Search results for "solu"
showing 10 items of 7577 documents
Crystal structure of (R)-6-fluoro-2-[(S)-oxiran-2-yl]chroman
2015
The title compound, C11H11FO2, is a building block in the synthesis of the active pharmaceutical ingredient DL-nebivolol. The synthesis starting from the enantiomerically pure (R)-6-fluoro-4-oxo-3,4-dihydro-2H-chromene-2-carboxylic acid resulted in a mixture of two stereoisomers, namely (R)-6-fluoro-2-[(S)-oxiran-2-yl]chroman and (R)-6-fluoro-2-[(R)-oxiran-2-yl]chroman. The mixture was separated by column chromatography but only one stereoisomer crystallized. The X-ray structure analysis revealed that the solid consisted of theR,Sisomer. A similar procedure was repeated for (S)-6-fluoro-4-oxo-3,4-dihydro-2H-chromene-2-carboxylic acid and, in this case, theS,Risomer was produced as a crystal…
A Simple Complex on the Verge of Breakdown: Isolation of the Elusive Cyanoformate Ion
2014
Cyanide Hitches a Ride Cyanide is a by-product of the biosynthesis of ethylene in plants and it has been somewhat puzzling how the ion is safely removed before it can shut down enzymatic pathways by coordination to catalytic iron centers. A proposed mechanism has implicated the cyanoformate ion—essentially, a weak adduct of cyanide and carbon dioxide—as the initial product, although its lifetime was uncertain. Murphy et al. (p. 75 ; see the Perspective by Alabugin and Mohamed ) crystallized this previously elusive adduct and found that its solution-phase stability varies inversely with the dielectric properties of the medium. The results bolster a picture in which the adduct shuttles the cy…
Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetramethyl-3a,6,7,7a,3′a,6′,7′,7′a-octahydro-4,4′-bi[1,3-benzodioxolyl…
2017
The absolute configuration,i.e.(3aR,3′aR,7aS,7′aS), of the title compound, C18H26O4, synthesizedviaa palladium-catalyzed homocoupling reaction, was determined on the basis of the synthetic pathway and was confirmed by X-ray diffraction. The homocoupled molecule is formed by two chemically identical moieties built up from two five- and six-membered fused rings. The supramolecular assembly is controlled mainly by C—H...O interactions that lead to the formation of hydrogen-bonded chains of molecules along the [001] direction, while weak dipolar interactions and van der Waals forces hold the chains together in the crystal structure.
Crystal structure and absolute configuration of (4S,5R,6S)-4,5,6-trihydroxy-3-methylcyclohex-2-enone (gabosine H)
2017
The absolute configuration of the title compound, determined as 4S,5R,6S on the basis of the synthetic pathway, was confirmed by single-crystal X-ray diffraction. The molecule is formed by a substituted six-membered cyclohexene ring adopting an envelope conformation and substituted by carbonyl, methyl and hydroxyl groups. The supramolecular structure is mainly built by a combination of O—H⋯O and weaker C—H⋯O hydrogen bonds.
Characterization of spatial porosity and mineral distribution of crystalline rock using X-ray micro computed tomography, C-14-PMMA autoradiography an…
2019
The spatial porosity and mineral distribution of geological materials strongly affects transport processes in them. X-ray micro computed tomography (X-mu CT) has proven to be a powerful tool for characterizing the spatial mineral distribution of geological samples in 3-D. However, limitations in resolution prevent an accurate characterization of pore space especially for tight crystalline rock samples and 2-D methods such as C-14-polymethylmethacrylate (C-14-PMMA) autoradiography and scanning electron microscopy (SEM) are needed. The spatial porosity and mineral distributions of tight crystalline rock samples from Aspo, Sweden, and Olkiluoto, Finland, were studied here. The X-mu CT were use…
Dissident bodies: bodies in resistance from art and feminism
2017
Resumen A lo largo de este artículo pretendemos mostrar cómo diferentes mujeres artistas han utilizado su cuerpo como un lienzo de expresión. Sus cuerpos disidentes, abiertos y llevados al extremo serán sujeto de representación y de autoafirmación, a través de los cuales empoderarse y resistir frente a las consideradas verdades absolutas patriarcales, según las cuales, las mujeres han sido representadas como objetos de placer para la miradas masculinas. Abstract Throughout this article we intend to show how different women artists have used their body as a canvas of expression. Their dissident bodies, opened and taken to the extreme, will be subject of representation and self-affirmation, t…
Il danno da risoluzione
2013
This work aimed to demonstrate that termination’s retroactive effect, under the Italian system, no longer allows to consider the contract as a source of performance rights. Therefore, the contract should only be contemplated historically as a failed transaction, or rather, as a damage for the aggrieved party. Thus, such a party should be entitled to recover reliance damages, such as wasted expenditures and loss of chance, and not performance damages, i.e. the value of the performance of the contract. This study constituted a double challenge, as, first, the prevalent idea, under the Italian system, is that after termination for breach of contract the party aggrieved has the right to perform…
Track finding at Belle II
2021
Computer physics communications 259, 107610 (2021). doi:10.1016/j.cpc.2020.107610
Monitoring water and carbon fluxes at fine spatial scales using HyspIRI-like measurements
2012
Remotely sensed observations in the visible to the shortwave infrared (VSWIR) and thermal infrared (TIR) regions of the electromagnetic spectrum can be used synergistically to provide valuable products of land surface properties for reliable assessments of carbon and water fluxes. The high spatial, spectral and temporal resolution VSWIR and TIR observations provided by the proposed Hyperspectral - InfraRed (HyspIRI) mission will enable a new era of global agricultural monitoring, critical for addressing growing issues of food insecurity. To enable predictions at fine spatial resolution (<100m), modeling efforts must rely on a combination of high-frequency temporal and highresolution spa…
Integration of high resolution spatial and spectral data acquisition systems to provide complementary datasets for cultural heritage applications
2010
International audience; Modern optical measuring systems are able to record objects with high spatial and spectral precision. The acquisition of spatial data is possible with resolutions of a few hundredths of a millimeter using active projection-based camera systems, while spectral data can be obtained using filter-based multispectral camera systems that can capture surface spectral reflectance with high spatial resolution. We present a methodology for combining data from these two discrete optical measuring systems by registering their individual measurements into a common geometrical frame. Furthermore, the potential for its application as a tool for the non-invasive monitoring of painti…