Search results for "speleothem"

Hydrogeochemistry and fractionation pathways of Mg isotopes in a continental weathering system: Lessons from field experiments

2012

Abstract The potential of magnesium isotope records from cave carbonate archives (speleothems) has been documented but remains underexplored. This is due to the limited knowledge regarding the complex suite of physico-chemical and biological disequilibrium fractionation processes affecting meteoric fluids in the soil zone, the carbonate hostrock and calcite precipitation in the cave. This study presents δ 26  Mg data from a monitored cave in Germany (Bunker Cave) including rain water (δ 26  Mg: − 0.70 ± 0.14‰), soil water (δ 26  Mg: − 0.51 ± 0.10‰) and drip waters (δ 26  Mg: − 1.65 ± 0.08‰) sampled between November 2009 and May 2011. Field precipitation experiments, i.e., calcite precipitat…

Textural features and isotope geochemistry of the Scillato travertine (north-central Sicily): genetic implications.

2015

The travertine deposit, outcropping near the Scillato town (north-central Sicily), was originated by precipitation of calcium carbonate from the Scillato springs, documented as bicarbonate-enriched waters due to dissolution of the Madonie mountains carbonate rocks. This deposit is today well represented by the Travertine Cave, essentially constituted by stalactites and stalagmites in which travertine typically appears laminated with alternation of light and dark laminae. Mineralogical analysis have revealed the almost exclusive presence of calcite and observation under the polarized-light microscope showed different textural features, like presence of debris and porous portions, micritic po…

Disequilibrium carbon and oxygen isotope fractionation in recent cave calcite: Comparison of cave precipitates and model data

2013

Abstract Speleothem proxy data provide important information in continental palaeo-climate research due to their precise chronology and wide geographic distribution. Despite a continuously growing number of field and numerical studies designed to study stable isotope fractionation effects, many aspects remain a matter of debate. Here, carbon and oxygen isotope ratios from cave drip water and calcite precipitates sampled on watch glasses in the Bunker Cave (Western Germany) are compared with the values expected for isotopic equilibrium. Furthermore, the field data are compared with the results of a numerical model simulating stalagmite growth and stable isotope ratios. Two drip sites with di…

Are oxygen isotope fractionation factors between calcite and water derived from speleothems systematically biased due to prior calcite precipitation …

2021

Abstract The equilibrium oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) is an important quantity in stable isotope geochemistry and allows in principle to infer temperature variations from carbonate δ18O if carbonate formation occurred in thermodynamic equilibrium. For this reason, many studies intended to determine the value of the oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) for a wide range of temperatures using modern cave calcite and the corresponding cave drip water or ancient speleothem carbonate and fluid inclusion samples. However, the picture that emerges from all of these studies indicates that speleothem calcite i…

The effects of drip rate and geometry on the isotopic composition of speleothems: Evaluation with an advection-diffusion-reaction model

2022

Abstract The curvature and slope of speleothem surfaces have been shown to affect the reaction rates in the aqueous carbonate system by altering the thickness of the CaCO3-precipitating solution. However, the effects of speleothem geometry and drip rate on the speleothem’s carbon and oxygen isotopic composition have yet to be investigated. Over more strongly sloping surfaces, solutions are thinner and flow faster. The effects of thinner and faster-flowing solutions on the isotopic composition of carbonate minerals precipitated from these solutions are of opposite sense. Thinner solutions enhance rates of CO2 degassing and mineral formation, increasing the degree of isotopic distillation of …

SISALv2: a comprehensive speleothem isotope database with multiple age–depth models

2020

Characterizing the temporal uncertainty in palaeoclimate records is crucial for analysing past climate change, correlating climate events between records, assessing climate periodicities, identifying potential triggers and evaluating climate model simulations. The first global compilation of speleothem isotope records by the SISAL (Speleothem Isotope Synthesis and Analysis) working group showed that age model uncertainties are not systematically reported in the published literature, and these are only available for a limited number of records (ca. 15 %, n = 107/691). To improve the usefulness of the SISAL database, we have (i) improved the database’s spatio-temporal coverage and (ii) create…

Physicochemical characteristics of drip waters: Influence on mineralogy and crystal morphology of recent cave carbonate precipitates

2014

Speleothems are one of the most intensively explored continental archives for palaeoclimate variability. The parameters, however, that control speleothem petrography and its changes with time and space, specifically calcite crystal morphology and carbonate mineralogy, are still poorly understood. In order to shed light on processes and their products, precipitation experiments of recent carbonate crystals on watch glasses and glass plates were performed in seven selected caves. Drip water sites were analysed for their fluid Mg/Ca molar ratio, pH, degree of saturation for calcite and aragonite and drip rates. Corresponding precipitates were analysed with respect to their mineralogy, calcite …

Geoconservation in Sicily (Italy): the Example of the Isola delle Femmine (Palermo)

2022

Abstract The Regional Administration of Sicily recently erected Isola delle Femmine—a small island of the Tyrrhenian Sea, close to Palermo—as a geosite. A detailed geological survey has been carried out in order to define the most important geological features of the island together with the development of a new geological map based on topographic data and a digital model at 1:2.000 scale specially processed. Finally, a geological pathway through the island has been traced and illustrated. The geological substrate of Isola delle Femmine consists of a Mesozoic carbonate succession belonging to the Panormide Carbonate Platform. Two lithostratigraphic units have been differentiated. The lowest…

2019

Abstract. Here, we present the first quantitative speleothem record of lignin oxidation products (LOPs), which has been determined in a Holocene stalagmite from the Herbstlabyrinth Cave in central Germany. In addition, we present LOP results from 16 months of drip water monitoring. Lignin is only produced by vascular plants and therefore has the potential to be an unambiguous vegetation proxy and to complement other vegetation and climate proxies in speleothems. We compare our results with stable isotope and trace element data from the same sample. In the stalagmite, LOP concentrations show a similar behavior to P, Ba and U concentrations, which have previously been interpreted as vegetatio…

2020

Abstract. A compilation of the published literature on dust content in terrestrial and marine sediment cores was synchronized with pollen data and speleothem growth phases on the Greenland Ice Core Chronology 2005 (GICC05) time axis. Aridity patterns for eight key areas of the global climate system have been reconstructed for the last 60 000 years. These records have different time resolutions and different dating methods, i.e. different types of stratigraphy. Nevertheless, all regions analysed in this study show humid conditions during early Marine Isotope Stage 3 (MIS3) and the early Holocene or deglaciation, but not always at the same time. Such discrepancies have been interpreted as reg…