Search results for "quench"
showing 10 items of 306 documents
Aza–oxa macrocyclic ligands functionalised with naphthylmethyl fluorescent groups
2000
Abstract Compounds L 1 and L 2 were obtained by reaction of 2-(bromomethyl)naphthalene with 1,4,10-trioxa-7,13-diazacyclopentadecane and 1,4,7-trioxa-10-azacyclododecane, respectively. These receptors contain aza–oxa crowns attached covalently to fluorescent groups. The protonation and coordination behaviour of L 1 and L 2 against metal ions has been studied in dioxane:water (70:30 v/v, 25°C, 0.1 M potassium nitrate) using potentiometric methods. All metal ions studied form complexes with L 1 and L 2 with the logarithm of the formation constants L+M 2+ =[M(L)] 2+ in the sequence Cd 2+ ≅Pb 2+ , Zn 2+ 2+ for L 1 and Zn 2+ 2+ 2+ 2+ 2+ for L 2 . The fluorescent behaviour of L 1 and L 2 was stud…
Zeaxanthin Dependent and Zeaxanthin Independent Changes in Nonphotochemical Energy Dissipation
1994
Summary The influence of zeaxanthin on high-energy-state quenching (qE) of room temperature chlorophyll fluorescence and on the quantum yield of oxygen evolution(ФO2) has been studied with isolated spinach thylakoids. A set of three different pretreatments was tested which all led to thylakoids with high contents of zeaxanthin. Depending on the presence of light the pretreatments differed strongly with respect to their effect on nonphotochemical fluorescence quenching. Independently from the extent of changes in nonphotochemical energy dissipation in the membrane energized state as reflected by nonphotochemical quenching the light pretreatments caused also changes in nonphotochemical energy…
Dynamic Characterization of Upconversion in Highly Er-Doped Silica Photonic Crystal Fibers
2012
Measurements of time evolution of amplified spontaneous emission for square-wave modulated pump were made on a highly erbium-doped silica photonic crystal fiber and fitted to theoretical results calculated using different formalisms to describe the ${\rm Er}^{3+}$ -ion migration-assisted co-operative upconversion mechanism in the population densities rate equations. The determined characterization parameters are the constant homogeneous upconversion coefficient, 3.0 $\times 10^{-24}~{\rm m}^{3}/{\rm s}$ , the critical radii for upconversion and migration, 10.5 and 14A, respectively, and the rate of clustered ions, 14%. These parameters are analysed and compared to those obtained with contin…
Formation of Ordered Structures in Quenching Experiments: Scaling Theory and Simulations
1987
In this note we want to address the particular problem of the formation of ordered structures resulting from “quenching experiments”. The generic experimental situation is depicted in Figure 1. Initially the system is in an unordered random state in the one-phase region. Then the temperature is lowered (for some systems like polymers the coexistence curve is inverted so that the temperature must be raised) until the system is in the two phase region. The system is now in a non-equilibrium situation and evolves toward equilibrium. It is during the evolution toward equilibrium that the system develops ordered structures /1,2/.
Single and Double Beta-DecayQValues among the TripletZr96,Nb96, andMo96
2016
The atomic mass relations among the mass triplet ^{96}Zr, ^{96}Nb, and ^{96}Mo have been determined by means of high-precision mass measurements using the JYFLTRAP mass spectrometer at the IGISOL facility of the University of Jyvaskyla. We report Q values for the ^{96}Zr single and double β decays to ^{96}Nb and ^{96}Mo, as well as the Q value for the ^{96}Nb single β decay to ^{96}Mo, which are Q_{β}(^{96}Zr)=163.96(13), Q_{ββ}(^{96}Zr)=3356.097(86), and Q_{β}(^{96}Nb)=3192.05(16) keV. Of special importance is the ^{96}Zr single β-decay Q value, which has never been determined directly. The single β decay, whose main branch is fourfold unique forbidden, is an alternative decay path to the…
Non-isothermal crystallization kinetics of PET
2000
The crystallization kinetics of poly(ethylene terephthalate) was studied using constant cooling rate, isothermal and quenching experiments. A non-isothermal crystallization kinetics equation based on a single mechanism was used to analyze the data. Different mechanisms of crystallization at low, intermediate, and high cooling rates were hypothesized based on deviation of the experimental data from the single mechanism model.
Quenching of bandgaps by flow noise.
2009
We report an experimental study of acoustic effects produced by wind impinging on noise barriers based on two‐dimensional sonic crystals with square symmetry. We found that the attenuation strength of sonic‐crystal‐bandgaps decreases for increasing values of low speed. A quenching of the acoustic bandgap appears at a certain speed value that depends of the barrier filling ratio. For increasing values of low speed, the data indicate that the barrier becomes in a sound source because of its interaction with the wind. We conclude that flow noise has paramount importance in designing acoustic barriers based on sonic crystals. [Work supported by Spanish AECI.]
On the thermo-mechanical loads and the resultant residual stresses in friction stir processing operations
2008
In friction stir welding and processing both a thermal flux and a mechanical action are exerted on the material determining metallurgical evolutions, changes in the mechanical behaviour and a complex residual stress state. In the paper, the metallurgical changes are examined through numerical simulation and experiments to highlight and distinguish the effects of thermal and mechanical loadings. A particular focus is made on the residual stresses generated during the stir processing of AA7075-T6 aluminium blanks. The predictions of FE model are validated by experimental measurements. Lastly, this paper presents an in-process quenching of the processed blanks for improved mechanical propertie…
Structural transformations in amorphous selenium as studied by the differential thermal analysis and exoelectron emission technique
2007
The parameters (temperature, activation energy) of the surface and volume glass transition (retrification process) in amorphous selenium produced by rapid quenching of the liquid phase have been determined using the EEE and DTA techniques. EEE is a surface effect connected with structural transformations in the surface layer whereas the DTA measurements give the information about the transformations occurring in the volume of the sample. It has been found that the surface retrification of selenium occurs with activation energy smaller than the volume retrification, both observed in the first heating run. The value of activation energy for the volume retrification measured in the second DTA …
Stabilization of the rhombohedral phase in LiZr2(PO4)3 by thermal quenching
1993
Abstract Two LiZr2(PO4)3 samples, which show rhombohedral and monoclinic symmetries, have been studied by powder XRD and MAS-NMR (31P and 7Li) techniques. In the monoclinic sample phosphorus occupies three crystallographic sites and lithium is preferentially placed in M2 environment. When the samples are subjected to successive heating-quenching treatments, the rhombohedral phase is not appreciably modified while the monoclinic phase is transformed into the rhombohedral one. In the quenched samples only one site for phosphorus has been detected and occupancy of lithium in the more symmetric M1 site is favoured. After the thermal treatments, when the samples are stored at room temperature fo…