Search results for "sandwich"
showing 10 items of 62 documents
Diastereoselective Synthesis of Dialkylated Bis(phosphino)ferrocenes: Their Use in Promoting Silver-Mediated Nucleophilic Fluorination of Chloroquino…
2017
International audience; The diastereoselective synthesis of dialkylated ferrocenyl bis(phosphane)s bearing aryl, alkyl, and hetero- or polycyclic substituents on the phosphino groups is reported, together with their characterization in the solid state by X-ray structure analysis and in solution by multinuclear NMR spectroscopy. Introduction of various alkyl groups on the ferrocene backbone, namely, tert-butyl, isopropyl, and trimethylsilyl, has a significant influence on the stereoselectivity of the ensuing lithiation/phosphination reactions. Only the introduction of the tert-butyl groups ensures both a high yield and perfect diastereoselectivity, which leads to the exclusive formation of t…
EXPERIMENTAL AND NUMERICAL EVALUATION OF THE MECHANICAL BEHAVIOUR OF GFRP SANDWICH PANELS
2007
This work deals with the analysis of the mechanical behaviour of a class of sandwich structures widely employed in marine constructions, constituted by fiber-glass laminate skins over PVC foam or polyester mat cores. In detail, a systematic experimental study and numerical simulations have shown that the theoretical prediction of the strength and the actual failure mechanism of these sandwich structures can be affected by significant errors, specially in the presence of prevalent shear loading. Moreover, because of the low shear stiffness and the elastic constants mismatch of the skins and core material, failure modes and strength are strongly influenced by eventual stresses orthogonal to t…
Metallatomsynthese, Eigenschaften und Struktur von μ 2 ‐(η 3 ,η 3 ‐Toluol)bis[(η 6 ‐toluol)eisen](Fe‐Fe)
1995
Metal Atom Synthesis, Properties, and Structure of μ2(η3,η3-Toluene)bis[(η6-toluene)iron](Fe-Fe) Metal atom cocondensation of iron atoms and toluene produces the mononuclear iron sandwich compound [(η6-toluene)(η4-toluene)Fe] 1. Complex 1 reacts with a palette of N-containing ligands such as primary, secondary, and tertiary amines as well as pyridine, pyrrolidine, and tmeda to form highly reactive instable intermediates. In the temperature range from -80 to -30°C, the proposed intermediates react with toluene to form the first homoleptic Fe/toluene complex μ2-(η3η3-toluene)-bis[(η6-toluene)iron](Fe-Fe) (3) regardless which N-containing ligand is used. Additionally, 3 is also formed when eth…
Inferential tools in penalized logistic regression for small and sparse data: A comparative study.
2016
This paper focuses on inferential tools in the logistic regression model fitted by the Firth penalized likelihood. In this context, the Likelihood Ratio statistic is often reported to be the preferred choice as compared to the ‘traditional’ Wald statistic. In this work, we consider and discuss a wider range of test statistics, including the robust Wald, the Score, and the recently proposed Gradient statistic. We compare all these asymptotically equivalent statistics in terms of interval estimation and hypothesis testing via simulation experiments and analyses of two real datasets. We find out that the Likelihood Ratio statistic does not appear the best inferential device in the Firth penal…
The "sandwich technique" for iris-fixated phakic intraocular lens implantation.
2006
ABSTRACT PURPOSE: To describe a new technique of implantation of the Artisan/Verisyse phakic intraocular lens (PIOL). METHODS: After PIOL insertion into the anterior chamber, a bolus of a high viscosity ophthalmic viseosurgical device (OVD) is placed over the optic, separating it widely from the endothelium. RESULTS: The technique decreases the chance of endothelial damage during enclavation. CONCLUSIONS: A bolus of a high viscosity OVD placed on the anterior surface of the Artisan/Verisyse PIOL may make enclavation safer. [J Refract Surg. 2006;22:96-98.]
Forming of aluminum foam sandwich panels: Numerical simulations and experimental tests
2006
Abstract The forming of the completed aluminium foam sandwich (AFS) panels would determine an improvement in the manufacturing of parts and panels. In this paper the authors have investigated the formability of AFS through experiments and numerical simulations. As far as the former are concerned, commercially prepared panels have been considered and bending and stamping processes have been taken into account. In addition, FEM analyses have been developed, utilizing a porous material model following the evolution of the material density throughout the forming processes.
Mechanical behavior of a sandwich with corrugated GRP core: numerical modeling and experimental validation
2014
In this work the mechanical behaviour of a core reinforced composite sandwich structure is studied. The sandwich employs a Glass Reinforced Polymer (GRP) orthotropic material for both the two external skins and the inner core web. In particular, the core is designed in order to cooperate with the GRP skins in membrane and flexural properties by means of the addition of a corrugated laminate into the foam core. An analytical model has been developed to replace a unit cell of this structure with an orthotropic equivalent thick plate that reproduces the in plane and out of plane behaviour of the original geometry. Different validation procedures have been implemented to verify the quality of t…
Stability of solution for Rao-Nakra sandwich beam model with Kelvin-Voigt damping and time delay
2022
This paper deals with stability of solution for a one-dimensional model of Rao?Nakra sandwich beam with Kelvin?Voigt damping and time delay given by ??1?1?????? ? ??1?1?????? ? ??(??? + ?? + ??????) ? ?????????? ? ??????????( ? , ?? ? ??) = 0, ??3?3?????? ? ??3?3?????? + ??(??? + ?? + ??????) ? ?????????? = 0, ????????? + ?????????????? ? ????(??? + ?? + ??????)?? ? ?????????? = 0. A sandwich beam is an engineering model that consists of three layers: two stiff outer layers, bottom and top faces, and a more compliant inner layer called ?core layer?. Rao?Nakra system consists of three layers and the assumption is that there is no slip at the interface between contacts. The top and bottom lay…
Investigation on the behaviour of fully thermoplastic composite sandwich beams under concentrated loads
2009
The recent development of new low cost manufacturing processes adopting thermoplastic matrices in the production of structural long fibre reinforced laminates is fostering an increasing interest towards this class of materials. The automotive sector in particular is attracted by the high energy absorbing, damage tolerance performances and manufacturing and recycling potentials of structural thermoplastic composites. In this study a number of fully thermoplastic sandwich beams have been manufactured in order to investigate flexural and shear rigidity performances as well as the indentation behavior under static concentrated loads.
Bimetallic ruthenium-tin chemistry: synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands
2010
A series of neutral, anionic and cationic arene ruthenium complexes containing the trichlorostannyl ligand have been synthesised from SnCl2 and the corresponding arene ruthenium dichloride dimers [(η6-arene)Ru(μ2-Cl)Cl]2 (arene = C6H6, PriC6H4Me). While the reaction with triphenylphosphine and stannous chloride only gives the neutral mono(trichlorostannyl) complexes [(η6-C6H6)Ru(PPh3)(SnCl3)Cl] (1) and [(η6-PriC6H4Me)Ru(PPh3)(SnCl3)Cl] (2), the neutral di(trichlorostannyl) complex [(η6-PriC6H4Me)Ru(NCPh)(SnCl3)2] (3) could be obtained for the para-cymene derivative with benzonitrile as additional ligand. By contrast, the analogous reaction with the benzene derivative leads to a salt compose…