Search results for "spectrum"
showing 10 items of 2043 documents
Efficient transfer of positrons from a buffer-gas-cooled accumulator into an orthogonally oriented superconducting solenoid for antihydrogen studies
2012
Positrons accumulated in a room-temperature buffer-gas-cooled positron accumulator are efficiently transferred into a superconducting solenoid which houses the ATRAP cryogenic Penning trap used in antihydrogen research. The positrons are guided along a 9 m long magnetic guide that connects the central field lines of the 0.15 T field in the positron accumulator to the central magnetic field lines of the superconducting solenoid. Seventy independently controllable electromagnets are required to overcome the fringing field of the large-bore superconducting solenoid. The guide includes both a 15° upward bend and a 105° downward bend to account for the orthogonal orientation of the positron accu…
Masstodon : a tool for assigning peaks and modeling electron transfer reactions in top-down mass spectrometry
2019
Abstract: Top-down mass spectrometry methods are becoming continuously more popular in the effort to describe the proteome. They rely on the fragmentation of intact protein ions inside the mass spectrometer. Among the existing fragmentation methods, electron transfer dissociation is known for its precision and wide coverage of different cleavage sites. However, several side reactions can occur under electron transfer dissociation (ETD) conditions, including nondissociative electron transfer and proton transfer reaction. Evaluating their extent can provide more insight into reaction kinetics as well as instrument operation. Furthermore, preferential formation of certain reaction products can…
Influence of a specific aquatic adapted physical activity in a child with Autism Spectrum Disorders: A case study
2019
Aquatic environment offers an exciting and motivating place for children and aquatic exercise programs provide an appropriate setting for early educational interventions in individuals with autism spectrum disorders (ASD). The purpose of this study was to examine the effects of a specific Multi-systemic Aquatic Therapy (CI-MAT) on gross motor and adaptive skills in a child with ASD. The study was divided into three phases: baseline, 12-week CI-MAT program and Post-Test. Child was administered a battery of tests incorporating anthropometric measurements, gross motor development test (TGM test), Vineland Adaptive Behavior Scales (VABS) and Psychoeducational Profile (PEP-3) before and after a …
Theoretical electronic spectra of 2-aminopurine in vapor and in water
2006
The accurate quantum chemical CASSCF and CASPT2 methods combined with a Monte Carlo procedure to mimic solvation effects have been used in the calculation of the spectroscopic properties of two tautomers of 2-aminopurine (2AP). Absorption and emission spectra have been simulated both in vacuum and in aqueous environment. State and transition energies and properties have been obtained with high accuracy, leading to the assignment of the most important spectroscopic features. The lowest-lying 1 (,*) ( 1 La) state has been determined as responsible for the first band in the absorption spectrum and also for the strong fluorescence observed for the system in water. The combined approach used in …
Halogen-containing BODIPY derivatives for photodynamic therapy
2019
Abstract Two iodinated (1 and 2) and two brominated (3 and 4) BODIPY-based photosensitizers are prepared and characterized using slightly modified synthetic procedures previously described. 1–4 present intense absorption bands in the 510–540 nm interval and very weak emissions due to the presence of halogen atoms in their structure. Irradiation of aqueous solutions of 1–4 with visible light (wavelength > 475 nm) induce the generation of singlet oxygen with quantum yields of ca. 0.62–0.66 for the photosensitizers containing iodine atoms (1 and 2) and of ca. 0.16–0.21 for the brominated counterparts (3 and 4). In vitro studies carried out with HeLa, SCC-13 and HaCaT cell lines and the four ph…
CORRELATION BETWEEN SPECTRAL, SEM/EDX AND ELECTROCHEMICAL PROPERTIES OF MAYA BLUE: A CHEMOMETRIC STUDY*
2009
Visible spectra, composition from SEM/EDX and solid-state electrochemical data are correlated for a set of 12 Maya Blue samples from different archaeological sites of Campeche and Yucatan (Mexico). In addition to indigo and dehydroindigo, indirubin and other possibly indigo-type compounds can be detected in Maya Blue samples. Application of hierarchical cluster analysis techniques allows similarity relationships to be established between samples from different sites, confirming prior results which suggest that the preparation of Maya Blue pigment evolved with time during the Maya culture following a ramified scheme.
Broadband dielectric spectroscopy of 0.4PMN-0.3PSN-0.3PZN ceramics
2007
In this paper, results of the broadband dielectric spectroscopy of 0.4PbMg1/3Nb2/3O3-0.3PbZn1/3Nb2/3O3-0.3PbSc1/2Nb1/2O3(0.4PMN-0.3PZN-0.3PSN) are presented. Dielectric spectra of these solutions were investigated in a broad frequency range from 20 Hz to 100 GHz. Very strong and broad dielectric relaxation was analyzed in terms of distribution of relaxations times, using Tichonov regularization method. It revealed slowing down of the longest relaxation and the mean relaxation times in the agreement with the Vogel-Fulcher law and the Arrhenius law, respectively.
Phonon coupling of non-bridging oxygen hole center with the silica environment: Temperature dependence of the 1.9 eV emission spectra
2008
Abstract We report an experimental study on the shape of the 1.9 eV emission associated with non-bridging oxygen hole centers in silica and its temperature dependence, from 4 up to 300 K, under visible and ultraviolet excitation. Our analysis points out that these defects are coupled with their environment by phonons whose contribution can be described by the single mode of mean frequency between 300–400 cm −1 and Huang–Rhys factor of ∼3. On increasing the temperature, the luminescence intensity undergoes a thermal quenching caused by non-radiative processes, its deviation from a pure Arrhenius law can be accounted for by an uniform distribution of activation energy, from 0.002 to 0.05 eV. …
Speciation and oxidation kinetics of arsenic in the thermal springs of Wiesbaden spa, Germany.
2001
Since 1886 arsenic has been known to be present as a trace component in the Wiesbaden thermal waters at concentrations of over 100 microg L(-1). In this study for the first time molecular level speciation of arsenic was measured both in the water (by HG-AAS) and in wellstone scale deposits (by XANES). Most of the arsenic in the anoxic NaCl-type waters is in the reduced arsenite form. Hydrous ferric oxide (HFO) precipitates in the scale deposits scavenge only the minor dissolved arsenate portion which is, however, accumulated up to 3% w/w. Isothermal precipitation experiments at in-situ temperatures showed a difference between the progress of both arsenic and iron oxidation and precipitation…
Error-Based Interference Detection in WiFi Networks
2017
In this paper we show that inter-technology interference can be recognized by commodity WiFi devices by monitoring the statistics of receiver errors. Indeed, while for WiFi standard frames the error probability varies during the frame reception in different frame fields (PHY, MAC headers, payloads) protected with heterogeneous coding, errors may appear randomly at any point during the time the demodulator is trying to receive an exogenous interfering signal. We thus detect and identify cross-technology interference on off-the-shelf WiFi cards by monitoring the sequence of receiver errors (bad PLCP, bad PCS, invalid headers, etc.) and develop an Artificial Neural Network (ANN) to recognize t…