Search results for "quantum"

showing 10 items of 9714 documents

Crystal field and magnetism with Wannier functions: Rare-earth doped aluminum garnets

2015

Using the recently developed method we calculate the crystal field parameters in yttrium and lutetium aluminum garnets doped with seven trivalent Kramers rare-earth ions. We then insert calculated parameters into the atomic-like Hamiltonian taking into account the electron-electron, spin-orbit and Zeeman interactions and determine the multiplet splitting by the crystal field as well as magnetic $\hat{g}$ tensors. We compare calculated results with available experimental data.

rare earthsWannier functionZeeman effectStrongly Correlated Electrons (cond-mat.str-el)Condensed matter physicsMagnetismab initio calculationsFOS: Physical scienceschemistry.chemical_elementGeneral ChemistryYttriumLutetiumIongarnetssymbols.namesakeCondensed Matter::Materials ScienceCondensed Matter - Strongly Correlated ElectronschemistryGeochemistry and PetrologysymbolsCondensed Matter::Strongly Correlated ElectronsHamiltonian (quantum mechanics)crystal fieldMultiplet
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KOSMOS 2017 Peru Side Experiment: nutrients, phytoplankton abundances, enzyme rates, photophysiology

2022

This data was collected during an short-term incubation experiment in March 2017 that investigated the response of a surface plankton community to upwelling. This experiment was carried in the framework of the SFB754-funded KOSMOS mesocosm study that took place in La Punta, Callao, Peru between February-April 2017. A total of six different treatments were used to disentangle chemical and biological characteristics of deep water that influence surface plankton blooms: 2 different deep water sources with different nutrient concentrations; 3 treatments to distinguish the effects of inorganic nutrients, organic nutrients and deep water microbial populations. Measured variables include inorganic…

ratioDay of experimentSFB754colored dissolved organic matter at 325 nmNitriteChlorophyll aAbsorption coefficient colored dissolved organic matter at 254 nmClimate - Biogeochemistry Interactions in the Tropical Ocean (SFB754)colorimetric determinationFluorometerFluorometricNitrateNanoplanktonPhytoplankton cells phycocyanin-containing (FL-4)PicoeukaryotesFluorometer fast repetition rateCalculatedFlow cytometryNutrient consumption ratioforward scatterSynechococcusupwelling systemsMesocosm experimentSpectrophotometricClimate Biogeochemistry Interactions in the Tropical Ocean SFB754SilicateBiogeochemistryBiospheric SciencesMaximum photochemical quantum yield of photosystem IIenzyme activitycell sizeDissolved inorganic nitrogen/dissolved inorganic phosphorus ratioKOSMOS_2017chainsAbsorption coefficient colored dissolved organic matter 250 nm/365 nm ratioeastern tropical South Pacific OceanKOSMOSExcess phosphateAbsorption coefficient colored dissolved organic matter at 325 nmNatural SciencesGeosciencescolored dissolved organic matter at 254 nmphycocyanin containing FL 4Absorption coefficientPhosphateTank numberPhytoplankton cells chainsNetwork of Leading European AQUAtic MesoCOSM Facilities Connecting Mountains to Oceans from the ArctReplicatenutrientsfast repetition rateDATE TIMECryptophytesMicrophytoplanktonPhytoplankton cellsLeucine aminopeptidase activityDissolved inorganic nitrogen dissolved inorganic phosphorus ratiofungiEnzymatic assayContinuous flow analyserTreatmentDATE/TIMEcolored dissolved organic matter 250 nm 365 nmPhytoplanktonPhytoplankton cell size forward scatterNetwork of Leading European AQUAtic MesoCOSM Facilities Connecting Mountains to Oceans from the Arctic to the Mediterranean (AQUACOSM)CDOMContinuous flow analyser colorimetric determinationNitrate and Nitrite
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Hard Two-Photon Contribution to Elastic Lepton-Proton Scattering Determined by the OLYMPUS Experiment

2017

The OLYMPUS collaboration reports on a precision measurement of the positron-proton to electron-proton elastic cross section ratio, $R_{2\gamma}$, a direct measure of the contribution of hard two-photon exchange to the elastic cross section. In the OLYMPUS measurement, 2.01~GeV electron and positron beams were directed through a hydrogen gas target internal to the DORIS storage ring at DESY. A toroidal magnetic spectrometer instrumented with drift chambers and time-of-flight scintillators detected elastically scattered leptons in coincidence with recoiling protons over a scattering angle range of $\approx 20\degree$ to $80\degree$. The relative luminosity between the two beam species was mo…

ratioPhysics::Instrumentation and DetectorsHadronFOS: Physical sciencesSocio-culturaleGeneral Physics and AstronomyElectron01 natural sciencestransfersNuclear physicsEconomica0103 physical sciencesddc:550electromagnetic form factorsNuclear Experiment (nucl-ex)010306 general physicselectromagnetic form factors transfers ratioNuclear ExperimentPhysicsLuminosity (scattering theory)010308 nuclear & particles physicsScatteringGenerator (category theory)Form factor (quantum field theory)BremsstrahlungHigh Energy Physics::ExperimentLeptonPhysical Review Letters
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The SO2F2 quasi-spherical top: Correspondence between tensorial and Watson's formalisms

2006

Abstract The SO2F2 quasi-spherical top molecule with C2v symmetry is considered as a distorted spherical top deriving from the SO 4 2 − tetrahedral ion. We present here a detailed correspondence between the tensorial formalism using the Td⊃C2v reorientation and the usual Hamiltonian of Watson. We have also performed ab initio calculations in order to determine the centrifugal distorsion constants in the vibrational ground state.

reductions01 natural sciencesasymmetric top moleculesAnalytical ChemistryIon010309 opticsInorganic Chemistrysymbols.namesakeAb initio quantum chemistry methodsQuantum mechanics0103 physical sciencesPhysics::Atomic and Molecular ClustersPhysics::Chemical Physics010306 general physicsSpectroscopy[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]Chemistryab initio calculationsOrganic ChemistryRotation formalisms in three dimensionsFormalism (philosophy of mathematics)[ PHYS.PHYS.PHYS-AO-PH ] Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]symbolsTetrahedronGround stateHamiltonian (quantum mechanics)tensorial formalismquasi-spherical tops
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Four-dimensional representation of scattering amplitudes and physical observables through the application of the Loop-Tree Duality theorem

2019

Las últimas dos décadas han sido testigo de un tremendo progreso en la física teórica de alta precisión. Muchos avances han sido hechos, en particular, en la evaluación de diagramas multi-loop, pero el principal desafío yace en el tratamiento de las divergencias IR a través de eficientes esquemas de substracción. Con la complejidad del procedimiento incrementándose exponencialmente con el número de escalas, se ha hecho necesario tratar la cuestión desde un ángulo diferente, invocando así al desarrollo de nuevas técnicas. La Dualidad Lazo-Árbol (LTD, por sus siglas en inglés) provee de un nuevo marco para el cómputo de amplitudes con loops. A través de la modificación de la prescripción está…

regularisation and renormalisationUNESCO::FÍSICA::Nucleónicaperturbative quantum field theory:FÍSICA::Nucleónica::Física de partículas [UNESCO]UNESCO::FÍSICA::Nucleónica::Física de partículas:FÍSICA::Nucleónica [UNESCO]cancellation of singularities
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Quantum aspects originated by Gravitation: from cosmology to astrophysics

2018

El estudio de campos cuánticos que se propagan en espacio-tiempos clásicos, curvos y dinámicos, ofrece una primera manera de evaluar las consecuencias de la teoría cuántica cuando los fenómenos gravitatorios no son despreciables. Esta es una cuestión importante que debe ser abordada cuando un campo gravitatorio intenso juega un papel principal en la dinámica de un sistema físico, tal como ocurre durante el universo temprano (inflación cósmica) o en la formación de agujeros negros astrofísicos. Una de las características más sorprendentes de esta materia es quizás el hecho de que el cálculo de observables físicos, incluso para campos sin interacción, frecuentemente involucra operadores cuadr…

renormalization in curved spacetimeelectromagnetic field:FÍSICA [UNESCO]UNESCO::FÍSICAgeneral relativityclassical symmetriesinflationquantum anomaliesquantum field theorycosmology
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Structure-based evaluation of the resonance interactions and effectiveness of the charge transfer in nitroamines

2011

Structural data for five nitroamines of general formula Me₂N–G–NO₂ show effectiveness of the ground-state charge transfer to be most and least efficient in N,N-dimethylnitramine and in 4-N,N-dimethylamino-β-nitrostyrene, respectively. Electron-donor power of the amino nitrogen atom in the latter compound is less than that in 4-nitro-β-N,N-dimethylaminostyrene (these two compounds are isomers). Natural population analysis shows that the charge transfer from the amino to the nitro oxygen atoms is most effective in N,N-dimethylnitramine, Me₂N–NO₂. The nitro oxygen atoms are not the only acceptors of the negative charge lost by the amino nitrogen atom. The nitro group in two substituted nitrobe…

resonance interactionrakennevuorovaikutusresonancequantum-chemical calculationsnitroaminenitroamiiniresonanssi
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Structures and EPR spectra of binary sulfur−nitrogen radicals from DFT calculations

2007

he scattered electron paramagnetic resonance (EPR) spectroscopic data for binary sulfur–nitrogen (S,N) radicals have been compiled and critically assessed.Many of these are inorganic rings or cages.For each species, possible equilibrium structures in the gas phase and the EPR hyperfine coupling (hfc) constants have been calculated with DFT using the B3LYP functional and basis sets of triple-ζ (or better) quality.Good agreement is obtained between calculated and measured values for the well characterized [S3N2]+radical dot, a planar π-radical for which the s-component of the orbitals is likely to be reasonably independent of minor geometrical changes between gas-phase and condensed-phase sta…

rikki-typpi radikaalitPhysics::Chemical PhysicsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectEPR spektroskopiaDFTsulfur-nitrogen radicalsEPR spectroscopy
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Compact Quantum Circuit Design of PUFFIN and PRINT Lightweight Ciphers for Quantum Key Recovery Attack

2023

Quantum computing plays a vital role in the next generation computing platforms as researchers have achieved quantum supremacy by proving that quantum computers can outperform classical computers. These high performance computers will pose a serious threat to the security of the conventional cryptographic algorithms. The secret key of the conventional cryptographic algorithms when implemented by quantum circuits can easily be recovered with the help of Grover key search algorithm. The Grover’s algorithm requires low cost quantum implementation of cryptographic algorithms in order to mount the quantum key recovery attack successfully. Hence the low cost quantum implementation of conventional…

salauslogic gatesalgoritmitcostskvanttilaskentatietoturvaquantum circuitciphersqubitquantum computingencryption
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Nonlinear Absorption and Refraction of Picosecond and Femtosecond Pulses in HgTe Quantum Dot Films

2021

We report measurements of the saturated intensities, saturable absorption, and nonlinear refraction in 70-nm thick films containing 4 nm HgTe quantum dots. We demonstrate strong nonlinear refraction and saturable absorption in the thin films using tunable picosecond and femtosecond pulses. Studies were carried out using tunable laser pulses in the range of 400–1100 nm. A significant variation of the nonlinear refraction along this spectral range was demonstrated. The maximal values of the nonlinear absorption coefficients and nonlinear refractive indices determined within the studied wavelength range were −2.4 × 10−5 cm2 W−1 (in the case of 28 ps, 700 nm probe pulses) and −3 × 10−9 cm2 W−1 …

saturable absorptionQuantum dotsThin filmsGeneral Chemical EngineeringSaturable absorptionPhysics::Opticsquantum dotsquantum dots; mercury telluride; thin films; saturable absorption; nonlinear refraction02 engineering and technology021001 nanoscience & nanotechnology01 natural sciencesArticle010309 opticsChemistrythin filmsNonlinear refraction0103 physical sciences:NATURAL SCIENCES [Research Subject Categories]nonlinear refractionGeneral Materials ScienceMercury telluride0210 nano-technologyQD1-999mercury tellurideNanomaterials
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