Search results for "reduction"
showing 10 items of 2058 documents
The Spanish Turn against Renewable Energy Development
2018
[EN] In this study, we focus on the case of Spanish energy policy and its implications for sustainable energy development. In recent years, Spanish legislation has changed dramatically in its approach to sustainable energy sources. This change is despite EU and international efforts to increase energy efficiency, and to accelerate the transition to renewable energy sources (RES) in order to reduce greenhouse gas emissions. Based on the socio-technical transitions literature, this paper assesses the role of the new legislation in this altered scenario, and analyzes the evolution of energy production in Spain in the EU context. The results are triangulated with two expert assessments. We find…
The dynamic interdependence in the demand of primary and emergency secondary care: A hidden Markov approach
2021
This paper develops an extension of the class of finite mixture models for longitudinal count data to the bivariate case by using a trivariate reduction technique and a hidden Markov chain approach. The model allows for disentangling unobservable time-varying heterogeneity from the dynamic effect of utilisation of primary and secondary care and measuring their potential substitution effect. Three points of supports adequately describe the distribution of the latent states suggesting the existence of three profiles of low, medium and high users who shows persistency in their behaviour, but not permanence as some switch to their neighbour's profile.
Regression with imputed covariates: A generalized missing-indicator approach
2011
A common problem in applied regression analysis is that covariate values may be missing for some observations but imputed values may be available. This situation generates a trade-off between bias and precision: the complete cases are often disarmingly few, but replacing the missing observations with the imputed values to gain precision may lead to bias. In this paper, we formalize this trade-off by showing that one can augment the regression model with a set of auxiliary variables so as to obtain, under weak assumptions about the imputations, the same unbiased estimator of the parameters of interest as complete-case analysis. Given this augmented model, the bias-precision trade-off may the…
Special functions for the study of economic dynamics: The case of the Lucas-Uzawa model
2008
The special functions are intensively used in mathematical physics to solve differential systems. We argue that they should be most useful in economic dynamics, notably in the assessment of the transition dynamics of endogenous economic growth models. We illustrate our argument on the famous Lucas-Uzawa model, which we solve by the means of Gaussian hypergeometric functions. We show how the use of Gaussian hypergeometric functions allows for an explicit representation of the equilibrium dynamics of all variables in level. The parameters of the involved hypergeometric functions are identified using the Pontryagin conditions arising from the underlying optimization problems. In contrast to th…
Industry 4.0: Advanced digital solutions implemented on a close power loop test bench
2021
Abstract The paradigm of Industry 4.0 allows to increase the efficiency and effectiveness of the production. Companies that will implement advanced solutions in production systems will increase their level of competitiveness and will be able reach high market shares. The present paper is focused on the development of advanced digital solutions to be implemented on a close power loop test bench designed to test high power transmissions for naval unit. In particular, the test configuration consists of a back-to-back connection between two identical mechanical reducers. Since the efficiency of these systems are very high, it is not necessary to use large electric motors, thus managing to conta…
Electrochemical conversion of carbon dioxide to formic acid: on the road to applicative scale
2018
In this context, electrochemical reduction of CO2 is considered one of the more attractive pathway to convert CO2, because the products can be selectively controlled by changing the operative conditions of the electrolysis. In the last years, an increasing attention has been devoted on the electrochemical conversion of CO2 to formic acid in water [2,3]. The main hurdle of the reduction of CO2 from water solution is the low CO2 solubility in water. In this work, the effect of some operating parameters, including pressure, current density, and flow rate, on the conversion of CO2 at tin flat cathodes to formic acid was studied using a pressurized filter-press cell with a continuous recirculati…
Electrochemical conversion of carbon dioxide: effect of the cell and of the operating parameters on the performances of the process.
2017
Recycling technologies of CO2 allow to introduce renewable energy in the chemical and energy chain, storing a renewable energy in the chemical form. In this context, electrochemical conversion of CO2 is considered one of the more interesting approaches, using excess electric energy from intermittent renewable sources. (1) Furthermore, products can be selectively controlled by changing the operating conditions of electrolysis. In particular, in the last years, an increasing attention has been devoted to the electrochemical conversion of CO2 to formic acid or formate in water. (2,3,4) The main hurdle of the reduction of CO2 from water solution is the low CO2 solubility in water. In this work,…
ELECTROCHEMICAL CONVERSION OF CARBON DIOXIDE TO FORMIC ACID IN A PRESSURIZZED FILTER PRESS CELL
2018
To limit the negative effect of carbon dioxide as a greenhouse gas, an interesting approach is the utilization of Carbon Capture and Conversion (CCC) methodology, which is focused on the use of CO2 waste as a feedstock to produce added-value product by using the excess electric energy from renewable source [1]. In this framework, an increasing attention has been devoted in the electrochemical conversion of carbon dioxide to formic acid in water [2,3], which is considered one of the more attractive pathway to convert CO2. Since the main hurdle of the CO2 reduction from aqueous solution is the low CO2 solubility in water, in this work, the effect of some operating parameters, including pressu…
Simple electrochemical reduction of nitrones to amines.
2018
Only electricity is needed for the transformation of nitrones to amines. Such a direct double reduction has not been reported by any sole chemical reagent in a single step process.
Electrochemistry as an Attractive and Effective Tool for the Synthesis and Immobilization of Porphyrins on an Electrode Surface
2014
Magnesium(II) 10-phenyl-5,15-p-ditolylporphyrin is easily and cleanly transformed by electrolysis. A nitro group is first introduced at the free meso position by anodic substitution. Hydrogenation into the amine is then carried out electrocatalytically under ambient conditions with water as a hydrogen supplier. The synthesized porphyrin under the nickel(II) form can be covalently grafted onto a platinum electrode by electrochemical reduction of the diazonium cation, generated in situ by a reaction of the nickel(II) aminoporphyrin with sodium nitrite and trifluoroacetic acid. The electrosynthesized thin film gives an electrochemical response typical of a porphyrin material. Films grown under…