Search results for "recrystallization"
showing 10 items of 76 documents
Influence of PVP/VA copolymer composition on drug–polymer solubility
2015
In this study, the influence of copolymer composition on drug-polymer solubility was investigated. The solubility of the model drug celecoxib (CCX) in various polyvinylpyrrolidone/vinyl acetate (PVP/VA) copolymer compositions (70/30, 60/40, 50/50 and 30/70 w/w) and the pure homopolymers polyvinylpyrrolidone (PVP) and polyvinyl acetate (PVA) was predicted at 25 °C using a thermal analysis method based on the recrystallization of a supersaturated amorphous dispersion (recrystallization method). These solubilities were compared with a prediction based on the solubility of CCX in the liquid monomeric precursors of PVP/VA, N-vinylpyrrolidone (NVP) and vinyl acetate (VA), using the Flory-Huggins …
Fire effects on soil aggregation: A review
2011
Abstract Fire can affect soil properties depending on a number of factors including fire severity and soil type. Aggregate stability (AS) refers to soil structure resilience in response to external mechanical forces. Many authors consider soil aggregation to be a parameter reflecting soil health, as it depends on chemical, physical and biological factors. The response of AS to forest fires is complex, since it depends on how fire has affected other related properties such as organic matter content, soil microbiology, water repellency and soil mineralogy. Opinions differ concerning the effect of fire on AS. Some authors have observed a decrease in AS in soils affected by intense wildfire or …
CDRX modelling in friction stir welding of aluminium alloys
2005
In the paper a numerical model aimed to the determination of the average grain size due to continuous dynamic recrystallization phenomena (CDRX) in friction stir welding processes of AA6082 T6 aluminum alloys is presented. In particular, the utilized model takes into account the local effects of strain, strain rate and temperature; an inverse identification approach, based on a linear regression procedure, is utilized in order to develop the proper material characterization.
Metallurgical Phenomena Modelling in Friction Stir Welding of Aluminium Alloys: Analytical vs. Neural Network Based Approaches
2008
In this paper, the metallurgical phenomena occurring in friction stir welding processes of AA6082-T6 and AA7075-T6 aluminum alloys are investigated. In particular, to predict the local values of the average grain size, either a simple analytical expression depending on a few material constants or a properly trained neural network is linked to the finite element model of the process. The utilized tools, which take as inputs the local values of strain, strain rate, and temperature, were developed starting from experimental data and numerical results.
Chemical variations in clay minerals of the Archaean Barberton Greenstone Belt (South Africa)
1996
Abstract Four rock profiles of shales, carbonates and greywacke-type sediments were sampled from the mafic compositional influenced sedimentary Fig Tree Group and from overlying, more felsic related, sedimentary Moodies Group of the Archaean Barberton Greenstone Belt in South Africa. Clay separates of forty sedimentary rocks were examined by XRD and SEM to study the mineralogical, chemical and morphological variations of the constitutive illite and chlorite. The clay minerals showed a significant K-enrichment in the illites and Mg- and Fe-depletions in the chlorites upwards the stratigraphic sequence. Three independent parameters influenced these variations: (1) a change in the origin of th…
The comparison of seven different methods to quantify the amorphous content of spray dried lactose
2006
The purpose of this work was to verify the usefulness, advantages and disadvantages of seven methods that are widely used to detect, and quantify the amorphous contents in pharmaceutical solids. Here, StepScan DSC, a type of modulated temperature calorimetry method, was applied for the first time to quantify amorphicity. The comparison of the analytical methods was undertaken with real (non-artificial) test samples, i.e. spray-dried lactose samples with various degrees of crystallinity. In these samples, it was essential that the amorphous and the crystalline portions are not present as separate particles, which is the case when physical (artificial) mixtures of totally amorphous and totall…
Conditioning following powder micronization: influence on particle growth of salbutamol sulfate.
2003
Micronization is a high-energy process that induces changes in the crystallinity of materials. As a result, the crystalline structures on the particles' surface are being destroyed and amorphous areas are formed. After micronization of salbutamol sulfate to be used in dry powder inhalers, only small amounts of amorphous material are produced. Nevertheless, even these small amounts can have important effects on the physical stability of the powder. The amorphous state is thermodynamically unstable and tends to convert to the stable, crystalline state. The recrystallization process of disordered regions on the particles' surface leads to particle growth of milled particles. In this case, brid…
The Annealing Behavior of the Subsurface Zone Induced by Friction in Bismuth Detected by Positron Lifetime Technique
2013
The annealing behavior of the subsurface zone (SZ) in pure bismuth induced by dry sliding was studied using the positron lifetime measurement. This measurement allows us to detect the SZ and its recovery, and recrystallization processes. The comparative measurements of the sample exposed to compression revealed the thermal stability of the SZ. The compressed sample rebuilt its structure due to the recovery and recrystallization processes at the temperature of 60 °C, whereas the sample exposed to dry sliding does it at higher temperature of 260 °C, which is close to the melting point. The isothermal annealing at the temperature of 100 °C confirmed these results. The defect depth profile indu…
Reworking of Archaean and Palaeoproterozoic crust in the Mozambique belt of central Tanzania as documented by SHRIMP zircon geochronology
2005
Abstract New SHRIMP zircon ages for high-grade rocks from the Pan-African Mozambique belt (MB) of central Tanzania document reworking of Archaean–Palaeoproterozoic crust during the formation of this Neoproterozoic collisional orogen. Several gneisses and granulites from the Great Ruaha river area yielded late Archaean emplacement ages of 2575–2680 Ma for their magmatic precursors. Core-rim relationships in some zircons revealed new zircon growth during relatively short episodes of granitoid magmatism. Metamorphic zircons, dated at 1925 Ma, provide new evidence for high-grade metamorphism during formation of the Palaeoproterozoic Usagaran mobile belt. Metamorphic rims around magmatic cores i…
Palaeoproterozoic ancestry of Pan-African high-grade granitoids in southernmost India: Implications for Gondwana reconstructions
2015
Abstract SHRIMP dating of magmatic zircons from granitoid gneisses and charnockites of the Trivandrum and Nagercoil Blocks in the granulite terrane of southernmost India yielded well-defined protolith emplacement ages between 1765 and ca. 2100 Ma and also document variable recrystallization and/or lead-loss during the late Neoproterozoic Pan-African event at around 540 Ma. Hf-in-zircon and whole rock Nd isotopic data suggest that the granitoid host rocks were derived from mixed crustal sources, and Hf–Nd model ages vary between 2.2 and 2.8 Ga. A gabbroic dyke, emplaced into a charnockite protolith and deformed together with it, only contained metamorphic zircon whose mean age of 542.3 ± 4.0…