Search results for "sol"
showing 10 items of 23782 documents
A survey on models for the prediction of phase equilibria in polymer solutions
2011
Realization of polyaspartamide-based nanoparticles and in vivo lung biodistribution evaluation of a loaded gucocorticoid after aerosolization in mice
2016
Abstract In this study, novel polymeric nanoparticles (NPs) were developed and their potential as carriers for beclomethasone dipropionate (BDP) into the lung after aerosolization was demonstrated by in vivo studies in mice. In particular, these NPs were obtained starting from two polyaspartamide-based copolymers which were synthesized by chemical reaction of α,β-poly(N-2-hydroxyethyl)- dl -aspartamide (PHEA) and its pegylated derivative (PHEA-PEG2000) with poly(lactic acid) (PLA). To obtain nanosized particles, the high pressure homogenization (HPH)—solvent evaporation method was followed by using an organic phase containing both PHEA-PLA and PHEA-PEG2000-PLA (at a weight ratio equal to 1:…
Synthesis of oxide-supported vanadium catalysts and their activity in ethylene polymerization
1999
The activity of oxide-supported vanadium-based catalyst systems (VOCl 3/Et 2AlCl) in low-pressure ethylene polymerization and the properties of the resulting polyethylenes were studied in relation to the type and mode of modification of the oxide support. Alumina, silica and an un"conventional silica-type material prepared by the sol-gel process were used as supports. Results are compared with those obtained earlier with a catalyst supported on MgCl 2(THF) 2. Of the oxides studied, the silica-type sol-gel material dehydrated and subsequently modified with Et 2AlCl proved to be the best carrier for a vanadium catalyst. The polyethylene prepared by using this catalyst support was found to exh…
Presentación defensa tesis doctoral la legitimación del cooperativismo y la economía social y solidaria en las políticas públicas de iberoamérica. el…
2016
El material hace referencia a la presentación utilizada durante la lectura y defensa de la tesis doctoral correspondiente.
In Vitro Evaluation of Poly(lactide-co-glycolide) In Situ Forming Gels for Bedaquiline Fumarate Salt and Pharmacokinetics Following Subcutaneous Inje…
2021
This study evaluated in vitro and in vivo drug release of bedaquiline from in situ forming gels (ISGs) containing 200 mg eq./g bedaquiline fumarate salt prepared with four different grades of poly(d,l-lactide) (PDLLA) or poly(d,l-lactide-co-glycolide) (PLGA) with a lactide/glycolide ratio of 50/50 or 75/25 and acid (A) or ester (E) end-capping in N-methyl-2-pyrrolidone at a polymer/solvent ratio of 20/80% (w/w). Mean in vitro drug release in 0.05 M phosphate buffer pH 7.4 with 1% (w/v) sodium lauryl sulphate was 37.3, 47.1, 53.3, and 62.3% within 28 days for ISGs containing PLGA5050A, PDLLA, PLGA7525A, and PLGA7525E, respectively. The data suggested that drug release was primarily controlle…
Inside Cover: Hydrogen-Bonded Open-Framework with Pyridyl-Decorated Channels: Straightforward Preparation and Insight into Its Affinity for Acidic Mo…
2017
International audience; A hydrogen-bonded open framework with pores decorated by pyridyl groups was constructed by off-charge-stoichiometry assembly of protonated tetrakis(4-pyridyloxymethyl)methane and [Al(oxalate)(3)](3-), which are the H-bond donor and acceptor of ionic H-bond interactions, respectively. This supramolecular porous architecture (SPA-2) has 1nm-large pores interconnected in 3D with large solvent-accessible void (53%). It demonstrated remarkable affinity for acidic organic molecules in solution, which was investigated by means of various carboxylic acids including larger drug molecules. Competing sorption between acetic acid and its halogenated homologues evidenced good sel…
Città-porto a prova di futuro. Linee guida per l’integrazione di soluzioni basate sulla natura per l’adattamento climatico e la tutela della biodiver…
2023
Quale è il ruolo della pianificazione nel rispondere alle sfide della crisi climatica e della perdita di biodiversità nei contesti urbano-portuali? Il lavoro di ricerca costituisce un avanzamento del dibattito sulla riqualificazione delle aree portuali, contesti storicamente avulsi dalla considerazione di tematiche legate alla preservazione e valorizzazione degli habitat naturali e degli ecosistemi. La tesi desidera mettere al centro della discussione le città porto mediterranee come ecosistemi e come insediamenti urbani multi-specie, come attrici del cambiamento responsabile di fronte alle crisi e non soltanto nodi infrastrutturali strategici per l’economia, la finanza e gli usi militari. …
The pentafluorophenyl group as π-acceptor for anions: a case study
2015
Chemical science 6(1), 354-359 (2015). doi:10.1039/C4SC02762K
Two positive solutions for a nonlinear parameter-depending algebraic system
2021
The existence of two positive solutions for a nonlinear parameter-depending algebraic system is investigated. The main tools are a finite dimensional version of a two critical point theorem and a recent weak-strong discrete maximum principle.
Oscillation of Second-Order Neutral Differential Equations
2013
Author's version of an article in the journal: Funkcialaj Ekvacioj. Also available from the publisher at: http://www.math.kobe-u.ac.jp/~fe/ We study oscillatory behavior of a class of second-order neutral differential equations relating oscillation of these equations to existence of positive solutions to associated first-order functional differential inequalities. Our assumptions allow applications to differential equations with both delayed and advanced arguments, and not only. New theorems complement and improve a number of results reported in the literature. Two illustrative examples are provided.