Search results for "resolve"
showing 10 items of 258 documents
Bridging Sensing and Decision Making in Ambient Intelligence Environments
2009
Context-aware and Ambient Intelligence environments represent one of the emerging issues in the last decade. In such intelligent environments, information is gathered to provide, on one hand, autonomic and easy to manage applications, and, on the other, secured access controlled environments. Several approaches have been defined in the literature to describe context-aware application with techniques to capture and represent information related to a specified domain. However and to the best of our knowledge, none has questioned the reliability of the techniques used to extract meaningful knowledge needed for decision making especially if the information captured is of multimedia types (image…
Femtosecond Raman time-resolved molecular spectroscopy
2004
International audience; The applicability of several femtosecond time resolved non-linear coherent techniques such as Raman induced polarization spectroscopy (RIPS), degenerate four-wave mixing (DFWM) and coherent anti-Stokes Raman spectroscopy (CARS) for molecular spectroscopy is presented. All methods rely on the initial coherent excitation of molecular states producing wavepackets, whose time evolution is then measured. In the case of RIPS and DFWM only pure rotational transitions are involved, whereas in CARS vibrational states can be excited. First the methodology of concentration and temperature measurements using RIPS in gas mixtures involving N2, CO2, O2, and N2O is shown. In additi…
Effects of the net charge on abundance and stability of supramolecular surfactant aggregates in gas phase
2011
Self-assembling of amphiphilic molecules under electrospray ionization (ESI) conditions is characterized by quite unexpected phenomenology. The noticeable differences with respect to the condensed phase are attributable to the absence of the surfactant-solvent interactions, the presence of net charge in the aggregates, and the strong deviation from equilibrium conditions. Aiming to investigate the effects of the net charge on abundance and stability of supramolecular surfactant aggregates, positively and negatively charged aggregates of sodium bis(2-ethylhexyl)sulfosuccinate (AOT) and sodium methane sulfonate (MetS), butane sulfonate (ButS) and octane sulfonate (OctS) have been studied by E…
Measurement of haemodynamics of exercising and non-exercising vastus lateralis muscle with hybrid diffuse optics
2016
We present simultaneous diffuse correlation spectroscopy (DCS) and time resolved spectroscopy (TR NIRS) measurements on exercising and non-exercising vastus lateralis muscle. We discuss the results at two different exercise levels.
Sensorless control of permanent magnet synchronous motors for wide speed range applications
2006
This paper deals with sensorless control of Interior Permanent Magnet Synchronous Motors (IPMS) based on the estimation of speed and rotor angular position. The above estimate is based on the injection of high frequency stator currents able to generate a signal similar to that generated by a resolver connected to the axis of the motor. A new digital algorithm has been designed to demodulate the above signal whose implementation can be carried out on the same DSP that processes the control algorithm. In this paper a new scheme of speed and angular position estimator is proposed and justified on the theoretic point of view. The experimental results here shown validate the effectiveness of the…
A new method for the study of antiparallel ferroelectric domains
1992
Abstract Beam-coupling topography is a non-destructive holographic technique for spatially resolved recording of hysteresis loops and for imaging of domains. Its basic principle is interference of rays diffracted from a holographic grating with collinear, transmitted ones. Full domain contrast and noise suppression is achieved by appropriate control of intensity and phase of the interfering beams. The method is applied to antiparallel a-domains in (Sr0.61Ba0.39)Nb2O6:Ce.
Effect of S1 Torsional Dynamics on the Time-Resolved Fluorescence Spectra of 9,9‘-Bianthryl in Solution
1997
Time-resolved fluorescence spectra of 9,9‘-bianthryl (BA) were measured in methylcyclohexane (MCH) and a Decalin−isooctane (D−ISOO) mixture at several temperatures between 127 and 200 K. A suitable...
Controlling Spin-Correlated Radical Pairs with Donor-Acceptor Dyads: A New Concept to Generate Reduced Metal Complexes for More Efficient Photocataly…
2021
Abstract One‐electron reduced metal complexes derived from photoactive ruthenium or iridium complexes are important intermediates for substrate activation steps in photoredox catalysis and for the photocatalytic generation of solar fuels. However, owing to the heavy atom effect, direct photochemical pathways to these key intermediates suffer from intrinsic efficiency problems resulting from rapid geminate recombination of radical pairs within the so‐called solvent cage. In this study, we prepared and investigated molecular dyads capable of producing reduced metal complexes via an indirect pathway relying on a sequence of energy and electron transfer processes between a Ru complex and a cova…
Environmental Stewardship, Moral Psychology and Gardens
2013
Vast and pervasive environmental problems such as climate change and biodiversity loss call every individual to active stewardship. Their magnitude and causal and strategic structures, however, pose powerful challenges to our moral psychology. Stewardship may feel overburdening, and appear hopeless. This may lead to widespread moral and political disengagement. This article proposes a resolve to garden practices as a way out of that danger, and describes the ways in which it will motivate individuals to so act as to coordinate on behavioural patterns that will significantly alleviate grave, but seemingly distant and intractable environmental quandaries.
Embedded-atom calculations of Auger and x-ray photoemission shifts for metallic elements
1982
Change in self-consistent-field energy density-functional calculations are reported for Auger and core-level binding-energy shifts in sp-bonded metals. The basic model, atom in jellium vacancy, gives good agreement with experiment, especially in the Auger case. The chemical and relaxation contributions to the shifts are discussed, and the extra-atomic response is analyzed in detail, both in position and energy space. The adequacy of the "excited-atom" approach to the energy shifts is discussed. Peer reviewed