Search results for "rotation"
showing 10 items of 935 documents
Analysis of highly excited 'hot' bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2
2010
International audience; We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, v(2) + 3v(3) - v(2) and 2v(1) + v(2) + v(3) - v(2), of the SO2 molecule. As the first step of the study, the 'cold' bands, 3v(3) and 2v(1) + v(3), are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers J(max.) = 60, K-a(max.) = 19, and J(max.) = 69, K-a(max.) = 20 for the bands 3v(3) and 2v(1) + v(3), respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3v(3) and 2v(1) + v(3) bands, a variational procedure was used that allowed us to assign 230 and 115 transiti…
Modelling of interference fits with taking into account surfaces roughness with homogenization technique
2013
International audience; The assembly technique by shrink fit is increasingly used today because it allows for the assembly of two pieces without any intermediary part simply by the tightening effect given by the difference in diameters of the two parts assembled. The definition of assemblies depends on calculation models available in the standard. They make very restrictive assumptions that limit the geometrical defects and the surface finish. It is increasingly common to use a finite element method to better adapt the model to the complex forms of industrial parts. However, the standard is limited with regard to the consideration of roughness which results in a loss of tightening. An easy …
COBieOWL, an OWL ontology based on COBie standard
2015
International audience; Building Information Modelling (BIM) standards have been recognized by construction and political actors as a highly promising tool for resolving issues of data dematerialization, notably in the field of Architecture, Engineering, Construction and Facility Management. Among worldwide-adopted BIM standards, there is COBie. COBie’s goals are to dematerialize building data and to enhance building information interoperability. Nevertheless, COBie data is available in static formats such as STEP or spreadsheet templates. Such formats lack logical formalisms and semantic features provided by languages such as OWL. Because of this, in this paper, we propose a method for sem…
High-resolution infrared spectroscopy and analysis of the v2=v4 bending dyad and v3 stretching fundamental of ruthenium tetroxide
2017
International audience; RuO4 is a heavy tetrahedral molecule which has practical uses for several industrial fields. Due to its chemicaltoxicity and the radiological impact of its 103 and 106 isotopologues, the possible remote sensing of this compound in theatmosphere has renewed interest in its spectroscopic properties. We investigate here for the first time at high resolutionthe bending dyad region in the far IR and the line intensities in the 3 stretching region. Firstly, new high resolutionFTIR spectra of the bending modes region in the far infrared have been recorded at room temperature, using a speciallyconstructed cell and an isotopically pure sample of 102RuO4. New assignments and e…
Laser induced field-free molecular alignment
2008
Talk given by O. Faucher; International audience
La molécule d'éthylène soumise à des impulsions laser femtosecondes : spectroscopie rotationnelle et alignement
2006
Talk given by B. Lavorel
Control and optimization of postpulse molecular alignment by shaped laser pulse
2008
Talk given by O. Faucher; International audience
Laser induced molecular alignment of ethylene
2007
Talk given by O. Faucher
Alignement moléculaire par impulsions laser ultrabrèves : Mesures & Applications
2009
The interaction of an intense ultrashort laser pulse with a molecular sample leads, after the end of the pulse, to molecular alignment at specific time under field-free conditions. This thesis is dedicated to the measurements and applications of this effect. The degree of alignment is determined through the variation of the refractive index induced by the rearrangement of the molecular dipoles. A two-dimensional technique allowing to measure molecular alignment on a single-shot basis is reported in this document. The alignment is then exploited in order to determine physical quantities which are usually difficult to estimate through others methods. The "cross-defocusing technique" has been …
Différents régimes impulsionnels dans un laser Raman à fibre optique
2008
National audience; Nous rapportons différents régimes impulsionnels observés au sein d'une cavité laser Raman en anneau.