Search results for "rare earth element"
showing 10 items of 47 documents
Impact of basin burial and exhumation on Jurassic carbonates diagenesis on both sides of a thick clay barrier (Paris Basin, NE France).
2014
27 pages; International audience; Several diagenetic models have been proposed for Middle and Upper Jurassic carbonates of the eastern Paris Basin. The paragenetic sequences are compared in both aquifers to propose a diagenetic model for the Middle and Late Jurassic deposits as a whole. Petrographic (optical and cathodoluminescence microscopy), structural (fracture orientations) and geochemical (δ18O, δ13C, REE) studies were conducted to characterize diagenetic cements, with a focus on blocky calcite cements, and their connection with fracturation events. Four generations of blocky calcite (Cal1-Cal4) are identified. Cal1 and Cal2 are widespread in the dominantly grain-supported facies of t…
Ceramic productions and human interactions during the Early Bronze Age in northern Iberia
2021
The Early Bronze Age ceramic collection found into the caves of La Llana and El Toral III in Asturias (Spain) presents common decoration such as that found in the centre of Cantabrian Spain from the same period, which resembles others found in the Ebro Valley and Atlantic Europe. Therefore, the main objective of this study it is to identify the raw material origin and understand the pottery production process during the Early Bronze Age in the Cantabrian region. A methodological approach based on the chemical and mineralogical analysis of vessels and experimentally fired clay samples collected all over the centre of this region was developed. Furthermore, the post-depositional processes aff…
Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters
2010
International audience; Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll- content suggest that leaching of Fe-rich atmospheric particulates…
Geochemistry of REE, Zr and HF in a wide range of pH and water composition: The Nevado del Ruiz volcano hydrothermal system (Colombia)
2015
International audience; The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominated with different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters.Y–Ho and Z…
Geochemical processes assessed by Rare Earth Elements fractionation at "Laguna Verde" acidic-sulphate crater lake (Azufral volcano, Colombia)
2017
Abstract The geochemical behaviour of major elements, Fe, Al, Mn, and Rare Earth Elements (REE) was investigated in the “Laguna Verde” acidic crater lake of Azufral volcano (Colombia). The cold lake water (T close to 10 °C) is sulphate-dominated, due to absorption and oxidation of H2S (pH 2.1–2.7, Eh 196–260 mV), and Na-enriched (Total Dissolved Solids 0.79 g L−1). The total amount of REE dissolved in the lake ranges from 3.3 to 9.1 ppb. The REE patterns normalized to the local rocks show a Light Rare Earth Elements (LREE) depletion quite constant in the 15 samples. Similar patterns were already found in the acidic sulphate springs of Nevado del Ruiz volcano-hydrothermal system, caused by t…
Toxicological Impact of Rare Earth Elements (REEs) on the Reproduction and Development of Aquatic Organisms Using Sea Urchins as Biological Models
2022
The growing presence of lanthanides in the environment has drawn the attention of the scientific community on their safety and toxicity. The sources of lanthanides in the environment include diagnostic medicine, electronic devices, permanent magnets, etc. Their exponential use and the poor management of waste disposal raise serious concerns about the quality and safety of the ecosystems at a global level. This review focused on the impact of lanthanides in marine organisms on reproductive fitness, fertilization and embryonic development, using the sea urchin as a biological model system. Scientific evidence shows that exposure to lanthanides triggers a wide variety of toxic insults, includi…
Rare earths release from dissolving atmospheric dust and their accumulation into crystallising halite. The dead-sea example
2023
: The industrial extraction of Y and lanthanides (hereafter defined as Rare Earth Elements, REE) often requires the achievement of leaching procedures removing these metals from primary rocks and their transfer in aqueous leachates or incorporated in newly forming soluble solids. These procedures are the most dangerous to the environment in relation to the composition of leachates. Hence, the recognition of natural settings where these processes currently occur, represents a worthy challenge for learning how to carry out similar industrial procedures under natural and more eco-friendly conditions. Accordingly, the REE distribution was studied in the brine of Dead Sea, a terminal evaporating…
The distribution of Rare Earth Elements discriminates the growth substrate of Vitis vinifera L.
2021
Sustainable agricultural, food-related strategies and geographic traceability require understanding of the plant physiological response to stress potentially generated by contaminated soils. Here, we have investigated the effect of contaminated substrate on growth of Vitis vinifera L. plants analysing the distribution of full Rare Earth Elements (REE) spectra in different parts of the plant. Experiments were carried out using pristine plants growing in a handmade substrate (blank experiment) and in REE artificially-enriched soil (spiked experiment). Our results show that both plant mass and REE amount in leaves are not influenced by the substrate enrichment while roots are by one-order of m…
Behaviour of REE in the soil/Vitis Vinifera L. system. Geochemical Approach for Food Traceability
2021
The geographic traceability of food products through the use of chemical markers is an important challenge to ensure quality and authenticity of food. In recent years, the behaviour of Rare Earth Elements (REE) has been identified as possible tool for food geographical identification based on their known capability of tracing pedo-genetic and petro-genetic processes. In this thesis, the behaviour of REE in the Soil/Vitis vinifera L. system has been explored using a geochemical approach. The goal is to understand if the normalized pattern of REE (REE*) can be a useful tool to trace the geographical origin of food. REE may be accumulated in plants keeping their distribution in passing from so…
Petrography and high-resolution geochemical records of Lower Jurassic manganese-rich deposits from Monte Mangart, Julian Alps
2016
Deposits with unusually high Mn contents sampled at Monte Mangart in the Julian Alps include organic-rich marlstone and black shale with interbedded manganoan and siliceous limestone, which were deposited during the early Toarcian Oceanic Anoxic Event. Mn enrichment during that period has been related to global sea-level change coincident with increasing subsidence rate. The formation of Fe-Mn nodules, marking a hardground at the base of the Monte Mangart section, seems to be triggered by release of Mn from remote hydrothermal vents into a region of relatively elevated submarine topography where oxidizing conditions prevailed. However, very high Mn contents in carbonate phases above the har…