Search results for "rare"
showing 10 items of 2778 documents
Anterior dislocation in a total knee arthroplasty: A case report and literature review.
2015
Dislocations of a total knee arthroplasty (TKA) are an uncommon injury and only few cases of anterior dislocations have been reported. We report a rare case of anterior dislocation of a 10-year-old posterior stabilized total knee arthroplasty in a 74-year-old woman. The patient was successfully treated by close reduction of the dislocation followed by immobilization in full extension with a long leg cast. Because of a high risk of neurovascular complications, a high index of suspicion for vascular injury must be maintained. For this reason, a proper diagnosis is required and immediate reduction is recommended.
Proteins in Amorphous Saccharides: Structural and Dynamical Insights on Bioprotection
2011
We report on experimental and simulative insights on saccharide-based bioprotection, obtained through the study of proteins embedded in amorphous saccharide matrices. The data presented come from a complementary set of techniques (FTIR, MD simulations and SAXS), which provides a description of the bioprotection mechanism from the atomistic to the macroscopic level. The results concur to draw a picture in which bioprotection by saccharides can be explained in terms of a tight anchorage of the protein surface to a stiff matrix, via extended hydrogen-bond networks, whose properties are defined by all its components, and are strongly dependent on the water content. In particular, they show how …
Surface modification of poly(ethylene-co-acrylic acid) with amino-functionalized silica nanoparticles
2011
In this work we studied the possibility to achieve a hybrid-surface through the modification, via a facile wet chemical process, of the surface of films of poly(ethylene-co-acrylic acid) (EAA) with amino-modified silica nanoparticles. Films of EAA were preliminarily activated by the introduction of -COCl groups on their surface. Silica nanoparticles were thereafter covalently bound on the polymeric surface as confirmed by FTIR, ATR-FTIR, XPS, NMR and SEM determinations. The nanoparticles formed a multilayer on the film surface and covered almost uniformly the whole film surface. Direct measurements of superficial amino groups by titration allowed us to detect a concentration of about 18 nmo…
Evaluación de la desaturación regional cerebral de oxígeno monitorizada mediante oximetría cerebral INVOS como método de detección de isquemia cerebr…
2022
Hipótesis: La monitorización de la saturación cerebral regional de oxígeno con el oxímetro INVOS- 5100 es eficaz en la detección de la isquemia cerebral intraoperatoria en la endarterectomía carotídea. Objetivo principal: Evaluar la oximetría cerebral INVOS como método de detección de isquemia cerebral en la cirugía carotídea. Para ello, se comparará el descenso en la saturación cerebral regional de oxígeno INVOS en el grupo de pacientes que presente clínica neurológica en el clampaje carotídeo con el grupo que permanece sin clínica. Objetivos secundarios: 1. Establecer un valor crítico de desaturación cerebral INVOS, absoluto y porcentual, a partir del cual aparece clínica neurológica y es…
Mixtures identification of chemical compounds on the basis of their IR spectra by artificial intelligence
2012
Infrared (IR) spectrometric identification of individual chemical compounds from their mixtures is still a challenging process. Therefore, we developed a method in which we use the IR “Fingerprint” spectra of a particular chemical substance followed by artificial intelligence (AI) – based analysis to correctly characterise components of relatively simple chemical mixtures. We describe here the assembly of tools developed especially for this purpose as well as the artificial neural network design together with the requirements that must be met for its proper functioning. To test our approach, we used a mixture of amphetamine and creatinine which are difficult to identify in mixtures by stand…
Red Light Optogenetics in Neuroscience
2022
Optogenetics, a field concentrating on controlling cellular functions by means of light-activated proteins, has shown tremendous potential in neuroscience. It possesses superior spatiotemporal resolution compared to the surgical, electrical, and pharmacological methods traditionally used in studying brain function. A multitude of optogenetic tools for neuroscience have been created that, for example, enable the control of action potential generation via light-activated ion channels. Other optogenetic proteins have been used in the brain, for example, to control long-term potentiation or to ablate specific subtypes of neurons. In in vivo applications, however, the majority of optogenetic too…
Vibrational Spectrum of HXeSH revisited : Combined computational and experimental study
2020
Vibrational spectrum of HXeSH embedded in low-temperature matrix is experimentally studied. To support the spectrum interpretation, anharmonic vibrational analysis is performed using different models and basis sets and the data is compared with previous experimental and theoretical analyses. Computations of overtones and combination modes allowed for new band assignments. The HXeSH molecule exhibits high anharmonicity similarly as other molecules from the noble-gas hydride family. Comparison of the employed computational methods shows once again that the modelling of the noble-gas compounds faces theoretical challenges to yield quantitatively reliable results. peerReviewed
High-resolution spectrum of La and Ar
2013
A high-resolution spectrum of lanthanum has been recorded by a Fourier Transform spectrometer in the wavelength range from 833nm to 1666nm (6000/cm to 12000/cm) using as light source a hollow cathode lamp operated with argon as the discharge carrier gas. In total, 2386 spectral lines were detected in this region, of which 555 lines could be classified as La I transitions and 10 lines as La II transitions. All La II transitions and 534 of these La I transitions were classified for the first time, and 6 of the La II transitions and 433 of the classified La I transitions appear to be new lines, which could not be found in the literature. The corresponding energy level data of classified lines …
Gaia-ESO Survey: Li-rich stars in NGC2547
2015
The nearby (distance ~350-400pc), rich Vela OB2 association, includes gamma^2^ Velorum, one of the most massive binaries in the solar neighborhood, and is an excellent laboratory for investigating the formation and early evolution of young clusters. Recent Gaia-ESO survey observations led to the discovery of two kinematically distinct populations in the young (10-15Myr) cluster immediately surrounding gamma^2^ Velorum. Here we analyse the results of Gaia-ESO survey observations of NGC 2547, a 35Myr cluster located two degrees south of gamma^2^ Velorum. The radial velocity distribution of lithium-rich pre-main sequence stars shows a secondary population, kinematically distinct and younger th…
Photometry of candidate members of NGC6611
2009
We present the list of candidate members of the young open cluster NGC 6611, selected in a field of view of 33'x34' by the X-rays emission and excesses in infrared bands. X-ray sources without infrared excesses are classified as candidate Class III cluster members; stars with infrared excesses as disk bearing members. Cone search capability for table J/A+A/496/453/catalog (NGC 6611 cluster member positions and magnitudes)