as the density, of sea urchins living around CO2 vents at Vulcano, Italy. We conducted in situ transplantation and field-based laboratory exposures to different pCO2/pH regimes. Our results confirm that sea urchins have some ability to regulate their extracellular fluid under elevated pCO2. Furthermore, we show that even in cl…