Search results for "rotation"
showing 10 items of 935 documents
Influence of Different DXA Acquisition Modes on Monitoring the Changes in Bone Mineral Density After Hip Resurfacing Arthroplasty
2011
Dual-energy X-ray absorptiometry (DXA) is a technique enabling the measurement of bone mineral density (BMD) around prostheses after hip resurfacing arthroplasty (HRA). In this study, we evaluated the consistency of different DXA acquisition modes with 33 patients who had undergone HRA. Patients were scanned with DXA immediately after surgery and at 3-, 6-, and 12-mo time points. All the patients were scanned with dual femur and orthopedic hip acquisition modes and analyzed using 10-region ROI model. With both acquisition modes, a statistically significant decrease (p0.05, Wilcoxon's test) in BMD at 3mo was revealed in 3 ROIs, located to upper and lateral upper femur. Both acquisition modes…
Short baseline line matching for central imaging systems
2012
We develop a generic line matching method especially applicable to omnidirectional images taken from constructed scenes with short baseline motion where the motion of the imaging system between two views is mainly an arbitrary rotation and the translation of the camera between two views with respect to its distance to the imaged scene is negligible. We start by studying the relationship between images of lines on unitary sphere followed by proposing a simple algorithm for simultaneously matching vanishing points and lines. The developed algorithm is very simple, yet it works on images captured by all types of central imaging systems, including perspective, fish-eye and catadioptric images. …
A Generic Method of Line Matching for Central Imaging Systems under Short-Baseline Motion
2009
Line matching across images taken by a central imaging system (perspective or catadioptric) with focus on short baseline motion of the system is proposed. The relationship between images of lines on unitary sphere is studied and a simple algorithm for matching lines are proposed assuming the rotation of the system is known apriori or it can be estimated from some correspondences in two views. Two methods are discussed for retrieving R in the case it is not known apriori. Experimental results on both synthetic and real images are also presented.
Self-assembled PAA-based nanoparticles as potential gene and protein delivery systems
2012
A series of nanoparticles is prepared via layer-by-layer assembly of oppositely charged, synthetic biocompatible polyamidoamine polymers as potential carriers. Particle size, surface charge and internal chain mobility are quantified as a function of the polymer type and number of layers. The effect of addition of surfactant is examined to simulate the effects of nanoparticle dissolution. The cyctotoxicity of these particles (in epithelia and murine cell lines) are orders of magnitude lower than polyethyleneimine controls. Stable nanoparticles may be prepared from mixtures of strongly, oppositely charged polymers, but less successfully from weakly charged polymers, and, given their acceptabl…
How important is roaming in the photodegradation of nitrobenzene?
2020
At low excitation energies nitrobenzene photoreleases NO with low translational and rotational energy, while at higher excitation energies NO is photoreleased with both low and high translational and rotational energy. The fast products are formed through a singlet-triplet crossing (STC) region featuring an oxaziridine ring, while a ground state roaming mechanism was suggested to produce the slow molecules. Computing translational and rotational energies performing CASSCF classical dynamics, we here prove how the same oxaziridine STC can account for both fast and slow photoproducts, depending on the region of the seam through which the ground state is populated. A roaming-type STC/CI has al…
Helium and Argon Line Broadening in the nu2 Band of CH4
2004
Abstract The spectra of the gaseous mixtures CH 4 –He and CH 4 –Ar were obtained in the spectral region 1400–1750 cm −1 with a resolution up to 0.003 cm −1 . Helium and argon pressure broadenings for the vibration–rotation lines of the ν 2 band of CH 4 have been estimated at room temperature for some lines in the P , Q , and R branches. These values were also calculated using the theoretical approach developed by Robert and Bonamy, extended to the case of tetrahedral molecules. The helium data have been found to be in a satisfactory agreement whereas a divergence of calculated and measured broadening coefficients has been evidenced in the case of argon. Simulations of the ν 2 band shapes of…
Damping of rotor conical whirl by asymmetric dry friction suspension
2009
Abstract A new technique for the rotor whirl damping in rotating machinery, based on the elastic suspension of the journal boxes and the use of dry friction surfaces normal to the shaft axis between their supports and the frame, is here analysed theoretically for several cases of rotor systems characterized by mass and constraint asymmetry, where gyroscopic effects are to be expected and conical whirl motions may grow up. The critical flexural speeds can be easily cut off by an adhesive state of the supports and the whirl amplitude can be minimized as well throughout the remaining sliding range. Confining the operative angular speed of the rotor in the range of adhesive contact between the …
High-resolution stimulated Raman spectroscopy of O2
1992
Abstract The S S and O O branches of the fundamental vibrational band of molecular oxygen in its electronic ground state have been resolved for the first time in Raman spectroscopy. The spectra have been observed, at room temperature and low pressure, with a stimulated Raman scattering (S.R.S.) spectrometer including a multipass cell. From these accurate Raman data combined with microwave data, we have improved the values of the vibrational, rotational, spin-spin, and spin-rotation interactions constants in the v = 1 vibrational state. Moreover, Raman Q branches of the first and second hot-bands have been recorded, allowing us to determine a set of molecular parameters for the v = 2 and v =…
2 H-NMR-Stimulated Echo Study of Ultraslow Reorientational Motion in Viscous Glycerol near Its Glass Transition Temperature
1990
2H-NMR stimulated echo experiments have been performed in order to study the molecular basis of the ?-process in viscous glycerol near its glass transition temperature. Decay functions following modified Jeener-Broekaert pulse sequences were compared with predictions from different models for molecular reorientation. Rotational diffusion, rotational random jumps, rotational fixed-angle jumps and combinations of diffusive and jump motions have been tested. All data are fitted with a log-Gaussian distribution of correlation times. Thereby, small-but finite-angle reorientation processes turn out to dominate in the 10-3 s.. 100 s regime. Pure large-angle rotational jumps can be ruled out with h…
Dynamical heterogeneities of rotational motion in room temperature ionic liquids evidenced by molecular dynamics simulations
2018
Room temperature ionic liquids (RTILs) have been shown to exhibit spatial heterogeneity or structural heterogeneity in the sense that they form hydrophobic and ionic domains. Yet studies of the relationship between this structural heterogeneity and the ∼picosecond motion of the molecular constituents remain limited. In order to obtain insight into the time scales relevant to this structural heterogeneity, we perform molecular dynamics simulations of a series of RTILs. To investigate the relationship between the structures, i.e., the presence of hydrophobic and ionic domains, and the dynamics, we gradually increase the size of the hydrophobic part of the cation from ethylammonium nitrate (EA…