Search results for "shell"

The study of neutron-rich nuclei production in the region of the closed shell N=126 in the multi-nucleon transfer reaction 136Xe+208Pb

2015

Expérience LNL/PRISMA; International audience; The unexplored area of heavy neutron rich nuclei is extremely important for nuclearastrophysics investigations and, in particular, for the understanding of the r-process ofastrophysical nucleogenesis. For the production of heavy neutron rich nuclei located along theneutron closed shell N=126 (probably the last "waiting point" in the r-process of nucleosynthesis)the low-energy multi-nucleon transfer reaction 136Xe+208Pb at Elab=870MeV was explored.Due to the stabilizing eect of the closed neutron shells in both nuclei, N=82 and N=126, andthe rather favorable proton transfer from lead to xenon, the light fragments formed in this processare well b…

Hydration dependent dynamics in sol-gel encapsulated myoglobin.

2008

In this work we study the effect of hydration on the dynamics of a protein in confined geometry, i.e. encapsulated in a porous silica matrix. Using elastic neutron scattering we investigate the temperature dependence of the mean square displacements of non-exchangeable hydrogen atoms of sol-gel encapsulated met-myoglobin. The study is extended to samples at 0.2, 0.3 and 0.5 g water/g protein fractions and comparison is made with met-myoglobin powders at the same average hydration and with a dry powder sample. Elastic data are analysed using a model of dynamical heterogeneity to take into account deviations of elastic intensity from gaussian behaviour in a large momentum transfer range and r…

Collective features of Cr and Fe isotopes

2014

The question of the sudden increase of collectivity in neutron-rich nuclei when approaching N = 40 has recently interested both experimentalists and theorists. In this paper we study the development of collectivity along the chromium and iron isotopic chains. The calculations are performed within two different perspectives, namely, the proton-neutron interacting boson model (IBM-2) and interacting shell model (ISM) and compared with the available experimental data. The onset of collectivity is studied through nuclear quantities and observables that suggest differences in the nuclear structure of Cr and Fe isotopical chains. Furthermore, a prediction for the shape transition from a spherical…

Ultrastructure of the Interlamellar Membranes of the Nacre of the Bivalve Pteria hirundo, Determined by Immunolabelling.

2015

The current model for the ultrastructure of the interlamellar membranes of molluscan nacre imply that they consist of a core of aligned chitin fibers surrounded on both sides by acidic proteins. This model was based on observations taken on previously demineralized shells, where the original structure had disappeared. Despite other earlier claims, no direct observations exist in which the different components can be unequivocally discriminated. We have applied different labeling protocols on non-demineralized nacreous shells of the bivalve Pteria. With this method, we have revealed the disposition and nature of the different fibers of the interlamellar membranes that can be observed on the …

The Al 50 Cp* 12 Cluster – A 138‐Electron Closed Shell ( L = 6) Superatom

2011

Metal clusters stabilized by a surface ligand shell represent an interesting intermediate state of matter between molecular metal-ligand complexes and bulk metal. Such "metalloid" clusters are characterized by the balance between metal-metal bonds in the core and metal-ligand bonds at the exterior of the cluster. In previous studies, the electronic stability for the Al50Cp*(12) cluster was not fully understood. We show here that the known cluster Al50Cp*(12) can be considered as an analogue to a giant atom ("superatom") with 138 sp electrons organized in concentric angular momentum shells up to L = 6 symmetry.

Nature of Bonding in Group 13 Dimetallenes: a Delicate Balance between Singlet Diradical Character and Closed Shell Interactions

2010

The nature of metal-metal bonding in group 13 dimetallenes REER (E = Al, Ga, In, Tl; R = H, Me, (t)Bu, Ph) was investigated by use of quantum chemical methods that include HF, second order Møller-Plesset perturbation theory (MP2), coupled cluster (CCSD(T)), complete active space with (CASPT2) and without (CAS) second order perturbation theory, and two density functionals, namely, B3LYP and M06-2X. The results show that the metal-metal interaction in group 13 dimetallenes stems almost exclusively from static and dynamic electron correlation effects: both dialuminenes and digallenes have an important singlet diradical component in their wave function, whereas the bonding in the heavier diinde…

Quaternary Heusler Compounds without Inversion Symmetry: CoFe 1+ x Ti 1– x Al and CoMn 1+ x V 1– x Al

2011

We report the quaternary Heusler compound derivatives CoFe1+xTi1–xAl and CoMn1+xV1–xAl, which do not have centers of inversion. Classical T2T′M (T, T′ = transition metal, M = main group element) Heusler compounds (prototype: Cu2MnAl) crystallize in the L21 structure, space group Fmm (225) that exhibits a center of inversion. Replacing one of the T2 atoms by another transition element (T″) results in a quaternary TT′T″M compound with F3m symmetry (Y; structure type LiMgPdSn) without center of inversion. In the case of “quasi closed shell” compounds with 24 valence electrons in the primitive cell, one expects the absence of ferromagnetism according to the Slater–Pauling rule. Increasing the n…

Front Cover: Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model (Eur. J. Inorg. Chem. 31/2018)

2018

Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model

2018

An invasive species may be better than none: invasive signal and native noble crayfish have similar community effects

2014

14 pages; International audience; Human activities have resulted in the decline of native crayfish and promoted the spread of invasive crayfish species in European fresh waters, threatening ecosystem structure and functioning. We compared effects of native noble crayfish (Astacus astacus), invasive signal crayfish (Pacifastacus leniusculus) and of the absence of crayfish on leaf litter breakdown and invertebrate prey density and biomass in stream ecosystems. In microcosm experiments, invertebrate shredder density was significantly reduced by crayfish presence but similarly affected by the two crayfish species. While crayfish did not directly influence leaf litter breakdown, their presence r…