Search results for "quantum dot"
showing 10 items of 418 documents
Characteristic Excitation Wavelength Dependence of Fluorescence Emissions in Carbon "quantum" Dots
2017
Carbon "quantum" dots (CDots), generally defined as small carbon nanoparticles with various surface passivation schemes, have emerged to represent a rapidly advancing and expanding research field. CDots are known for their bright and colorful fluorescence emissions, where the colorfulness is associated with the emissions being excitation wavelength dependent. In this work, CDots with 2,2′-(ethylenedioxy)bis(ethylamine) (EDA) for surface functionalization were studied systematically by using steady-state and time-resolved fluorescence methods. The observed fluorescence quantum yields are strongly excitation wavelength dependent, and the dependence apparently tracks closely the observed absor…
Opportunities and Challenges of Fluorescent Carbon Dots in Translational Optical Imaging
2015
The fluorescent carbon dot (C-dot) is a new class of carbon nanomaterials. It has a discrete or quasispherical structure, typically measures less than 10 nm and contains sp(2)/sp(3) carbon, oxygen/nitrogen-based groups and surface-modified functional groups. Compared with semiconductor quantum dots (QDs), C-dots offer much lower toxicity and a better biocompatibility profile. Their other favorable features include easy and inexpensive synthesis and surface modification potential. C-dots can be morphologically classified into graphene-based quantum dots (GQDs) and amorphous carbon nanodots (ACNDs). Numerous methods have been developed to synthesize C-dots, and are mainly divided into 'top-do…
Quantum information processing on spin degrees of freedom in QDs placed in diluted magnetic semiconductor
2006
The spin degrees of freedom in quantum dot (QD) embedded in a diluted magnetic semiconductor (DMS) medium are considered in a model of a qubit and a gate for quantum information processing (QIP). The qubit is defined as a singlet and triplet pair of states of two electrons in a He-type QD in the DMS medium with strongly enhanced gyromagnetic factor. Methods of qubit rotation (Rabi oscillations) as well as two-qubit operations are suggested and analyzed. Moreover, decoherence related to spin waves (magnon-induced dephasing) in this new system (QD in DMS) is studied, and the relevant time-scale is estimated in accordance with preliminary experimental results. (© 2006 WILEY-VCH Verlag GmbH & C…
Quantum dots of Cd0.5Mn0.5Te semimagnetic semiconductor formed by the cold isostatic pressure method
2005
Abstract Cd0.5Mn0.5Te is a semimagnetic semiconductor, which crystallizes in the zinc-blende structure (ZB) and exhibits a magnetic spin glass like transition at 21 K. Under pressure it shows a first-order phase transition around 2.6 GPa to the NaCl like structure. In this work, the pressure cycled method using a Paris–Edinburgh cell up to 8 GPa has been applied to Cd0.5Mn0.5Te samples in order to obtain recovered nanocrystals. The nanoparticles have been characterized by EDX and electron microscopy. The X-ray and electron diffraction results confirmed the existence of nanocrystals in the ZB phase with an average size of 7 nm. Magnetization measurements made in the range of 2–300 K at low f…
Pressure dependence of photoluminescence of InAs/InP self-assembled quantum wires
2007
6 páginas, 4 figuras, 1 tabla.-- PACS 62.50.+ p, 73.21.Hb, 78.55.Cr, 78.67.Lt, 81.15.Hi, 81.16.Dn
Electron tunneling from colloidal CdSe quantum dots to ZnO nanowires studied by time-resolved luminescence and photoconductivity experiments
2015
CdSe quantum dots (QDs) with different organic linker molecules are attached to ZnO nanowires (NWs) to study the luminescence dynamics and the electron tunneling from the QDs to the nanowires in time-resolved photoluminescence (PL) and photoconductivity measurements. The PL transients of the QD luminescence indicate two different recombination channels: the direct recombination inside the QD core and the recombination via QD surface defect states. After linking the QDs to the ZnO NW surface, photo-induced electron tunneling from an excited state of the QD into the conduction band of the nanowire becomes visible by a clear decrease of the PL decay time. Efficient electron tunneling is confir…
Energy of excitons and acceptor–exciton complexes to explain the origin of ultraviolet photoluminescence in ZnO quantum dots embedded in a SiO2 matrix
2011
Abstract Assuming finite depth and within the effective mass approximation, the energies of exciton states and of the acceptor–exciton complexes confined in spherical ZnO quantum dots (QDs) embedded in a SiO2 matrix are calculated using a matrix procedure, including a three-dimensional confinement of carrier in the QDs. This theoretical model has been designed to illustrate the two emission bands in the UV region observed in our experimental Photoluminescence spectrum (PL), with the first emission band observed at 3.04 eV and attributed to the bound ionized acceptor–exciton complexes, and the second one located at 3.5 and assigned to the free exciton. Our calculations have revealed a good a…
Carrier recombination in InAs/GaAs self-assembled quantum dots under resonant excitation conditions
2002
5 páginas, 4 figuras.-- PACS: 73.21.La;73.63.Kv;78.55.Cr;78.67.Hc;S7.12.-- Trabajo presentado en la 7th International Conference on Optics and Excitons in Confined Systems (OECS7).
Exciton recombination in self-assembled InAs/GaAs small quantum dots under an external electric field
2002
5 páginas, 3 figuras.-- PACS: 73.63.Kv; 78.55.Cr; 78.67.Hc; S7.12.-- Trabajo presentado en la 7th International Conference on Optics and Excitons in Confined Systems (OECS7).
Facile synthesis of L-cysteine functionalized graphene quantum dots as a bioimaging and photosensitive agent
2021
Nowadays, a larger number of aggressive and corrosive chemical reagents as well as toxic solvents are used to achieve structural modification and cleaning of the final products. These lead to the production of residual, waste chemicals, which are often reactive, cancerogenic, and toxic to the environment. This study shows a new approach to the modification of graphene quantum dots (GQDs) using gamma irradiation where the usage of reagents was avoided. We achieved the incorporation of S and N atoms in the GQD structure by selecting an aqueous solution of L-cysteine as an irradiation medium. GQDs were exposed to gamma-irradiation at doses of 25, 50 and 200 kGy. After irradiation, the optical,…