Search results for "reactors"
showing 10 items of 299 documents
Effects of Humic Substances and Soya Lecithin on the Aerobic Bioremediation of a Soil Historically Contaminated by Polycyclic Aromatic Hydrocarbons (…
2004
The high hydrophobicity of polycyclic aromatic hydrocarbons (PAHs) strongly reduces their bioavailability in aged contaminated soils, thus limiting their bioremediation. The biodegradation of PAHs in soils can be enhanced by employing surface-active agents. However, chemical surfactants are often recalcitrant and exert toxic effects in the amended soils. The effects of two biogenic materials as pollutant-mobilizing agents on the aerobic bioremediation of an aged-contaminated soil were investigated here. A soil historically contaminated by about 13 g kg(-1) of a large variety of PAHs, was amended with soya lecithin (SL) or humic substances (HS) at 1.5% w/w and incubated in aerobic solid-phas…
Photocatalytic processes in membrane reactors
2017
Photocatalytic membrane reactors (PMRs) represent an interesting alternative technology useful both in the field of water and air purification and in organic syntheses. The necessity to develop chemical products and industrial processes that reduce or eliminate the use and the generation of toxic substances along with the risk for human health and for environment constitutes the aim of the research efforts based on the principles of green chemistry. Heterogeneous photocatalysis is a technology extensively studied for about three decades, since Fujishima and Honda1 discovered the photocatalytic splitting of water on TiO2 electrodes in 1972, which includes a large range of reactions. When a s…
Influence of operative conditions in a hybrid activated sludge/biofilm process for the treatment of municipal wastewater in a cold climate region: a …
2012
In the last years the idea to combine suspended and attached bomass by introducing suspended carriers into the aeration tank for biofilm attachment and growth was proposed. The increase of the overall sludge age in the system leads to a favourable environment for the growth of nitrifying bacteria, so that nitrification may be maintained throughout the winter. The main aim of the study was to investigate a hybrid MBBR process, mostly in terms of nitrification, when operating with different values of the sludge retention time (SRT), and highlighting the influence of temperature on the process. Based on experience in practice it was hypothesized that nitrification could be maintained at far lo…
Integrated production of biopolymers with industrial wastewater treatment: Effects of OLR on process yields, biopolymers characteristics and mixed mi…
2022
The production of polyhydroxyalkanoates (PHA) using industrial wastewaters as feedstocks is a current and challenging topic. This study investigated the production of biopolymers by a mixed microbial culture under different OLRs equal to 1 kgCOD m-3d-1 (Period 1), 2 kgCOD m-3d-1 (Period 2) and 3 kgCOD m-3d-1 (Period 3). The maximum PHA content was achieved in Period 2 (0.38 gPHA gTSS-1), whereas lower values were obtained in Period 1 (0.13 gPHA gTSS-1) and Period 3 (0.26 gPHA gTSS-1). Overall, the maximum PHA productivity resulted equal to 0.08 gPHA L-1h-1 (P2), 0.05 gPHA L-1h-1 (P1) and 0.04 gPHA L-1h-1 (P3), respectively. The molecular weight of the PHA increased from Period 1 (250 kDa) t…
Towards a conceptual mathematical tool linking physical and biological processes for a reduction of ghg emissions from an mb-mbr plant
2016
The current study explores the influence of the air flow rate on greenhouse gas (GHG) emissions (direct and indirect), the operational costs (OCs), the effluent quality index (EQI) and effluent fines (EF). An University Cape Town (UCT) moving bed (MB) membrane bioreactor (MBR) pilot plant has been considered as case study where the influence of the air flow rate on the biological and physical processes has been analyzed. Constitutive relationships between the air flow rate and some performance indicators (i.e., EQI, OCs, direct and indirect GHG emissions) have been identified. Results showed that the EQI increases at low flow rate likely due to the dissolved oxygen (DO) limitation in the bi…
Photoelectrochemical monitoring of rouging and de-rouging process on AISI 316L for chemical reactors
2016
The food and fine-chemical industry has for a long time been troubled by red brown to dark violet deposits in distillation columns, storage vessels and distribution systems for purified water and clean steam. Owing to the visual appearance of those deposits, the phenomena was referred as rouge. Although formation of rouge, i.e. rouging, is a commonly known phenomenon in stainless steel systems, the basic mechanism is still not fully understood. The phenomenon causes precipitation of iron as fine red-brown ferric oxide or hydroxide particles. Moreover adherent discoloration of the stainless steel surface is often observed in conjunction with the loosely adhered rouge particles. The affected …
Monitoring of Rouging and De-Rouging of Stainless Steel for Chemical Reactors by Photoelectrochemical and Impedance Measurements
2016
The food and fine-chemical industry has for a long time been troubled by red brown to dark violet deposits in distillation columns, storage vessels and distribution systems for purified water and clean steam. Owing to the visual appearance of those deposits, the phenomena was referred as rouge. Although formation of rouge, i.e. rouging, is a commonly known phenomenon in stainless steel systems, the basic mechanism is still not fully understood. The phenomenon causes precipitation of iron as fine red-brown ferric oxide or hydroxide particles. Moreover adherent discoloration of the stainless steel surface is often observed in conjunction with the loosely adhered rouge particles. The affected …
Photoelectrocatalytic reactors and light sources
2023
Photoelectrocatalysis (PEC) couples electrochemical methods with photocatalysis (PC) to enhance the separation of the photoproduced electron and hole pairs at semiconductor active surface, thus increasing the photocatalytic efficiency. PEC technology is considered one of the most promising method for processes as water treatment, fuel generation, and PEC sensing. This chapter try to link fundamental research and practical applications in photoelectrochemical engineering including reactors design strategies in different scales.
PMRs Utilizing Non–Pressure-Driven Membrane Techniques
2018
In the present chapter it is shown how photocatalytic membrane reactors utilizing membrane processes, which are not pressure driven, can exploit various mechanisms to obtain a substantial improvement of the process. The fundamentals of this particular type of membrane reactors are reviewed including the effects of the most important parameters and the methods and rules of coupling photocatalysis and membrane separation. The survey of the studies on photocatalytic membrane reactors (PMRs) utilizing pervaporation, dialysis, membrane contactors and membrane distillation offers the opportunity of discussing the advantages with respect to PMRs adopting pressure driven membrane processes. Indeed,…
Photocatalytic Membrane Reactors: Case Studies and Perspectives
2009
Photocatalysis by polycrystalline semiconductor oxides is being successfully applied to the abatement of organic and inorganic pollutants both in gas and in liquid phase. In order to increase the efficiency of this method, the coupling of this technology with the membrane separation process has been the object of sound investigation. In this combination, the membrane may act in different ways: to confine the photocatalytic powder in the reacting suspension, to selectively separate the photoreaction products, or to be the support of photocatalyst. This article reports recent studies in which different types of membranes (such as distillation, dialysis, nanofiltration, pervaporation and osmos…