Search results for "radical"
showing 10 items of 1401 documents
Bond stretching and redox behavior in coinage metal complexes of the dichalcogenide dianions [(SPh2P)2CEEC(PPh2S)2]2- (E=S, Se): diradical character …
2011
The metathetical reactions of a) [Li(tmeda)](2)[(S)C(PPh(2)S)(2)] (Li(2)·3c) with CuCl(2) and b) [Li(tmeda)](2)[(SPh(2)P)(2)CSSC(PPh(2)S)(2)] (Li(2)·4c) with two equivalents of CuCl both afford the binuclear Cu(I) complex {Cu(2)[(SPh(2)P)(2)CSSC(PPh(2)S)(2)]} (5c). The elongated (C)S-S(C) bond (ca. 2.54 and 2.72 A) of the dianionic ligand observed in the solid-state structure of 5c indicate the presence of diradical character as supported by theoretical analyses. The treatment of [Li(tmeda)](2)[(SPh(2)P)(2)CSeSeC(PPh(2)S)(2)] (Li(2)·4b) and Li(2)·4c with AgOSO(2)CF(3) produce the analogous Ag(I) derivatives, {Ag(2)[(SPh(2)P)(2)CEEC(PPh(2)S)(2)]} (6b, E=Se; 6c, E=S), respectively. The disele…
Asymptotics for the Amitsur's Capelli - Type Polynomials and Verbally Prime PI-Algebras
2006
We consider associativePI-algebras over a field of characteristic zero. The main goal of the paper is to prove that the codimensions of a verbally prime algebra [11] are asymptotically equal to the codimensions of theT-ideal generated by some Amitsur's Capelli-type polynomialsEM,L* [1]. We recall that two sequencesan,bnare asymptotically equal, and we writean≃bn,if and only if limn→∞(an/bn)=1.In this paper we prove that\(c_n \left( {M_k \left( G \right)} \right) \simeq c_n \left( {E_{k^2 ,k^2 }^ * } \right) and c_n \left( {M_{k,l} \left( G \right)} \right) \simeq c_n \left( {E_{k^2 + l^2 ,2kl}^ * } \right) \)% MathType!End!2!1!, whereG is the Grassmann algebra. These results extend to all v…
Associative rings with metabelian adjoint group
2004
Abstract The set of all elements of an associative ring R, not necessarily with a unit element, forms a monoid under the circle operation r∘s=r+s+rs on R whose group of all invertible elements is called the adjoint group of R and denoted by R°. The ring R is radical if R=R°. It is proved that a radical ring R is Lie metabelian if and only if its adjoint group R° is metabelian. This yields a positive answer to a question raised by S. Jennings and repeated later by A. Krasil'nikov. Furthermore, for a ring R with unity whose multiplicative group R ∗ is metabelian, it is shown that R is Lie metabelian, provided that R is generated by R ∗ and R modulo its Jacobson radical is commutative and arti…
Radical Rings with Engel Conditions
2000
Abstract An associative ring R without unity is called radical if it coincides with its Jacobson radical, which means that the set of all elements of R forms a group denoted by R ∘ under the circle operation r ∘ s = r + s + rs on R . It is proved that, for a radical ring R , the group R ∘ satisfies an n -Engel condition for some positive integer n if and only if R is m -Engel as a Lie ring for some positive integer m depending only on n .
El discurso totalitario del partido político España 2000
2016
Este artículo analiza los elementos principales del discurso del partido político español, España 2000, concebida como una formación adscrita a la corriente de «derecha radical populista». Para ello, se emplea la metodología de análisis de contenido y se aplica el modelo de «Totalismo Ideológico» propuesto por Robert Jay Lifton, que describe los elementos que caracterizan a las ideologías radicales. Como fuentes de información se utilizan las declaraciones de los líderes de la formación durante un conflicto sucedido en la ciudad de Valencia (España). La investigación muestra las particularidades totalitarias del discurso de la formación española y sus principales ejes ideológicos, que al ig…
Copolymerization of VDF and HFP in Supercritical Carbon Dioxide: A Robust Approach for Modeling Precipitation and Dispersion Kinetics
2012
A kinetic model is developed for the heterogeneous free-radical copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical CO 2. The model accounts for polymerization in both the dispersed (polymer-rich) phase and in the continuous (polymer-free) supercritical phase, for radical interphase transport, diffusion limitations, and chain-length-dependent termination in the polymer-rich phase. A parameter evaluation strategy is developed and detailed to estimate most of the kinetic parameters a priori while minimizing their evaluation by direct fitting. The resulting model predictions compare favorably with the experimental results of conversion and MWD at varying monomer fe…
Synthesis of hydrophilic polymers in supercritical carbon dioxide in the presence of a siloxane-based macromonomer surfactant: Heterogeneous polymeri…
2003
Batch free radical polymerization of 1-vinyl-2-pyrrolidone (VP) in super- critical carbon dioxide (scCO2) was studied in the presence of a reactive polysiloxane surfactant (PDMS-mMA). Phase behavior investigation showed that when the initial concentration of the surface active macromonomer was higher than 2.5% w/w with respect to the monomer, the reaction mixture, in the absence of efficient stirring, was initially opaque to the visible light, and it slowly turned to an orange tint. Polymeriza- tion experiments carried out with surfactant concentration higher than the aforemen- tioned value proceeded with a fast kinetics, and led to the formation of spherical nanoparticles with almost quant…
Dispersion Polymerization of Vinylidene Fluoride in Supercritical Carbon Dioxide
2006
The dispersion polymerization of vinylidene fluoride in supercritical carbon dioxide is investigated using two ammonium carboxylate perfluoropolyether stabilizers of different molecular weights. Under suitable operating conditions a polymer made of well-dispersed spherical particles has been obtained up to relatively high conversion. The experimental data of polymerization rate and molecular weight distribution are in good agreement with the predictions of a model previously developed. Such an agreement supports the conclusion that the polymerization kinetics is dominated by the interphase transport of the active radicals between the continuous phase and the polymer particles.
Copolymerization of vinylidene fluoride and acrylic acid in supercritical carbon dioxide
2009
The free-radical copolymerization of vinylidene fluoride (VDF) and acrylic acid (AA) was carried out in supercritical carbon dioxide using both precipitation and dispersion techniques in the presence of an ammonium carboxylate perfluoropolyether compound. Formation of a copolymer was confirmed by variable contact time CP MAS NMR spectroscopy. Macromolecular matrices were significantly enriched in AA with respect to the initial feed composition and we found that the nonfluorinated monomer has a much higher reactivity ratio with respect to VDF. The cumulative concentration, crystallinity, and water affinity of the synthesized copolymers could be modified changing the initial feed composition,…
Copolymerization of VDF and HFP in Supercritical Carbon Dioxide: Experimental Analysis of the Reaction Loci
2010
Free radical copolymerization reactions of vinylidene fluoride (VDF) and hexafluoropropylene (HFP) were carried out in supercritical carbon dioxide at T=50 °C. When ammonium carboxylate perfluoropolyether surfactants were used, the formation of polymer particles was observed provided that HFP mole fraction in the feed was not larger than 0.30. Under these conditions, the effect of the total interphase area of the polymer phase, Ap, on the product propertieswas investigated by comparing experiments with largely different amounts of stabilizer, i.e., ranging from precipitation (smaller Ap) to dispersion (larger Ap) polymerization systems. We found that the copolymer molecular weight distribut…