Search results for "solu"

High resolution study of the SO2 infrared spectra: calculation scheme for assignment of transitions in very weak ro-vibrational bands.

2009

Identification of hexanuclear Actinide(IV) carboxylates with Thorium, Uranium and Neptunium by EXAFS spectroscopy

2012

International audience; Hydrated actinide(IV) ions undergo hydrolysis and further polymerization and precipitation with increasing pH. The resulting amorphous and partly crystalline oxydydroxides AnO(n)(OH)(4-2n)center dot xH(2)O can usually be observed as colloids above the An(IV) solubility limit. The aging process of such colloids results in crystalline AnO(2). The presence of carboxylates in the solution prevents the occurrence of such colloids by formation of polynuclear complexes through a competing reaction between hydrolysis and ligation. The majority of recently described carboxylates reveals a hexanuclear core of [An(6)(mu(3)-O)(4)(mu(3)-OH)(4)](12+) terminated by 12 carboxylate l…

Towards enhanced durability of electrochromic WO3 interfaced with liquid or ceramic sodium-based electrolytes

2020

Abstract The reversible intercalation of sodium ion into tungsten oxide WO3 appears as an interesting alternative to hydrogen or lithium ion reduction in order to get the characteristic transition from clear transparent to bluish coloration in electrochromic devices, but it has been comparatively less considered. In order to address further viable all-ceramic devices based on sodium ion intercalation and overcome the issue of WO3 degradation in aqueous media, three configurations of WO3 thin film-based electrochromic half-cells were tested, namely in (i) aqueous acidified Na2SO4 electrolyte, (ii) room temperature ionic liquid BEPipTFSI electrolyte and (iii) aqueous acidified Na2SO4 electrol…

Rational solutions to the mKdV equation associated to particular polynomials

2021

International audience; Rational solutions to the modified Korteweg-de Vries (mKdV) equation are given in terms of a quotient of determinants involving certain particular polynomials. This gives a very efficient method to construct solutions. We construct very easily explicit expressions of these rational solutions for the first orders n = 1 until 10.

Response of Chlamydomonas reinhardtii to Herbicides: Negative Relationship Between Toxicity and Water Solubility Across Several Herbicide Families

2002

International audience

Laboratory leaching studies of oryzalin and diuron through three undisturbed vineyard soil columns

2004

Article de revue (Article scientifique dans une revue à comité de lecture); International audience; The leaching of diuron and oryzalin through undisturbed soil columns was studied in the laboratory using three vineyard soils from Vosne-Romanée (Burgundy): a rendosol, a calcosol and a vegetated calcosol. After 845 mm of simulated rainfall in 15 days, soil leachates contained higher amounts of diuron (3.2%, 11.8% and 18.8% of applied diuron, respectively) than oryzalin (0.2%, 4.9%, 3.7%, respectively). A greater proportion of soil extractable residues was obtained for diuron (42.5%, 26.8% and 32.2%, respectively) than for oryzalin (14.7%, 12% and 15.5%, respectively). The greater mobility of…

Système de prise d'images haute résolution pour l'analyse de projection de particules : application à l'épandage centrifuge d'engrais

2002

This paper describes the design of a high resolution low cost imaging system for the analysis of high speed particle projection. This system, based on a camera and a set of flashes, is used to characterize the centrifugal spreading of fertilizer particles ejected at speeds of environ 30 m s. Multiexposure images collected with the camera installed perpendicular to the output flow of granules are analysed to estimate the trajectories of the fertilizer granules. Very good results are obtained with the Markov random fields method, in comparison with others.

Mapping intra-plot topsoil diversity of Burgundy vineyards (Aloxe- Corton, France) from very high spatial resolution (VHSR) images

2012

International audience; In this work, we present a method based on very high spatial resolution (VHSR) aerial images acquired in the visible domain and that map soil surface diversity at the hillslope scale with a spatial resolution of a few centimeters. This method combines aerial VHSR image classification with local soil sampling. Principal component analysis (PCA) and non-supervised classification was performed on image characteristics to define soil surface characteristic classes (SSC). Then soil surface mapping was combined with soil surface descriptions and soil profiles to define soil types by physical and chemical characteristics.

Task-specific ionic liquid for the depolymerisation of starch-based industrial waste into high reducing sugars

2014

Development of a simple route for the catalytic conversion of starch-based industrial waste (potato peels) and potato starch into reducing sugars was investigated in two ionic liquids for comparison – 1-allyl-3-methylimidazolium chloride [AMIM]Cl and 1-(4-sulfobutyl)-3-methylimidazolium chloride [SBMIM]Cl. Over a two hour period, a 20 wt% solution containing up to 43% and 98% of reducing sugars at low temperature in aqueous [SBMIM]Cl was achieved for the starch-based waste and the potato starch, respectively. In addition, the use of microwave and low frequency ultrasound to perform the depolymerisation of the raw starch-based material was explored and compared with conventional heating proc…

Variabilité intra-saisonnière et multi-décennale de la téléconnexion entre les pressions de surface (100°W–50°E ; 30°–70°N) et les ENSO/LNSO (1873–19…

2000

Abstract The relationships between an index of the NINO3.4 region and the wintertime sea level pressure (hereafter SLP) anomalies on the extratropical North Atlantic and the bordering areas (100°W–50°E; 30°–70°N) are studied for 1873–1996. This study emphasizes the need of a careful pooling of months and the multi-decadal variability of the ENSO/LNSO influence on the extratropical North Atlantic. We calculate the mean monthly climate anomalies for the 20 warmest and the 20 coldest NINO3.4 (170°–120°W; 5°N–5°S) years from October to March. The composite of SLP anomalies for the 20 warmest NINO3.4 years shows an anomalous trough centered near 30°W in November–December, and positive (respectiv…