Search results for "square"
showing 10 items of 1317 documents
Simultaneous Kinetic Determination of Carbamate Pesticides after Derivatization withp-Aminophenol by Using Partial Least Squares
1996
Abstract A method has been developed for the fast spectrophotometric determination of propoxur, carbaryl, and ethiofencarb in water samples using injection analysis in the stopped-flow mode. The method is based on the reaction between p -aminophenol and the phenolic compounds obtained from the pesticides, after a previous hydrolysis with 0.05 M NaOH at room temperature for 15 min. The partial least-squares treatment of the spectrophotometry kinetic data provides a simultaneous determination of the three carbamate pesticides assayed with a relative accuracy error lower than 5% in complex mixtures also containing formetanate, which is only partially hydrolyzed under the experimental condition…
Biopartitioning micellar chromatography to pedict mutagenicity of aromatic amines
2007
[EN] Mutagenicity is a toxicity endpoint associated with the chronic exposure to chemicals. Aromatic amines have considerable industrial and environmental importance due to their widespread use in industry and their mutagenic capacity. Biopartitioning micellar chromatography (BMC), a mode of micellar liquid chromatography that uses micellar mobile phases of Brij35 in adequate experimental conditions, has demonstrated to be useful in mimicking the drug partitioning process into biological systems. In this paper, the usefulness of BMC for predicting mutagenicity of aromatic amines is demonstrated. A multiple linear regression (MLR) model based on BMC retention data is proposed and compared wi…
Factors affecting Nigerian teacher educators’ technology integration : Considering characteristics, knowledge constructs, ICT practices and beliefs
2020
To provide a diverse comprehension of teachers' TPACK (Technological, Pedagogical, and Content Knowledge) and how TPACK is reflected in practice, this study examined teacher educators' (TEs') conceptions of technology integration. Specifically, the main objective of the study was to investigate the factors influencing Nigerian teacher educators' technology integration using a self-completion survey administered to Nigerian teacher educators from three schools in the southern region of Nigeria. We utilized the partial least squares structural equation modeling (PLS-SEM) approach for the data analysis. Two frameworks—TPACK and Second Information Technology in Education Study (SITES)— guided t…
Multi-technique approach for qualitative and quantitative characterization of furazidin degradation kinetics under alkaline conditions
2016
Degradation of drug furazidin was studied under different conditions of environmental pH (11-13) and temperature (30-60°C). The novel approach of hybrid hard- and soft-multivariate curve resolution-alternating least squares (HS-MCR-ALS) method was applied to UV-vis spectral data to determine a valid kinetic model and kinetic parameters of the degradation process. The system was found to be comprised of three main species and best characterized by two consecutive first-order reactions. Furazidin degradation rate was found to be highly dependent on the applied environmental conditions, showing more prominent differences between both degradation steps towards higher pH and temperature. Complim…
Prediction of Ductile Fractures Occurrence in Deep Drawing of Square Boxes
1996
Abstract The authors propose a new approach for the prediction of tearing in the deep drawing process of square boxes. Such an approach is based on a damage mechanics formulation and in particular on the yield condition for damaging materials proposed by Tvergaard and Needleman and on a strain controlled nucleation model. The flow rule associated to the yield condition is introduced in a finite element explicit formulation founded on the solution of the dynamic equilibrium equation and on an explicit time integration scheme. By this way the developed model allows to calculate the void volume fraction value during the deep drawing process of square boxes and consequently to predict the insur…
Comparison of Metrics for the Classification of Soils Under Variable Geometrical Conditions Using Hyperspectral Data
2008
International audience; The objective of this letter is to find a distance metric between reflectance spectra that is not sensitive to the variations on the soil reflectance induced by the geometry of solar-view angles. This is motivated by the fact that differences between spectra measured for the same soil under different observation and illumination configurations can lead to misclassifications. Using 26 soils of different compositions simulated with Hapke’s model and 92 soils of different compositions measured under 28 solarview angle geometries in laboratory conditions, we tested three metrics, namely, root-mean-square error, spectral angle mapper, and R2 (the coefficient of determinat…
Comparison of metrics to remove the influence of geometrical conditions on soil reflectance
2007
The objective of this work is to find the best metric to ignore the variations of soil reflectance induced by the solar-view angles geometry. Differences between spectra measured for the same soil under different observation and illumination configurations can leads to misclassifications. Using ninety two soils of different composition measured under twenty eight solar- view angles geometries, we tested 3 metrics : RMSE, SAM, R2 (the coefficient of determination) and we compared their performances. The best metric seems to be the coefficient of determination with 93 % of good classifications.
Prediction of soil texture distributions using VNIR-SWIR reflectance spectroscopy
2013
Abstract Reflectance spectroscopy provides an alternate method to non-destructively characterize key soil properties. Different approaches, including chemometrics techniques or specific absorption features, have been proposed to estimate soil properties from visible and near-infrared (VNIR, 400-1200 nm) and shortwave infrared (SWIR, 1200-2500 nm) reflectance domains. The main goal of this study was to test the performance of two distinct methods for soil texture estimation by VNIR-SWIR reflectance measurements: i) the Continuum Removal (CR) technique that was used to correlate specific spectral absorption features with clay, silt and sand content, and ii) the Partial Least-Squares Regressio…
Pheromone-induced olfactory memory in newborn rabbits: Involvement of consolidation and reconsolidation processes.
2009
Mammary pheromone (MP)-induced odor memory is a new model of appetitive memory functioning early in a mammal, the newborn rabbit. Some properties of this associative memory are analyzed by the use of anisomycin as an amnesic agent. Long-term memory (LTM) was impaired by anisomycin delivered immediately, but not 4 h after either acquisition or reactivation. Thus, the results suggest that this form of neonatal memory requires both consolidation and reconsolidation. By extending these notions to appetitive memory, the results reveal that consolidation and reconsolidation processes are characteristics of associative memories of positive events not only in the adult, but also in the newborn.
Construction and stability of a close-packed structure observed in thin colloidal crystals
2007
We have characterized a close-packed structure of confined charged colloidal spheres, which has been recently discovered. Using different microscopy experiments, the vertically arranged hexagonal planes of n - hcp perpendicular are found to continuously evolve from the horizontally oriented stacks of n hexagonal planes (nDelta) following the maximum packing criterion, but discontinuously transform to a stack of n+1 square planes [(n+1)[SHAPE OF A SQUARE]]. Large mechanically stable domains with threefold twin structures are regularly observed in the suspended state at packing fractions between 0.4 and 0.58.