Search results for "quantum dynamic"
showing 9 items of 129 documents
Quantum dynamics of the intensity-dependent Tavis-Cummings model
1999
An exactly solvable generalization of the intensity-dependent Jaynes-Cummings model to the case of N0 atoms is introduced together with its solution. The quantum dynamics of the model including the squeezing properties of the su(1,1) Perelomov and Glauber coherent states is investigated. The cases of one and two atoms present in the cavity are analysed in detail. These two cases are compared in the situation when the atomic subsystem is initially prepared in the ground state, the Dicke state and the state of thermal equilibrium.
A comparative account of quantum dynamics of the H+ + H2 reaction at low temperature on two different potential energy surfaces
2014
Rotationally resolved reaction probabilities, integral cross sections, and rate constant for the H+ + H2 (v = 0, j = 0 or 1) → H2 (v′ = 0, j′) + H + reaction are calculated using a time-independent quantum mechanical method and the potential energy surface of Kamisaka et al. [J. Chem. Phys.116, 654 (2002)] (say KBNN PES). All partial wave contributions of the total angular momentum, J, are included to obtain converged cross sections at low collision energies and rate constants at low temperatures. In order to test the accuracy of the KBNN PES, the results obtained here are compared with those obtained in our earlier work [P. Honvault et al. , Phys. Rev. Lett.107, 023201 (2011)] using the ac…
Conjugate and cut loci of a two-sphere of revolution with application to optimal control
2008
Abstract The objective of this article is to present a sharp result to determine when the cut locus for a class of metrics on a two-sphere of revolution is reduced to a single branch. This work is motivated by optimal control problems in space and quantum dynamics and gives global optimal results in orbital transfer and for Lindblad equations in quantum control.
Geometric Optimal Control of Simple Quantum Systems
2011
International audience
The role of the low-lying dark np* states in the photophysics of pyrazine: a quantum dynamics study
2014
The excited state dynamics of pyrazine has attracted considerable attention in the last three decades. It has long been recognized that after UV excitation, the dynamics of the molecule is impacted by strong non-adiabatic effects due to the existence of a conical intersection between the B2u(ππ*) and B3u(nπ*) electronic states. However, a recent study based on trajectory surface hopping dynamics simulations suggested the participation of the Au(nπ*) and B2g(nπ*) low-lying dark electronic states in the ultrafast radiationless decay of the molecule after excitation to the B2u(ππ*) state. The purpose of this work was to pursue the investigation of the role of the Au(nπ*) and B2g(nπ*) states in…
The Principles of Quantum Theory
2013
This chapter develops the formal framework of quantum mechanics: the mathematical tools, generalization and abstraction of the notion of state, representation theory, and a first version of the postulates on which quantum theory rests.
Quantum Correlation Dynamics in Controlled Two-Coupled-Qubit Systems
2020
We study and compare the time evolutions of concurrence and quantum discord in a driven system of two interacting qubits prepared in a generic Werner state. The corresponding quantum dynamics is exactly treated and manifests the appearance and disappearance of entanglement. Our analytical treatment transparently unveils the physical reasons for the occurrence of such a phenomenon, relating it to the dynamical invariance of the X structure of the initial state. The quantum correlations which asymptotically emerge in the system are investigated in detail in terms of the time evolution of the fidelity of the initial Werner state.
Enhancing Metastability by Dissipation and Driving in an Asymmetric Bistable Quantum System.
2018
The stabilizing effect of quantum fluctuations on the escape process and the relaxation dynamics from a quantum metastable state are investigated. Specifically, the quantum dynamics of a multilevel bistable system coupled to a bosonic Ohmic thermal bath in strong dissipation regime is analyzed. The study is performed by a non-perturbative method based on the real-time path integral approach of the Feynman-Vernon influence functional. We consider a strongly asymmetric double well potential with and without a monochromatic external driving, and with an out-of-equilibrium initial condition. In the absence of driving we observe a nonmonotonic behavior of the escape time from the metastable regi…
Octopus, a computational framework for exploring light-driven phenomena and quantum dynamics in extended and finite systems
2020
Over the last few years, extraordinary advances in experimental and theoretical tools have allowed us to monitor and control matter at short time and atomic scales with a high degree of precision. An appealing and challenging route toward engineering materials with tailored properties is to find ways to design or selectively manipulate materials, especially at the quantum level. To this end, having a state-of-the-art ab initio computer simulation tool that enables a reliable and accurate simulation of light-induced changes in the physical and chemical properties of complex systems is of utmost importance. The first principles real-space-based Octopus project was born with that idea in mind,…