Search results for "purity"
showing 10 items of 356 documents
Impurity analysis of JET DiMPle pulses
2021
Divertor monitoring pulses (DiMPle) have been run in JET from the C35 campaign onwards. They provide an opportunity to study the impurity contamination of the plasma when it is limited by different surfaces within the machine, as well as the longer term behaviour of the impurities. In these discharges the plasma is first limited on the outer wall, then on the inner wall and, subsequently, in the X-point configuration the outer strike point is positioned on the horizontal tile 5 of the machine followed by tile 6 and then the vertical tile 7. The present study details the impurity behaviour in the DiMPle pulses from JET-ILW campaigns C35 to C38, which ran from 2015 to 2019. The impurities can…
Giant magnetoresistance in semiconducting DyNiBi
2008
Abstract The semiconducting half-Heulser compound DyNiBi shows a negative giant magnetoresistance (GMR) below 200 K. Except for a weak deviation, this magnetoresistance scales roughly with the square of the magnetization in the paramagnetic state, and is related to the metal–insulator transition. At low temperature, a positive magnetoresistance is found, which can be suppressed by high fields. The magnitude of the positive magnetoresistance changes slightly with the amount of impurity phase.
Removal of total organic carbon from peat solution by hybrid method—Electrocoagulation combined with adsorption
2018
Abstract Humic substances end up in water from the drainage basin causing eutrophication and the spread of algae. These natural organic substances have an influence on the physical, chemical and biological properties of the water system. Adsorption and electrocoagulation (EC) are commonly used purification methods in the water and wastewater treatment. Both methods are used by themselves for removing a wide range of impurities. In this research, the novelty was to study the effect of combined activated carbon (AC) adsorption and electrocoagulation method on the removal of organic substances as total organic carbon (TOC) from the peat solution. With the hybrid method, TOC content was efficie…
Substitution effects on the relaxor properties of lead magnesium niobate ceramics
1999
Abstract The temperature dependence of the dielectric permittivity is studied in different Pb(Mg⅓Nb⅔)O3 based ceramics, in which the ordered region size can be changed by introducing titanium or lanthanum ions. Both the relaxor behaviour and the nonlinear dielectric component are found to be dependent on the impurity content. Especially, the nonlinearity increases strongly as the material exhibits a more conventional ferroelectric behaviour, i.e. as the size of the polar clusters, which develop in the paraelectric matrix, increases.
Comparison of clot lysis activity and biochemical properties of originator tenecteplase (Metalyse®) with those of an alleged biosimilar
2014
The bioengineered tissue plasminogen activator tenecteplase is an important treatment modality of acute myocardial infarction recommended by international guidelines. Following introduction of originator tenecteplase (brand names Metalyse(®) and TNKase(®)), a "biosimilar" tenecteplase became available for commercial use in India under the brand name Elaxim(®) in the absence of Indian biosimilar guidelines which came into force from September 15th, 2012. Based on a report of biochemical and fibrinolytical differences between Metalyse and Elaxim, we have systematically compared them in a range of routine quality testing assays. As compared to Metalyse, Elaxim exhibited less clot lysis activit…
Semi-empirical calculations of the Nb-ion positions in doped crystals
1998
The atomic and electronic structures of Nb impurities in doped perovskite KTaO3 crystals are calculated using the semi-empirical quantum chemical method of the intermediate neglect of the differential overlap (INDO) and a supercell model. When seven Ta ions are replaced by seven Nb ions, the latter clearly demonstrate self-ordering effects which are related to the experimentally observed impurity-induced phase transition. A single Nb impurity reveals an off-centre displacement which is very close to that found in XAFS experiments. The relevant energy gain is very small, approximately 0.0375 eV, which is much smaller than the Nb-clustering energy gain (0.12 eV). These results led us to the c…
Dipolar order and disorder phenomena in pure CO and dilute (CO)1−x(Ar)x mixtures physisorbed on graphite
1999
Abstract A detailed heat capacity study has been performed to characterize the properties of pure CO and (CO) 1− x (Ar) x mixture films physisorbed on the basal planes of graphite. The phase diagram of CO monolayers will be presented. At T c =5.18 K a phase transition to a novel low temperature phase is found with head-tail (dipolar) order of the molecules in an orientationally ordered herringbone structure. The phase transition is shown to belong to the 2D Ising universality class with anisotropic interactions between the molecules. Diluting CO weakly with Ar impurities leads to a dramatic destruction of the phase transition. This effect can be quantitatively described by the 2D random fie…
Tuning the band gap of PbCrO4 through high-pressure: Evidence of wide-to-narrow semiconductor transitions
2014
The electronic transport properties and optical properties of lead(II) chromate (PbCrO4) have been studied at high pressure by means of resistivity, Hall-effect, and optical-absorption measurements. Band-structure first-principle calculations have been also performed. We found that the low-pressure phase is a direct band-gap semiconductor (Eg = 2.3 eV) that shows a high resistivity. At 3.5 GPa, associated to a structural phase transition, a band-gap collapse takes place, becoming Eg = 1.8 eV. At the same pressure the resistivity suddenly decreases due to an increase of the carrier concentration. In the HP phase, PbCrO4 behaves as an n-type semiconductor, with a donor level probably associat…
Self-Ordered Second-Component Nb Clusters in KNbxTa1?xO3 Solid Solutions and Their Physical Properties
1999
Semi-empirical Hartree-Fock calculations using the intermediate neglect of the differential overlap (INDO) method, for self-ordered cubic symmetry clusters of seven Nb ions in KTaO 3 are performed with the aim of verifying the cluster model [1] of second component-induced phase transitions in ferroelectric perovskite matrices. It is shown that a seven-particle cluster in KTaO 3 :Nb has two types of states with different nature. Namely, a state with a dilatation combined with an off-center displacement of the central Nb ion in [111] directions in the cluster, and a state with a full-symmetric compression without any off-center effect. The consequences of such cluster structures on the multi-…
Computer simulations of a Lennard-Jones model for Ar1—x(N2)x: A prototype system for quadrupolar glasses
1998
Abstract Recent theoretical studies of orientational ordering in pure and diluted nitrogen crystals are summarized. While pure N2 has a first order phase transition from a plastic crystal to a phase with long-range orientational order, dilution with argon atoms leads to a quadrupolar glass phase. Monte Carlo simulations are used to study these phases, considering also the behavior of isolated N2 impurities in Ar crystals. It is shown that a simple model that neglects electrostatic interactions and takes only Lennard-Jones interactions into account can describe already many properties in qualitative agreement with experiment. Even the slow dynamics of the quadrupole moments can be modeled by…