Search results for "solu"
showing 10 items of 7577 documents
Structural and magnetic properties of the solid solution series Sr2Fe1–xMxReO6(M = Cr, Zn)
2005
Strong correlations between the electronic, structural and magnetic properties have been found during the study of doped double perovskites Sr2Fe1−xMxReO6 (0 ≤ x ≤ 1, M = Zn, Cr). The interplay between the van Hove singularity and the Fermi level plays a crucial role for the magnetic properties. Cr doping of the parent compound Sr2FeReO6 leads to a non-monotonic behaviour of the saturation magnetization and an enhancement for doping levels up to 10%. The Curie temperatures monotonically increase from 401 to 616 K. In contrast, Zn doping leads to a continuous decrease in the saturation magnetization and the Curie temperatures. Superimposed on the electronic effects is the structural influenc…
Heat-induced charge transfer in cobalt iron cyanide
2006
The heating of Co(2+) ferricyanide above 801C induces an inner charge transfer from Co(2+) towards Fe(III) to form the mixed valence system Co(2+)Co(III) ferri- ferro-cyanide. This charge transfer takes place preserving the material framework and forming a solid solution of the initial and final species. The cell edge of the cubic cell (Fm-3m) of this solid solution follows a regular variation with
Ar dabas aizsardzību saistīto terminu lietojums uzņēmumu mājas lapu tekstos
2021
Uzņēmumi savās mājas lapās var izmantot ar dabas aizsardzību (DA) saistītus terminus, lai sabiedrība tos uztvertu noteiktā veidā. Šī bakalaura darba mērķis ir analizēt DA terminu lietojumu desmit izvēlētu uzņēmumu mājas lapu tekstos, kas ņemti no piecām dažādām nozarēm. Galvenās pētījuma metodes ir literatūras apskats, absolūtā biežuma analīze un diskursa analīze. Dati parāda, ka automašīnu ražotāji savās mājaslapās izmanto visvairāk DA terminu, savukārt apģērbu firmas izmanto vismazāk DA terminu. Lielākā daļa atrasto DA terminu ir lietvārdi. Tiek secināts, ka uzņēmumus, kas savās mājaslapās lielākoties izmanto DA terminus no „vides risinājumu” kategorijas, var uztvert kā dabai draudzīgākus…
Photo-polymerized lauryl methacrylate monolithic columns for CEC using lauroyl peroxide as initiator
2009
Lauryl methacrylate (LMA)-ester based monolithic columns photo-polymerized using lauroyl peroxide (LPO) as initiator were prepared, and their morphological and CEC properties were studied. The composition of the polymerization mixture (i.e. ratios of monomers/porogenic solvents, 1,4-butanediol/1-propanol and LMA/crosslinker) was optimized. The morphological and chromatographic properties of LMA columns were evaluated by means of SEM pictures and van Deemter plots of PAHs, respectively. The polymerization mixture selected as optimal provided a fast separation of a mixture of PAHs with excellent efficiencies (minimum plate heights of 8.9-11.1 μm). Satisfactory column-to-column (RS D < 4.5%) a…
Simultaneous optimization of mobile phase composition, column nature and length to analyse complex samples using serially coupled columns
2013
Abstract The combination of the selectivity of different columns serially coupled improves the separation expectancies with regard to the separation offered by each single column. In the reported approaches, either a pre-selected isocratic mobile phase composition or gradient program, giving rise to acceptable retention, is used. In previous work (JCA 1281 (2013) 94), we showed that the approach succeeds with conventional columns, assembled through zero-dead volume couplers. In this work, the simultaneous interpretive optimization of mobile phase composition and column nature and length, based on a limited number of experimental data, is demonstrated. This approach allows an impressive redu…
Vanadium Carbide Dissolution during Austenitisation of a Model Microalloyed FeCV Steel
2005
High performance commercial micro alloyed steels contain elements such as vanadium, which leads to a fine dispersion of vanadium carbide precipitates. The precipitation state, in terms of volume fraction and size distribution, plays a significant role in final mechanical properties of the material. Different austenitisation heat treatments were performed on a model ternary alloy FeCV. Precipitation states were characterised combining different experimental techniques. TEM was used to identify the chemical composition of observed precipitates. ICP mass spectroscopy was performed to measure the volume fraction of precipitates. The size distribution was studied by SEM. Results are characterist…
Organic solvent vapor effects on phase transition of α and β tegafur upon grinding with solvent additives.
2012
Abstract Solvent effects on α tegafur (5-fluoro-1-(tetrahydro-2-furyl)uracil) phase transition to β tegafur during grinding with solvent additive, as well as phase transition in samples exposed to 95% relative solvent vapor pressure has been studied in this research. Samples containing 0.5% and 0.1% of β tegafur in α and β tegafur mixture, as well as samples of pure α tegafur were ground with different solvent additives, and conversion degrees depending on the solvent were determined using PXRD method. Samples with α and β tegafur weight fraction of 1:1 were exposed to 95% relative solvent vapor pressure, and phase transition rates were determined. Solubility of α tegafur, solvent sorption …
(Vapour + liquid) equilibria of (water + dimethylformamide): application of the headspace-gas chromatography for the determination of thermodynamic i…
1998
Abstract Isothermal measurements of the partial vapour pressures have been carried out on {water + dimethylformamide (DMF)} at temperatures betweenT=305.15 K andT=323.15 K using an apparatus composed of a headspace sampler and a normal gas chromatograph. These data were simultaneously evaluated in one step with respect to the (composition dependent, integral) Flory-Huggins interaction parametergby means of a new method which minimizes the Gibbs energy of mixing and does not require chemical potentials. The expression forggiven by Koningsveld and Kleintjens, originally designed for polymer solutions, describes the present results best.
PNA
2009
Bernardo.Gomez@uv.es; Mauricio.Contreras@uv.es Este artículo presenta parte de un estudio que persigue analizar el efecto de las variables de problema y las variables de resolución de problemas en las respuestas de estudiantes de segundo ciclo de educación secundaria obligatoria cuando resuelven problemas multiplicativos de división de fracciones. Se recoge aquí un análisis histórico-epistemológico que ha dado cuenta de los valores de dichas variables y, a partir de resultados preliminares, se sugiere la existencia de interrelaciones entre las variables de problema y las variables de resolución. This article presents part of a study aiming to analyze the effect of problem and problem solvin…
Natural and anthropogenic influences on the geochemistry of Quaternary lake sediments from Holzmaar, Germany
1997
The accumulation of heavy metals and trace elements has been investigated in a well laminated sequence of Holocene and late Pleistocene lake sediments composed of diatomaceous gyttja, tuff and silt and clay sediments. Varve chronology of the annually deposited gyttja yielded a continuous high-resolution time sequence and allowed the absolute age dating of the sediment. Fluxes of elements remained largely uniform from the late Pleistocene into the Holocene. Higher trace element and heavy metal fluxes occur from 2322 to 862 VT years ago (VT: varve time, years before 1950) and reached their maxima in the uppermost sediments (<845 VT years ago). These increasing element fluxes correlate with in…