Search results for "spectrum"

Stereoselective Synthesis and Pharmacological Evaluation of 2,4-Bridged Piperidine Derivatives Designed to Activate the κ-Opioid Receptor

2021

Spectrum and energy efficient solutions for OFDMA collaborative wireless networks

2013

Efficient Conversion of Light to Chemical Energy : Directional, Chiral Photoswitches with Very High Quantum Yields

2020

Abstract Photochromic systems have been used to achieve a number of engineering functions such as light energy conversion, molecular motors, pumps, actuators, and sensors. Key to practical applications is a high efficiency in the conversion of light to chemical energy, a rigid structure for the transmission of force to the environment, and directed motion during isomerization. We present a novel type of photochromic system (diindane diazocines) that converts visible light with an efficiency of 18 % to chemical energy. Quantum yields are exceptionally high with >70 % for the cis–trans isomerization and 90 % for the back‐reaction and thus higher than the biochemical system rhodopsin (64 %). T…

The Born–Oppenheimer equilibrium bond distance of GeO from millimetre- and submillimetre-wave spectra and quantum-chemical calculations

2014

The millimetre- and submillimetre-wave spectra of the five common isotopologues of (GeO)-O-16 in their electronic and vibrational ground state have been recorded in the spectral region 115-732GHz; for (GeO)-Ge-74-O-16, the rotational spectrum in the v = 1 state has been detected as well. Exploiting the high precision of the measurements, the Born-Oppenheimer breakdown parameter Delta(Ge)(01) could be determined from a Dunham analysis of the spectral data, whereas Delta(O)(01) was obtained from quantum-chemical calculations, because of the lack of high-precision measurements for the (GeO)-O-18 isotopologues. From the rotational equilibrium constant, the Born-Oppenheimer equilibrium distance …

Rotational spectrum of silyl chloride: hyperfine structure and equilibrium geometry

2012

The Lamb-dip technique was employed to record the rotational spectra of two isotopic species of silyl chloride, namely (28)SiH3Cl and (29)SiH3Cl, in order to investigate their hyperfine structure. High-accuracy quantum-chemical computations were employed to predict the hyperfine parameters involved and to support the experimental investigation. Analysis of the experimental spectra led to an improvement in the accuracy of the known spectroscopic constants as well as allowed us to determine additional spectroscopic parameters for the first time. Furthermore, the equilibrium structure of silyl chloride was reinvestigated using both theoretical and experimental data. The best theoretical and se…

Sexual Dysfunctions and Their Association with the Dual Control Model of Sexual Response in Men and Women with High-Functioning Autism

2019

Adults with an Autism Spectrum Disorder (ASD) are characterized by impairments in social interaction and communication, repetitive and stereotyped interests and behaviours as well as hyper- and/or hyposensitivities. These disorder specific symptoms could be associated with the development of sexual disorders. The Dual Control Model of Sexual Response presents one approach that is frequently used to explain the emergence of sexual dysfunctions. The aim of the present study was to assess the extent of symptoms of sexual dysfunctions in men and women with ASD and to evaluate their association with the individual propensity of sexual excitation and inhibition as defined by the Dual Control Mode…

Diseño físico-matemático de un espectrómetro óptico

2016

[EN] This work presents the design and construction of a spectrometer made in the laboratory and the development of mathematical models needed to process and analyze the acquired spectrum. For modeling functions it has been used LabVIEW program. The aim is to bring this type of instrumentation to engineering students from both, physical and mathematical point of view. The application has been successfully integrated in the learning strategies of the course Sensores Fisicos, Master Universitario en Sensores Para Aplicaciones Industriales at the Universitat Politecnica de Valencia. As an example, we have characterized different light sources emitting in different regions of the electromagneti…

Gas chromatographic and mass spectrometric characterization of the organic acids extracted from some preparations containing lyophilized royal jelly.

2009

Thirty-five aliphatic acids were identified by gas chromatography-mass spectrometry from the ether extract of commercial preparations containing lyophilized royal jelly. The article presents linear-programmed retention indices on capillary columns with non-polar and low-polar stationary phases and mass spectra for identified compounds which were not characterized earlier by these parameters. Nine compounds are reported for the first time as royal jelly constituents.

Transverse momentum distributions for exclusive $\varrho^{0}$ muoproduction

1992

We have studied transverse momentum distributions for exclusive rho(0) muoproduction on protons and heavier nuclei at 2 < Q2 < 25 GeV2. The Q2 dependence of the slopes of the p(t)2 and t' distributions is discussed. The influence of the non-exclusive background is investigated. The p(t)2-slope for exclusive events is 4.3 +/- 0.6 +/- 0.7 GeV-2 at large Q2. The p(t)2 spectra are much softer than inclusive p(t)2 spectra of leading hadrons produced in deep inelastic scattering.

On the discreet spectrum of fractional quantum hydrogen atom in two dimensions

2019

We consider a fractional generalization of two-dimensional (2D) quantum-mechanical Kepler problem corresponding to 2D hydrogen atom. Our main finding is that the solution for discreet spectrum exists only for $\mu>1$ (more specifically $1 < \mu \leq 2$, where $\mu=2$ corresponds to "ordinary" 2D hydrogenic problem), where $\mu$ is the L\'evy index. We show also that in fractional 2D hydrogen atom, the orbital momentum degeneracy is lifted so that its energy starts to depend not only on principal quantum number $n$ but also on orbital $m$. To solve the spectral problem, we pass to the momentum representation, where we apply the variational method. This permits to obtain approximate analytica…