Search results for "shell"
showing 10 items of 748 documents
Self-assembly of semiflexible polymers confined to thin spherical shells
2018
Confinement effects are critical for stiff macromolecules in biological cells, vesicles, and other systems in soft matter. For these molecules, the competition between the packing entropy and the enthalpic cost of bending is further shaped by strong confinement effects. Through coarse-grained molecular dynamics simulations, we explore the self-assembly of semiflexible polymers confined in thin spherical shells for various chain lengths, chain stiffnesses, and shell thicknesses. Here, we focus on the case where the contour and persistence length of the polymers are comparable to the radius of the confining cavity. The range of ordered structures is analyzed using several order parameters to …
Local structure and dynamics of wurtzite‐type ZnO from simulation‐based EXAFS analysis
2014
Conventional methods of EXAFS data analysis are often limited to the nearest coordination shells of the absorbing atom due to the difficulties in accurate accounting for the so-called multiple-scattering effects. Besides, it is often difficult to resolve the non-equivalent groups of atoms in a single coordination shell due to strong correlation between structural parameters. In this study we overcome these problems by applying two different simulation-based methods, i.e., classical molecular dynamics (MD) and reverse Monte with evolutionary algorithm (EA), to the analysis of the Zn K-edge EXAFS data for wurtzite-type bulk ZnO. The RMC/EA-EXAFS method allowed us to separate the contributions…
Quantum and carbon dots conjugated molecularly imprinted polymers as advanced nanomaterials for selective recognition of analytes in environmental, f…
2021
Abstract Samples with complex matrix analyzed during explanation of pathogenesis of various diseases and food or environmental monitoring request advanced analytical and instrumental devices. Among the materials used for described purposes, quantum (QDs) or carbon dots (CDs) layered by molecularly imprinted polymer (MIP) shells have gained widespread attention. Unique optical and physicochemical properties of QDs/CDs together with high MIPs selectivity make the QD/CD-MIP conjugates capable of adsorbing specific target molecules – such a binding event is then transduced as the optical signal of the response by the QDs/CDs. This review includes brief introduction on principles of imprinting p…
Bivalve mollusks shells valorisation and recycling: market potentiality and novel building products
2023
Construction is a fundamental driver of the world economy, recognized as a sector that generates a great contribution to the social and economic development. At the same time, it shows an enormous environmental impact through an unstoppable consumption of non-renewable resources, a high energy consumption, and an associated atmospheric emission of pollutant. Consequently, the research and development of novel and green production processes and sustainable building materials is of paramount importance. The sustainability of materials and production processes could be improved by enhancing and reusing wastes from various industrial sectors. In this paper, the fishery sector will be analysed, …
One-piece micropumps from liquid crystalline core-shell particles
2012
Responsive polymers are low-cost, light weight and flexible, and thus an attractive class of materials for the integration into micromechanical and lab-on-chip systems. Triggered by external stimuli, liquid crystalline elastomers are able to perform mechanical motion and can be utilized as microactuators. Here we present the fabrication of one-piece micropumps from liquid crystalline core-shell elastomer particles via a microfluidic double-emulsion process, the continuous nature of which enables a low-cost and rapid production. The liquid crystalline elastomer shell contains a liquid core, which is reversibly pumped into and out of the particle by actuation of the liquid crystalline shell i…
Costanti e metamorfosi di un mito. Beatrice Cenci nell'Ottocento, da Shelley a Guerrazzi e oltre.
2011
Il saggio ripercorre la trasformazione in mito letterario della storia di Beatrice Cenci, le la sua straordinaria fortuna nel romanzo e nel teatro europei, con riferimento particolare alla sua presa sulla sensibilità romantica e inoltre al suo ruolo nell'immaginario risorgimentale. The essay deals with the transformation of Beatrice Cenci’ story in a literary myth, with special reference to its impact on the romantic sensitivity, on the collective imagination of Italian Risorgimento, and in the works by Shelley, Stendhal, Dumas and Guerrazzi,
Collectivity along N=50: Nuclear Structure studies on the neutron-magic nuclei 92Mo and 94Ru with AGATA and VAMOS++
2019
El trabajo desarrollado en esta Tesis se centra en estudio experimental del comportamiento colectivo de los estados excitados de los núcleos semimágicos con N=50 en función de la ocupación del orbital g9/2 de protones, a través de la medida de la vida media de los estados "yrast" 4+ de los núcleos 92Mo y 94Ru. En particular, se ha investigado la conservación de "seniority" a lo largo de la capa g9/2 que es la primera capa donde podría no conservarse. El 100Sn, siendo el núcleo doblemente mágico ligado más pesado con igual número de protones y neutrones, ha atraído siempre un considerable interés desde el punto de vista experimental y teórico. La estructura de este núcleo y sus vecinos son e…
Single-neutron orbits near Ni-78: Spectroscopy of the N=49 isotope Zn-79
2015
5 pags., 6 figs.
Mass measurements towards doubly magic Ni-78 : Hydrodynamics versus nuclear mass contribution in core-collapse supernovae
2022
International audience; We report the first high-precision mass measurements of the neutron-rich nuclei 74,75Ni and the clearly identified ground state of 76Cu, along with a more precise mass-excess value of 78Cu, performed with the double Penning trap JYFLTRAP at the Ion Guide Isotope Separator On-Line (IGISOL) facility. These new results lead to a quantitative estimation of the quenching for the N=50 neutron shell gap. The impact of this shell quenching on core-collapse supernova dynamics is specifically tested using a dedicated statistical equilibrium approach that allows a variation of the mass model independent of the other microphysical inputs. We conclude that the impact of nuclear m…
High-resolution records of growth temperature and life history of two Nacella limpet species, Tierra del Fuego, Argentina
2020
Stable isotope ratios in patelloid limpets of the genus Patella have been established as proxies for coastal environmental change at sub-monthly resolution along the eastern North Atlantic and Mediterranean Sea. Nacella deaurata (Gmelin, 1791) and N. magellanica (Gmelin, 1791) are common intertidal species of patelloid limpets inhabiting the coast of Tierra del Fuego, Argentina/Chile and are commonly found in Holocene archaeological deposits. Here, we examine oxygen and carbon isotope ratios (δ18Oshell and δ13Cshell, respectively) of modern specimens of N. deaurata and N. magellanica to test the hypotheses that: 1) they form their shells in isotopic equilibrium with ambient water; and 2) pr…