Search results for "protonic"
showing 10 items of 17 documents
Continuous hydrothermal synthesis in supercritical conditions as a novel process for the elaboration of Y-doped BaZrO3
2021
Abstract The present work describes a novel process for the elaboration of a ceramic material. Y-doped barium zirconate, an electrolyte material for Protonic Ceramic Fuel cell, was synthesized by a continuous hydrothermal process in supercritical conditions (410 °C/30.0 MPa) using nitrate precursors and NaOH reactants. The use of supercritical water allowed the formation of particles of about 50 nm in diameter with a narrow size distribution. X-Ray Diffraction examination revealed that a major perovskite phase with few BaCO3 and YO(OH) impurities was obtained. BaCO3 is assumed to form due to faster kinetics than Y-doped BaZrO3 resulting in a Ba-deficient perovskite phase. The Ba-deficiency …
Protonic ceramic fuel cell : elaboration and characterization. Investigation of the BaZr0.8Y0.2O3-d electrolyte by electrochemical impedance spectros…
2021
One of the current global challenges is to find novel, clean and efficient techniques for the energy production. The use of electrochemical cells and hydrogen is one of the solutions. These cells convert the excess energy produced by conventional systems into hydrogen by steam electrolysis. The hydrogen can be stored and transformed into electricity when needed in the fuel cell mode. Among the different electrochemical cells, protonic ceramic electrochemical cells have attracted much attention due to their high efficiency at intermediate temperature (400 – 600 °C). In addition, these systems offer the advantage of not diluting the fuel in electrolysis mode. This thesis work focuses on the e…
Local environment of Barium, Cerium and Yttrium in BaCe1−xYxO3−δ ceramic protonic conductors
2007
Abstract Y-doped barium cerate protonic conductors with composition BaCe 1 − x Y x O 3 − δ ( x = 0.02, 0.1, 0.2, 0.3) have been synthesized by sol–gel route, giving by X-ray diffraction tests a homogeneous crystalline phase. A commercial sample BaCe 0.8 Y 0.2 O 3 − δ produced by combustion spray pyrolysis was also provided for comparison aim. The local structure around the cations was studied by X-ray absorption spectroscopy at the K-edges of Ba, Ce and Y. It is demonstrated that the insertion of yttrium in the site of cerium produces a remarkable local distortion of the dopant first-shell octahedral environment that affects also the next coordination shells by a static disorder increas…
Solid–Solid Interfaces in Protonic Ceramic Devices: A Critical Review
2020
The literature concerning protonic ceramic devices is critically reviewed focusing the reader's attention on the structure, composition, and phenomena taking place at solid-solid interfaces. These interfaces play a crucial role in the overall device performance, and the relevance of understanding the phenomena taking place at the interfaces for the further improvement of electrochemical protonic ceramic devices is therefore stressed. The grain boundaries and heterostructures in electrolytic membranes, the electrode-electrolyte contacts, and the interfaces within composite anode and cathode materials are all considered, with specific concern to advanced techniques of characterization and to …
Anti-Arrhenian behaviour of conductivity in octanoic acid–bis(2-ethylhexyl)amine systems: a physico-chemical study
2015
Pure surfactant liquids and their binary mixtures, owing to the amphiphilic nature of the molecules involved, can exhibit nano-segregation and peculiar transport properties. The structural and dynamic properties of octanoic acid (OA)–bis(2-ethylhexyl)amine (BEEA) liquid mixtures at various compositions have been studied by Wide Angle X-ray Scattering (WAXS), 1H-NMR and broadband dielectric spectroscopy as a function of temperature. It was found that the self-assembly occurs via proton exchange between the OA COOH group and the BEEA NH one; such self-assembled local structures are affected anisotropically by a temperature increase so that the thermal dilatation is more marked in a direction …
Physics at CERN's Antiproton Decelerator
2013
The Antiproton Decelerator of CERN began operation in 1999 to serve experiments for studies of CPT invariance by precision laser and microwave spectroscopy of antihydrogen ($\bar{\rm H}$) and antiprotonic helium ($\bar{p}{\rm He}^+$). The first 12 years of operation saw cold $\bar{\rm H}$ synthesized by overlapping clouds of positrons ($e^+$) and antiprotons ($\bar{p}$) confined in magnetic Penning traps. Cold $\bar{\rm H}$ was also produced in collisions between Rydberg positronium atoms and $\bar{p}$. Ground-state $\bar{\rm H}$ was later trapped for up to $\sim 1000$ s in a magnetic bottle trap, and microwave transitions excited between its hyperfine levels. In the $\bar{p}{\rm He}^+$ ato…
The Atomic Cascade in p̄p and Implications for p̄p Annihilations at Rest
1984
Many experiments at LEAR will study the pp interaction at rest via the formation of an atomic bound system of p and p (protonium). Protonium is formed in a highly excited state when the antiproton has been stopped in a target containing gaseous or liquid hydrogen and after it has been captured by a H2 molecule. The subsequent deexcitation process ends with the annihilation of the pp atom from an atomic s-, p- or d-state. The knowledge of the angular momentum of this atomic state is clearly of fundamental importance in the analysis of the annihilation final states. The aim of this contribution is to review the present experimental and theoretical understanding of the de-excitation and annihi…
Constraints on Exotic Spin-Dependent Interactions Between Matter and Antimatter from Antiprotonic Helium Spectroscopy.
2018
Heretofore undiscovered spin-0 or spin-1 bosons can mediate exotic spin-dependent interactions between standard-model particles. Here we carry out the first search for semileptonic spin-dependent interactions between matter and antimatter. We compare theoretical calculations and spectroscopic measurements of the hyperfine structure of antiprotonic helium to constrain exotic spin- and velocity-dependent interactions between electrons and antiprotons.
Cascade of exotic helium atoms
1987
Abstract The cascade of muonic helium and its pressure dependence has been calculated over the whole pressure range from 1×10 −2 to 1×10 3 atm. The calculation does not use any free parameter. The results show good agreement with experimental data.