Search results for "shale"
showing 10 items of 45 documents
Black shale deposition during Toarcian super-greenhouse driven by sea level
2013
Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a…
The shear strength of Opalinus Clay shale in the remoulded state
2020
Abstract The Opalinus Clay shale formation is considered as a potential host geomaterial for the Swiss deep geological repository for radioactive waste. It presents different facies and it is characterised by a multi-scale heterogeneous composition, by a typical fissile structure with well-defined bedding planes and by anisotropic hydro-mechanical behaviour. This peculiar complexity makes it difficult to assign a unique set of geomechanical parameters to the material. This paper presents an experimental study aimed at characterising the lowest values of the shear strength parameters. In this sense, the shear behaviour was investigated on remoulded samples where the fabric and the diagenetic…
The impact of the volumetric swelling behavior on the water uptake of gas shale
2018
Abstract Water uptake of gas shales is commonly considered one of the most important factors responsible for fluid loss during flowback operations after hydraulic fracturing. Imbibition experiments cover a key role in this context to analyze the impact of several factors (such as mineralogical composition, fluids composition, anisotropic structure, volumetric swelling) that contribute to the water uptake in these unconventional reservoirs. The aim of this study is the quantification of the impact of the volumetric response (swelling and shrinkage) of gas shales on the water uptake during imbibition and desiccation processes. An experimental methodology to quantify the volumetric response du…
One-dimensional compression and consolidation of shales
2016
This paper presents a comprehensive methodology for analysing the compression and consolidation behaviour of shales. An apparatus was designed to perform oedometric high-pressure tests by applying a maximum vertical total stress of 100 MPa and simultaneously controlling the pore water pressure of the specimen. An analytical method was formulated to analyse the shale consolidation behaviour, which allows information to be gathered on the coefficient of consolidation, stiffness, poroelastic properties, secondary compression and permeability of the tested material as a function of the applied stress conditions. Results obtained on Opalinus Clay shale using the developed methodology are present…
Fabric control on strain and rupture of heterogeneous shale samples by using a non-conventional mechanical test
2004
Abstract This work was a part of the preliminary stage of the ANDRA project on a deep-seated research laboratory for the feasibility study of long-term radioactive waste storage in the Callovo–Oxfordian argillites of the Eastern part of the Paris Basin. These rocks are bedded, their density is about 2.4, and they contain an average of 30% carbonates and 25% quartz. Thick (5 mm) sections from cores were put through a non-conventional device called CGI testcell (CGI: Centre de Geologie de l'Ingenieur, i.e. Engineering Geology Centre). The aim of this versatile device is to achieve plane deformation tests under compressive uniaxial loading together with controlled temperature and humidity cond…
Experimental assessment of the hydro-mechanical behaviour of a shale caprock during CO2 injection
2021
Abstract The presented experimental study focuses on the hydro-mechanical characterisation of a shale caprock (Opalinus Clay) in contact with carbon dioxide. The objective of this paper, consists in the evaluation of the material's sealing capacity in terms of entry-pressure, mechanical behaviour and sensitivity of the transport properties to chemo-mechanical effects induced by gaseous and liquid CO2 injection. Two types of Opalinus Clay core samples are tested; shaly and carbonate-rich. The sealing capacity has been evaluated on the shaly OPA according to the stepwise and the residual methods and compared to the results from mercury intrusion porosimetry. The obtained results and the diffe…
Cr(VI)/Cr(III) and As(V)/As(III) Ratio Assessments in Jordanian Spent Oil Shale Produced by Aerobic Combustion and Anaerobic Pyrolysis
2011
With the increase in the awareness of the public in the environmental impact of oil shale utilization, it is of interest to reveal the mobility of potentially toxic trace elements in spent oil shale. Therefore, the Cr and As oxidation state in a representative Jordanian oil shale sample from the El-Lajjoun area were investigated upon different lab-scale furnace treatments. The anaerobic pyrolysis was performed in a retort flushed by nitrogen gas at temperatures in between 600 and 800 °C (pyrolytic oil shale, POS). The aerobic combustion was simply performed in porcelain cups heated in a muffle furnace for 4 h at temperatures in between 700 and 1000 °C (burned oil shale, BOS). The high loss-…
Discussion on “Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions: Mechanical Properties and the Influence of …
2021
AbstractThe testing procedure and results on saturated samples of Opalinus Clay in the work of Schuster et al. (Rock Mech Rock Eng https://doi.org/10.1007/s00603-021-02474-3, 2021) were conducted and presented using strain rates two to four orders of magnitudes higher than the rates needed to allow pore pressure equilibrium in the material, both in drained and undrained conditions. This leads to an erroneous estimation of the mechanical properties in saturated conditions. We discuss this aspect in the context of shale testing. We also discuss the effect of drying-induced fissuring on the mechanical properties of geomaterials tested in dry conditions.
One dimensional consolidation of Opalinus Clay from shallow depth
2017
First experimental results on Opalinus Clay from shallow depth (< 30 m depth) are presented and compared to results on cores from Mont Terri Underground Rock Laboratory (~ 300 m depth). Samples were tested in one dimensional condition using an advanced experimental technique. The samples from the two sites show similar properties in terms of geotechnical characterization and one dimensional compressibility/swelling indexes, despite the different source depths.
Major and Trace Element Geochemistry of the European Kupferschiefer – An Evaluation of Analytical Techniques
2018
Simple and rapid techniques are needed for routine quantitative chemical bulk-rock analyses of Kupferschiefer, a black shale containing variable amounts of silicates, base metal sulphides, carbonates and an organic content of up to 30 weight percent. In this study, WD-XRF, TXRF, and ICP-OES of acid- as well as peroxide-digested samples were tested as potential techniques based on their availability and adaptability to analyse major (Si, Ti, Al, Mg, Ca, Fe, K, but also Cu, Zn, Pb) and selected trace (Ag, As, Ba, Co, Mo, Ni, V) element concentrations. Because of the absence of a suitable reference material, a comparative study was undertaken using instrumental neutron activation analysis to a…