Search results for "rotation"

Saturation effects of Faraday rotation signals in Cs vapor nanocells: thickness-dependent effects.

2008

On the 'expanded local mode' approach applied to the methane molecule: isotopic substitution CH2D2 <--- CH4

2011

International audience; On the basis of a compilation of the 'expanded local mode' model and the general isotopic substitution theory, sets of simple analytical relations between different spectroscopic parameters (harmonic frequencies, anharmonic coefficients, ro-vibrational coefficients, different kinds of Fermi- and Coriolis-type interaction parameters) of the CH2D2 molecule are derived. All of them are expressed as simple functions of a few initial spectroscopic parameters of the mother, CH4, molecule. Test calculations with the derived isotopic relations show that, in spite of a total absence of initial information about the CH2D2 species, the numerical results of the calculations have…

Tensorial development of the rovibronic Hamiltonian and transition moment operators for octahedral molecules

2001

Abstract We present a development of the Hamiltonian, dipole moment and polarizability operators of octahedral XY 6 molecules in a degenerate electronic state. These rovibronic operators are written with the aid of a tensorial formalism derived from the one already used in Dijon in the case of molecules in a non-degenerate electronic state. Electronic operators are defined from the group theory properties. Transition moment operators are introduced in order to consider rovibronic transitions. Spectrum simulations are made thanks to a new version of the HTDS sofware [J. Quant. Spectrosc. Radiat. Transfer 66 (2000) 16] used for the calculation of rovibrational spectra.

Molecular alignment echoes probe collision-induced rotational-speed changes

2020

International audience; We show that the decays with pressure of the rotational alignment echoes induced in N 2 O-He gas mixtures by two ultrashort laser pulses with various delays show detailed information about collision-induced changes of the rotational speed of the molecules. Measurements and classical calculations consistently demonstrate that collisions reduce the echo amplitude all the more efficiently when the echo appears late. We quantitatively explain this behavior by the filamentation of the classical rotational phase space induced by the first pulse and the narrowing of the filaments with time. The above mentioned variation of the echo decay then reflects the ability of collisi…

Etude des effets collisionnels dans les molécules tétraédriques. Applications au méthane perturbé par l'argon

1996

This thesis is devoted to the study of relaxational and collisional line-broadening processes in the first vibrational polyads of tetrahedral molecules. In a first part, the particular internal dynamics of such molecules is discussed. The second chapter reviews the literature on phenomena induced by intermolecular interactions involving this type of molecules. More theoretical aspects are developed in the second part. The so-called tetrahedral tensorial formalism adapted to the construction of Hamiltonians and transition moments of tetrahedral molecules is described. Main features of the infrared line-shapes theories and of semi-classical line-broadening and line-shifting calculations are a…

Evaluation of cropping systems for management of herbicide-resistant populations of blackgrass (Alopecurus myosuroides Huds.)

2001

Abstract Simplification of cropping systems often leads to an increase in weed populations which require an intensive use of herbicides to maintain populations at an acceptable level. Due to a heavy reliance on herbicides and a lack of cultural control measures, herbicide-resistant blackgrass (Alopecurus myosuroides Huds.) biotypes appeared recently in France. An experiment was conducted to evaluate the effects of different cropping systems on a population of herbicide-resistant blackgrass. Two crop rotations, one consisting exclusively of winter crops and another including spring crops, were assessed over a three-year period. Crop rotation was combined with different cultural practices (mo…

Raisonnement des pratiques et des changements de pratiques en matière de désherbage : regards agronomique et sociologique à partir d’enquêtes chez de…

2008

To ensure successful, more sustainable weed management practices, it is crucial to take account of farmer’s decision-making processes. Agronomists revealed that interviewed farmers had complex and various weeding programmes, and that, when designing these programmes, they integrated different time scales: the current year, the rotation, and the long term. They gave some light, too, on the decision-making processes and how it changes over time. Sociologists analyzed the way wine-growers bring about change from the cognitive angle and its bearing on interactive dialogue between the wine-growers themselves as well as with technical advisors

Effect of timing of grassland destruction on nitrogen mineralization kinetics.

2007

International audience

Large-scale distribution of arrival directions of cosmic rays detected above 1018 eV at the Pierre Auger Observatory

2012

A thorough search for large-scale anisotropies in the distribution of arrival directions of cosmic rays detected above 1018 eV at the Pierre Auger Observatory is presented. This search is performed as a function of both declination and right ascension in several energy ranges above 1018 eV, and reported in terms of dipolar and quadrupolar coefficients. Within the systematic uncertainties, no significant deviation from isotropy is revealed. Assuming that any cosmic-ray anisotropy is dominated by dipole and quadrupole moments in this energy range, upper limits on their amplitudes are derived. These upper limits allow us to test the origin of cosmic rays above 1018 eV from stationary Galactic …

The role of slabs and oceanic plate geometry in the net rotation of the lithosphere, trench motions, and slab return flow

2012

International audience; [1] Absolute plate motion models with respect to a deep mantle reference frame (e.g., hot spots) typically contain some net rotation (NR) of the lithosphere. Global mantle flow models for the present-day plate setting reproduce similarly oriented NRs but with amplitudes significantly smaller than those found in some high NR Pacific hot spot reference frames. It is therefore important to understand the mechanisms of NR excitation, which we attempt here with two-dimensional cylindrical models of an idealized Pacific domain. We study the influence of slab properties, oceanic ridge position, continental keels, and a weak asthenospheric layer on NR and trench migration. F…