Search results for "reduction"
showing 10 items of 2058 documents
Principal polynomial analysis for remote sensing data processing
2011
Inspired by the concept of Principal Curves, in this paper, we define Principal Polynomials as a non-linear generalization of Principal Components to overcome the conditional mean independence restriction of PCA. Principal Polynomials deform the straight Principal Components by minimizing the regression error (or variance) in the corresponding orthogonal subspaces. We propose to use a projection on a series of these polynomials to set a new nonlinear data representation: the Principal Polynomial Analysis (PPA). We prove that the dimensionality reduction error in PPA is always lower than in PCA. Lower truncation error and increased independence suggest that unsupervised PPA features can be b…
The use of Markovian metapopulation models: a comparison of three methods reducing the dimensionality of transition matrices.
2001
The use of Markovian models is an established way for deriving the complete distribution of the size of a population and the probability of extinction. However, computationally impractical transition matrices frequently result if this mathematical approach is applied to natural populations. Binning, or aggregating population sizes, has been used to permit a reduction in the dimensionality of matrices. Here, we present three deterministic binning methods and study the errors due to binning for a metapopulation model. Our results indicate that estimation errors of the investigated methods are not consistent and one cannot make generalizations about the quality of a method. For some compared o…
Porphyrin amino acids-amide coupling, redox and photophysical properties of bis(porphyrin) amides.
2013
New trans-AB2C meso-substituted porphyrin amino acid esters with meso-substituents of tunable electron withdrawing power (B = mesityl, 4-C6H4F, 4-C6H4CF3, C6F5) were prepared as free amines 3a-3d, as N-acetylated derivatives Ac-3a-Ac-3d and corresponding zinc(II) complexes Zn-Ac-3a-Zn-Ac-3d. Several amide-linked bis(porphyrins) with a tunable electron density at each porphyrin site were obtained from the amino porphyrin precursors by condensation reactions (4a-4d) and mono- and bis(zinc(II)) complexes Zn(2)-4d and Zn(1)Zn(2)-4d were prepared. The electronic interaction between individual porphyrin units in bis(porphyrins) 4 is probed by electrochemical experiments (CV, EPR), electronic abso…
Application of 3-Quinolinoyl Picket Porphyrins to the Electroreduction of Dioxygen to Water: Mimicking the Active Site of Cytochromec Oxidase
2001
International audience
Clarification of the oxidation state of cobalt corroles inheterogeneous and homogeneous catalytic reduction of dioxygen
2008
Co(III) corroles were investigated as efficient catalysts for the reduction of dioxygen in the presence of perchloric acid in both heterogeneous and homogeneous systems. The investigated compounds are (5,10,15-tris(pentafluorophenyl)corrole)cobalt (TPFCor)Co, (10-pentafluorophenyl-5,15-dimesitylcorrole)cobalt (F 5PhMes 2Cor)Co, and (5,10,15-trismesitylcorrole)cobalt (Mes 3Cor)Co, all of which contain bulky substituents at the three meso positions of the corrole macrocycle. Cyclic voltammetry and rotating ring-disk electrode voltammetry were used to examine the catalytic activity of the compounds when adsorbed on the surface of a graphite electrode in the presence of 1.0 M perchloric acid, a…
Greatly enhanced intermolecular π-dimer formation of a porphyrin trimer radical trications through multiple π bonds.
2010
A trefoil-like porphyrin trimer linked by triphenylamine (TPA-TPZn(3)) was synthesized. A three-electron oxidation of TPA-TPZn(3) forms a radical trication (TPA-TPZn(3)(3+)), in which each porphyrin ring undergoes a one-electron oxidation. The radical trication TPA-TPZn(3)(3+) spontaneously dimerizes to afford (TPA-TPZn(3))(2)(6+) in CH(2)Cl(2) . The characteristic charge-resonance band due to the charge delocalization over the π system of (TPA-TPZn(3))(2)(6+) was observed in the NIR region. The initial oxidation potential of TPA-TPZn(3) is negatively shifted relative to that of the corresponding monomer porphyrin, which results from the stabilization of the oxidized state of TPA-TPZn(3) as…
Education in Rwanda. Rebalancing Resources to Accelerate Post-Conflict Development and Poverty Reduction
2003
International audience; Rwanda's recent history was marred by genocide in 1994, in which at least ten percent of the population lost their lives. Rebuilding the stock of human capital is an important part of the rehabilitation process, where the government has made efforts to broaden access to education, and enhance the quality of services. On the international stage, the education sector has also come into the limelight, specifically under the 2000 United Nations Millennium Declaration, and, the foregoing context presents clear challenges for education managers. The purpose of this report is to provide a factual basis for discussion. Noteworthy are the efforts to reduce grade repetition in…
Using self-controlled case series to understand the relationship between conflict and cholera in Nigeria and the Democratic Republic of Congo
2021
Abstract Background Cholera outbreaks contribute significantly to diarrhoeal disease mortality, especially in low-income countries. Cholera outbreaks have several social and environmental risk factors and extreme conditions can act as catalysts for outbreaks. A social extreme with known links to infectious disease outbreaks is conflict, causing disruption to services, loss of income and displacement. Methods Here, we explored this relationship in Nigeria and the Democratic Republic of Congo (DRC), by fitting publicly available cholera and conflict data to conditional logistic regression models. We used the self-controlled case series method in a novel application, to understand if an exposu…
Tourism, Poverty Reduction and the Political Economy: Egyptian Perspectives on Tourism's Economic Benefits in a Semi-RentierState
2006
Abstract Tourism's potential as a tool for poverty reduction in developing countries is still part of an endless controversy. This paper argues that one of the main problems of the debate is rooted in a missing nexus between micro- and macro-perspectives. The result is a lack of an adequate consideration of local socio-political power structures and their influence on development issues. Macro-perspective paradigms – like dependency or neoclassic theory – tend to argue from a Euro-centric perspective and largely ignore local political conditions. On the other hand, micro-perspectives – like the alternative development paradigm – emphasize local conditions, but tend to underestimate superior…
Smart grid-aware scheduling in data centres
2015
In several countries the expansion and establishment of renewable energies result in widely scattered and often weather-dependent energy production, decoupled from energy demand. Large, fossil-fuelled power plants are gradually replaced by many small power stations that transform wind, solar and water power into electrical power. This leads to changes in the historically evolved power grid that favours top-down energy distribution from a backbone of large power plants to widespread consumers. Now, with the increase of energy production in lower layers of the grid, there is also a bottom-up flow of the grid infrastructure compromising its stability. In order to locally adapt the energy deman…