Search results for "scattering"
showing 10 items of 8332 documents
Formation and growth of palladium nanoparticles inside porous poly(4-vinyl-pyridine) monitored by operando techniques: The role of different reducing…
2017
In this work we followed the formation of palladium nanoparticles, starting from palladium (II) acetate precursor, inside a poly(4-vinylpyridine-co-divinylbenzene) polymer in presence of different reducing agents. The formation and growth of palladium nanoparticles in presence of H-2 was followed as a function of temperature by simultaneous XANES-SAXS techniques, coupled with DRIFT spectroscopy in operando conditions. It was found that the pyridyl functional groups in the polymer plays a fundamental role in the stabilization of the palladium (II) acetate precursor, as well as in the stabilization of the palladium nanoparticles. The effect of a thermal treatment in alcohol (ethanol and 2-pro…
<title>Micro-Raman scattering and infrared spectra of hemoglobin</title>
2008
Confocal micro-Raman and FT-IR spectroscopies have been used for detection of radiation influence of hemoglobin of patients examined by radio-isotopes diagnosis (Tc99m). After irradiation we observed some little changes of the Raman scattering bands which connected with out of plane porphyrine bending vibrations, also we observed additional band due to methemoglobin. Radiation of blood lead to the transition from hemoglobin (Fe2+) to methemoglobin (Fe3+) with a delocalization of iron from porphyrine plane. It was shown that FT-IR spectra indicate the radiation effects on hemoglobin.© (2008) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is per…
Birefringent porous silicon membranes for optical sensing
2012
In this work anisotropic porous silicon is investigated as a material for optical sensing. Birefringence and sensitivity of the anisotropic porous silicon membranes are thoroughly studied in the framework of Bruggeman model which is extended to incorporate the influence of environment effects, such as silicon oxidation. The membranes were also characterized optically demonstrating sensitivity as high as 1245 nm/RIU at 1500 nm. This experimental value only agrees with the theory when it takes into consideration the effect of silicon oxidation. Furthermore we demonstrate that oxidized porous silicon membranes have optical parameters with long term stability. Finally, we developed a new model …
Hydration dependence of myoglobin dynamics studied with elastic neutron scattering, differential scanning calorimetry and broadband dielectric spectr…
2014
In this work we present a thorough investigation of the hydration dependence of myoglobin dynamics. The study is performed on D2O-hydrated protein powders in the hydration range 0<h<0.5 (h≡gr[D2O]/gr[protein]) and in the temperature range 20-300K. The protein equilibrium fluctuations are investigated with Elastic Neutron Scattering using the spectrometer IN13 at ILL (Grenoble), while the relaxations of the protein + hydration water system are investigated with Broadband Dielectric Spectroscopy; finally, Differential Scanning Calorimetry is used to obtain a thermodynamic description of the system. The effect of increasing hydration is to speed up the relaxations of the myoglobin + hydration …
On the effect of the nature of counterions on the self-assembly of polyoxyethylene alkyl ether carboxylic acids
2020
In this contribution, we investigate the effect of the type of counterion on the properties of dilute solutions of polyoxyethylene alkyl ether carboxylic acids. Two different surfactants, presenting an oleic acid alkyl chain and on-average five and nine ethylene oxide units, and terminated by a weakly anionic carboxymethyl group were studied. The surfactants were gradually ionized with sodium hydroxide, arginine, and choline hydroxide. The solutions properties were probed by light scattering, electrophoretic mobility, density and sound velocity measurements, as well as by small-angle neutron scattering. To our initial surprise, no specific effect arising from the nature of the counterion co…
"Table 15" of "Search for heavy particles decaying into a top-quark pair in the fully hadronic final state in $pp$ collisions at $\sqrt{s} =13$ TeV w…
2020
Observed top-quark mass distribution and expected background in Region SR2 Tight 2b after the fit (Post-Fit) under the background-only hypothesis for the boosted analysis.
"Table 12" of "Search for heavy particles decaying into a top-quark pair in the fully hadronic final state in $pp$ collisions at $\sqrt{s} =13$ TeV w…
2020
Observed top-quark mass distribution and expected background in Region SR2 Medium 1b after the fit (Post-Fit) under the background-only hypothesis for the boosted analysis.
"Table 14" of "Search for heavy particles decaying into a top-quark pair in the fully hadronic final state in $pp$ collisions at $\sqrt{s} =13$ TeV w…
2020
Observed top-quark mass distribution and expected background in Region SR2 Tight 1b after the fit (Post-Fit) under the background-only hypothesis for the boosted analysis.
"Table 13" of "Search for heavy particles decaying into a top-quark pair in the fully hadronic final state in $pp$ collisions at $\sqrt{s} =13$ TeV w…
2020
Observed top-quark mass distribution and expected background in Region SR2 Medium 2b after the fit (Post-Fit) under the background-only hypothesis for the boosted analysis.
Multi-parameter analysis of the obstacle scattering problem
2022
Abstract We consider the acoustic field scattered by a bounded impenetrable obstacle and we study its dependence upon a certain set of parameters. As usual, the problem is modeled by an exterior Dirichlet problem for the Helmholtz equation Δu + k 2 u = 0. We show that the solution u and its far field pattern u ∞ depend real analytically on the shape of the obstacle, the wave number k, and the Dirichlet datum. We also prove a similar result for the corresponding Dirichlet-to-Neumann map.