Search results for "resolution"

showing 10 items of 1928 documents

Synthesis, resolution, stereochemistry, and molecular modeling of (R)- and (S)-2-acetyl-1-(4’-chlorophenyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinol…

2007

Abstract Recently we identified ( R , S )-2-acetyl-1-(4′-chlorophenyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline ( 6 ) as a potent non-competitive AMPA receptor antagonist able to prevent epileptic seizures. We report here the optimized synthesis of compound 6 , its resolution by chiral preparative HPLC, and the absolute configuration of ( R )-enantiomer established by X-ray diffractometry. The biological tests of the single enantiomers revealed that higher anticonvulsant and antagonistic effects reside in ( R )-enantiomer as also suggested by molecular modeling studies.

MaleModels MolecularMolecular modelStereochemistryClinical BiochemistryPharmaceutical ScienceConvulsantsAMPA receptorCrystallography X-RayBiochemistryChemical synthesisMicrowave-assisted synthesisEnantiomeric resolutionchemistry.chemical_compoundMiceSeizuresTetrahydroisoquinolinesTetrahydroisoquinolineDrug DiscoveryAnticonvulsantAnimalsMolecular BiologyMolecular StructureTetrahydroisoquinolineOrganic ChemistryAntagonistAbsolute configurationTetrahydroisoquinoline; Microwave-assisted synthesis; Enantiomeric resolution; AnticonvulsantBiological activityStereoisomerismRatschemistryReceptors GlutamateMolecular MedicineEnantiomerExcitatory Amino Acid Antagonists
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Courtship Behavior of Brain Mosaics in Drosophila

2000

0167-7063 (Print) Journal Article Research Support, Non-U.S. Gov't; Sites in the brain that show functional, sexual dimorphism in courtship behavior have been mapped at high resolution in male/female mosaics of Drosophila melanogaster. The sex mosaics were produced by enhancer-trap expression of GAL4 driving the female-spliced form of the transformer gene (tra), revealing sites in the dorsal brain, lateral protocerebrum, suboesophageal, thoracic and abdominal ganglia, and suggesting the importance of cross-talk between these regions in the implementation of the courtship sequence.

MaleNuclear Proteins/analysis/*geneticsProtocerebrumNervous systemDorsumanimal structuresSexual Behaviormedia_common.quotation_subjectGene ExpressionHigh resolutionGenetically ModifiedBiologyNervous SystemAnimals Genetically ModifiedCourtshipSexual Behavior AnimalCellular and Molecular NeuroscienceGeneticsmedicineDrosophila ProteinsAnimalsCluster AnalysisDrosophila melanogaster/*geneticsNervous System/*chemistrymedia_commonBrain ChemistryGeneticsCourtship displayHistocytochemistryMosaicismAnimalfungiNuclear Proteinsbiology.organism_classificationSexual dimorphismDrosophila melanogastermedicine.anatomical_structureEvolutionary biologyGangliaFemaleDrosophila melanogasterGanglia/chemistryJournal of Neurogenetics
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EAU Guidelines on Vesicoureteral Reflux in Children

2012

Context: Primary vesicoureteral reflux (VUR) is a common congenital urinary tract abnormality in children. There is considerable controversy regarding its management. Preservation of kidney function is the main goal of treatment, which necessitates identification of patients requiring early intervention.Objective: To present a management approach for VUR based on early risk assessment.Evidence acquisition: A literature search was performed and the data reviewed. From selected papers, data were extracted and analyzed with a focus on risk stratification. The authors recognize that there are limited high-level data on which to base unequivocal recommendations, necessitating a revisiting of thi…

MalePediatricsACID SCINTIGRAPHYmedicine.medical_treatmentKidneyurologic and male genital diseasesPediatricsVOIDING CYSTOURETHROGRAPHYURETERAL REIMPLANTATIONMedicineAntibiotic prophylaxisFamily historyChildChildrenNEONATAL HYDRONEPHROSISReimplantationUrinary tract infectionVesicoureteral refluxDiagnostic Techniques Urologicalfemale genital diseases and pregnancy complicationsAnti-Bacterial AgentsTreatment OutcomeRenal scarringBulking agentsEAUPREDICTIVE FACTORSChild PreschoolPredictive value of testsUrologic Surgical ProceduresFemaleRisk assessmentmedicine.medical_specialtyUrologyUrinary systemContext (language use)GuidelinesVesicoureteral refluxURINARY-TRACT-INFECTIONANTIBIOTIC-PROPHYLAXISPredictive Value of TestsHumansWatchful WaitingVesico-Ureteral RefluxProphylaxisbusiness.industryInfantEndoscopymedicine.diseaseVURSurgeryISOLATED ANTENATAL HYDRONEPHROSISEarly DiagnosisRENAL DAMAGESPONTANEOUS RESOLUTIONLaparoscopybusinessWatchful waitingEuropean Urology
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Oscillatory brain activity associated with skin conductance responses in the context of risk

2021

Understanding the neural correlates of risk-sensitive skin conductance responses can provide insights into their connection to emotional and cognitive processes. To provide insights into this connection, we studied the cortical correlates of risk-sensitive skin conductance peaks using electroencephalography. Fluctuations in skin conductance responses were elicited while participants played a threat-of-shock card game. Precise temporal information about skin conductance peaks was obtained by applying continuous decomposition analysis on raw electrodermal signals. Shortly preceding skin conductance peaks, we observed a decrease in oscillatory power in the frequency range between 3 and 17 Hz i…

MalePhysicsintegumentary systemPhysiologyBrain activity and meditationGeneral NeuroscienceResolution (electron density)Context (language use)Galvanic Skin ResponseBrain WavesArousalVisual processingYoung AdultRisk-TakingHumansOccipital LobeSkin conductanceNeuroscienceJournal of Neurophysiology
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High-resolution computed tomography quantitation of emphysema is correlated with selected lung function values in stable COPD

2012

<b><i>Background:</i></b> The literature shows conflicting results when high-resolution computed tomography (HRCT) scores of emphysema were correlated with different indices of airflow obstruction. <b><i>Objectives:</i></b> We correlated HRCT scores of emphysema with different indices of airflow obstruction. <b><i>Methods:</i></b> We performed HRCT of the chest in 59 patients, all smokers or ex-smokers, with stable chronic obstructive pulmonary disease of different severity [GOLD stages I–IV; mean age ± SD 67.8 ± 7.3 years; pack/years 51.0 ± 34.6; percent predicted forced expiratory volume in 1 s (FEV<sub>1</su…

MalePulmonary and Respiratory MedicineEmphysema COPD High-resolution computed tomography Lung structural alterationsVital capacityHigh-resolution computed tomographyPulmonary diseaseLung structural alterationsSeverity of Illness IndexPulmonary Disease Chronic ObstructiveFEV1/FVC ratioSeverity of illnessmedicineHumansCOPDLung volumesLung functionHigh-resolution computed tomographyAgedEmphysemaCOPDmedicine.diagnostic_testbusiness.industryChronic obstructive pulmonary diseaseSmokingrespiratory systemmedicine.diseaseBronchodilator AgentsRespiratory Function Testsrespiratory tract diseasesPulmonary EmphysemaAnesthesiaMultivariate AnalysisFemaleTomography X-Ray ComputedbusinessNuclear medicineChronic obstructive pulmonary disease; Emphysema; High-resolution computed tomography; Lung structural alterations;
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Assessment of Lung Cancer Development in Idiopathic Pulmonary Fibrosis Patients Using Quantitative High-Resolution Computed Tomography:A Retrospectiv…

2020

Purpose The purpose of this study was to investigate histogram-based quantitative high-resolution computed tomography (HRCT) indexes in the assessment of lung cancer (LC) development in idiopathic pulmonary fibrosis (IPF) patients. Materials and methods From IPF databases of 2 national respiratory centers, we retrospectively studied patients with and without LC development-respectively, divided into Group A (n=16) and Group B (n=33). The extent of fibrotic disease was quantified on baseline and follow-up HRCT examinations using kurtosis, skewness, percentage of high attenuation area (HAA%), and percentage of fibrotic area (FA%). These indexes were compared between the 2 groups using the Man…

MalePulmonary and Respiratory MedicineHigh-resolution computed tomography030204 cardiovascular system & hematologylung neoplasmsSensitivity and Specificity030218 nuclear medicine & medical imaging03 medical and health sciencesIdiopathic pulmonary fibrosis0302 clinical medicineFibrosismedicineRetrospective analysisHumansRadiology Nuclear Medicine and imagingusual interstitial pneumoniaLung cancerLungmultidetectorAgedRetrospective StudiesAged 80 and overmedicine.diagnostic_testbusiness.industryRetrospective cohort studycomputed tomographyMiddle Agedmedicine.diseaseidiopathic pulmonary fibrosisDisease ProgressionMann–Whitney U testKurtosisFemaleTomography X-Ray ComputedNuclear medicinebusiness
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Positive Adolescent Development: Effects of a Psychosocial Intervention Program in a Rural Setting

2020

The Positive Youth Development (PYD) approach identifies adolescents as resources to be empowered rather than problems to be solved. All adolescents have strengths and will fully develop when these strengths are integrated with healthy resources in the diverse environments where they live and interact. The objective of this study was twofold: (1) to present the Positive Development Program for Adolescents living in rural areas (DPAR Program) and (2) to pilot test the intervention program. The DPAR program was evaluated using a repeated-measures design before and after the intervention, with an intervention group and a control group. The sample consisted of 176 adolescents between 11 and 15 …

MaleRural PopulationAdolescentHealth Toxicology and Mutagenesismedia_common.quotation_subjectlcsh:Medicine050109 social psychologyEmpathyPsychosocial Interventionpositive developmentArticleDevelopmental psychologyrural contextAlexithymiaIntervention (counseling)Conflict resolutionmedicineHumans0501 psychology and cognitive sciencesAssertivenessadolescentsChildmedia_commonSchools05 social scienceslcsh:RPublic Health Environmental and Occupational HealthAdolescent Developmentmedicine.diseaseintervention programAdolescent BehaviorFemaleRural areaPositive Youth DevelopmentPsychologyPsychosocial050104 developmental & child psychologyInternational Journal of Environmental Research and Public Health
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Identification of a novel mutation in the alpha-galactosidase A gene in patients with Fabry disease.

2012

Abstract Objectives Mutation analysis of the alpha-galactosidase A (GLA) gene is a valuable tool for the diagnosis of affected families. In our work, we analyze about one thousand samples per year from patients suspected of having Fabry disease (FD). Design and methods We carried out high resolution melting analysis (HRM) and DNA sequencing of all the exons of the GLA gene. We also assayed the alpha-galactosidase A activity in patients' blood. Results In some members of one family, we identified a new mutation in the GLA gene, c.614delC. This is a deletion of a single nucleotide, a cytosine, in exon 4 of the gene which causes a frameshift mutation. Conclusions Patients with the c.614delC mu…

MaleSettore MED/09 - Medicina InternaClinical BiochemistryDNA Mutational AnalysisHigh Resolution MeltFrameshift mutationExonmedicineHumansFrameshift MutationGeneSequence DeletionGeneticsFamily HealthAlpha-galactosidasebiologyBase Sequencealpha-galactosidase A geneGeneral MedicineExonsmedicine.diseaseMolecular biologyFabry diseasealpha-GalactosidaseMutation (genetic algorithm)Mutation testingbiology.proteinFabry DiseaseFemalemutationClinical biochemistry
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Comparison of two artificial tear formulations for dry eye through high‐resolution optical coherence tomography

2011

Purpose:  The aim was to determine the efficacy of two artificial eye-drop formulations by analysing the lower tear film meniscus volume through a commercial high-resolution spectral-domain optical coherence tomographer. Methods:  Twenty dry eye patients (12 men, eight women, aged 57.5 ± 8.4 years) with refractive errors from -2.50 to +0.75 D (mean -1.34 ± 1.02 D) and cylinders lower than 1.00 D were examined. Tear meniscus volume was measured before, immediately after and 10, 30 and 60 minutes after instillation using the Copernicus high-resolution spectral-domain optical coherence tomographer (Optopol Tech SA, Zawiercie, Poland). Volume was calculated from the local area obtained from tom…

Malemedicine.medical_specialtyDrug Compoundingmedicine.medical_treatmentDry Eye SyndromesHigh resolutionMeniscus (anatomy)Young AdultOptical coherence tomographyReference ValuesOphthalmologymedicineHumansSurface Tensionmedicine.diagnostic_testbusiness.industryImage Enhancementeye diseasesSurgeryOphthalmologyArtificial tearsmedicine.anatomical_structureVolume (thermodynamics)TearsTearsDry Eye SyndromesFemalesense organsEyelidOphthalmic SolutionsbusinessTomography Optical CoherenceFollow-Up StudiesOptometryClinical and Experimental Optometry
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Chromoendoscopy and narrow-band imaging compared with high-resolution magnification endoscopy in Barrett's esophagus.

2008

Background & Aims: The aim of this study was to compare magnified still images obtained with high-resolution white light endoscopy, indigo carmine chromoendoscopy, acetic acid chromoendoscopy, and narrow-band imaging to determine the best technique for use in Barrett's esophagus. Methods: We obtained magnified images from 22 areas with the 4 aforementioned techniques. Seven endoscopists with no specific expertise in Barretes esophagus or advanced imaging techniques and 5 international experts in this field evaluated these 22 areas for overall image quality, mucosal image quality, and vascular image quality. In addition, the regularity of mucosal and vascular patterns and the presence of abn…

Malemedicine.medical_specialtyEsophageal NeoplasmsHigh resolutionIndigo CarmineGastroenterologyChromoendoscopychemistry.chemical_compoundBarrett EsophagusEsophagusInternal medicinemedicineHumansEsophagusColoring AgentsAcetic AcidAgedAged 80 and overObserver VariationNarrow-band imagingMucous MembraneHepatologybusiness.industryGastroenterologyReproducibility of ResultsMiddle Agedmedicine.diseaseImage EnhancementMagnification endoscopymedicine.anatomical_structureIndigo carminechemistryBarrett's esophagusHigh Grade Intraepithelial NeoplasiaFemaleEsophagoscopyNuclear medicinebusinessPrecancerous ConditionsGastroenterology
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