Search results for "quantum theory"
showing 10 items of 234 documents
Limits on neutral Higgs boson production in the forward region in $pp$ collisions at $\sqrt{s} = 7$ TeV
2013
Limits on the cross-section times branching fraction for neutral Higgs bosons, produced in p p collisions at root s = 7 TeV, and decaying to two tau leptons with pseudorapidities between 2.0 and 4.5, are presented. The result is based on a dataset, corresponding to an integrated luminosity of 1.0 fb(-1), collected with the LHCb detector. Candidates are identified by reconstructing final states with two muons, a muon and an electron, a muon and a hadron, or an electron and a hadron. A model independent upper limit at the 95% confidence level is set on a neutral Higgs boson cross-section times branching fraction. It varies from 8.6 pb for a Higgs boson mass of 90 GeV to 0.7 pb for a Higgs bos…
Matter, quantum gravity, and adiabatic phase
1990
Based on the observation that particle masses are much smaller than the Planck mass, a framework for the matter-gravity system in which matter follows gravitation adiabatically is examined in a path-integral approach. It is found that the equations that the resulting gravitational wave function satisfies involve, in addition to the expectation value of the matter stress tensor, an adiabatically induced gauge field which can lead to interesting topological structures in superspace. Such a non-trivial geometric contribution modifies the semiclassical quantization condition and can change the conserved quantities associated with the symmetries of the system. © 1990 The American Physical Societ…
Ab initio determination of the electron affinities of DNA and RNA nucleobases
2008
High-level quantum-chemical ab initio coupled-cluster and multiconfigurational perturbation methods have been used to compute the vertical and adiabatic electron affinities of the five canonical DNA and RNA nucleobases: uracil, thymine, cytosine, adenine, and guanine. The present results aim for the accurate determination of the intrinsic electron acceptor properties of the isolated nucleic acid bases as described by their electron affinities, establishing an overall set of theoretical reference values at a level not reported before and helping to rule out less reliable theoretical and experimental data and to calibrate theoretical strategies. Daniel.Roca@uv.es Manuela.Merchan@uv.es Luis.Se…
Precision measurement of D meson mass differences
2013
Using three- and four-body decays of D mesons produced in semileptonic b-hadron decays, precision measurements of D meson mass differences are made together with a measurement of the D-0 mass. The measurements are based on a dataset corresponding to an integrated luminosity of 1.0 fb(-1) collected in pp collisions at 7 TeV. Using the decay D-0 -> K+K-K-pi(+), the D-0 mass is measured to be M(D-0) = 1864.75 +/- 0.15 (stat) +/- 0.11 (syst) MeV/c(2). The mass differences M(D+) - M(D-0) = 4.76 +/- 0.12 (stat) +/- 0.07 (syst) MeV/c(2), M(D-s(+)) - M(D+) = 98.68 +/- 0.03 (stat) +/- 0.04 (syst) MeV/c(2) are measured using the D-0 -> K+K-pi(+)pi(-) and D-(s)(+) -> K+K-pi(+) modes.
Fluorine Scan of Inhibitors of the Cysteine Protease Human Cathepsin L: Dipolar and Quadrupolar Effects in the π-Stacking of Fluorinated Phenyl Rings…
2016
The π-stacking of fluorinated benzene rings on protein backbone amide groups was investigated, using a dual approach comprising enzyme-ligand binding studies complemented by high-level quantum chemical calculations. In the experimental study, the phenyl substituent of triazine nitrile inhibitors of human cathepsin L (hCatL), which stacks onto the peptide amide bond Gly67-Gly68 at the entrance of the S3 pocket, was systematically fluorinated, and differences in inhibitory potency were measured in a fluorimetric assay. Binding affinity is influenced by lipophilicity (clog P), the dipole and quadrupole moments of the fluorinated rings, but also by additional interactions of the introduced fluo…
The Ξ(1620) and Ξ(1690) molecular states from S = −2 meson-baryon interaction up to next-to-leading order
2023
We have studied the meson-baryon interaction in the neutral $S=-2$ sector using an extended Unitarized Chiral Perturbation Theory, which takes into account not only the leading Weinberg-Tomozawa term (as all the previous studies in $S=-2$ sector), but also the Born terms and next-to-leading order contribution. Based on the SU(3) symmetry of the chiral Lagrangian we took most of the model parameters from the BCN model \cite{Feijoo:2018den}, where these were fitted to a large amount of experimental data in the neutral $S=-1$ sector. We have shown that our approach is able to generate dynamically both $\Xi(1620)$ and $\Xi(1690)$ states in very reasonable agreement with the data, and can natura…
Probing Planck scale physics with IceCube
2005
Neutrino oscillations can be affected by decoherence induced e.g. by Planck scale suppressed interactions with the space-time foam predicted in some approaches to quantum gravity. We study the prospects for observing such effects at IceCube, using the likely flux of TeV antineutrinos from the Cygnus spiral arm. We formulate the statistical analysis for evaluating the sensitivity to quantum decoherence in the presence of the background from atmospheric neutrinos, as well as from plausible cosmic neutrino sources. We demonstrate that IceCube will improve the sensitivity to decoherence effects of ${\cal O}(E^2/M_{\rm Pl})$ by 17 orders of magnitude over present limits and, moreover, that it ca…
Lindblad equation approach for the full counting statistics of work and heat in driven quantum systems
2013
We formulate the general approach based on the Lindblad equation to calculate the full counting statistics of work and heat produced by driven quantum systems weakly coupled with a Markovian thermal bath. The approach can be applied to a wide class of dissipative quantum systems driven by an arbitrary force protocol. We show the validity of general fluctuation relations and consider several generic examples. The possibilities of using calorimetric measurements to test the presence of coherence and entanglement in the open quantum systems are discussed. QC 20141010
Direct perturbation theory in terms of energy derivatives: scalar-relativistic treatment up to sixth order.
2011
A formulation of sixth-order direct perturbation theory (DPT) to treat relativistic effects in quantum-chemical calculations is presented in the framework of derivative theory. Detailed expressions for DPT6 are given at the Hartree-Fock level in terms of the third derivative of the energy with respect to the relativistic perturbation parameter defined as λ(rel)=c(-2). They were implemented for the computation of scalar-relativistic energy corrections. The convergence of the scalar-relativistic DPT expansion is studied for energies and first-order properties such as dipole moment and electric-field gradient within the series of the hydrogen halides (HX, X = F, Cl, Br, I, and At). Comparison …
Inhibition of the Cysteine Protease Human Cathepsin L by Triazine Nitriles: Amide⋅⋅⋅Heteroarene π-Stacking Interactions and Chalcogen Bonding in the …
2016
We report an extensive "heteroarene scan" of triazine nitrile ligands of the cysteine protease human cathepsin L (hCatL) to investigate π-stacking on the peptide amide bond Gly67-Gly68 at the entrance of the S3 pocket. This heteroarene⋅⋅⋅peptide bond stacking was supported by a co-crystal structure of an imidazopyridine ligand with hCatL. Inhibitory constants (Ki ) are strongly influenced by the diverse nature of the heterocycles and specific interactions with the local environment of the S3 pocket. Binding affinities vary by three orders of magnitude. All heteroaromatic ligands feature enhanced binding by comparison with hydrocarbon analogues. Predicted energetic contributions from the ori…