Search results for "stabilité"
showing 10 items of 27 documents
Pas de titre en anglais
2010
Within the quick nano-fabrication techniques evolution and the increasing needs in low space and energy opto-electronic functions on-chip integration, studies and control of electromagnetic resonances of sub-micrometric objects are crucial issues. One aim of this work was then to improve our knowledge of the light-matter interaction. To this end, optical near-field experiments and complementary numerical development of models have been performed to study electromagnetic resonances due to light-matter interaction in sub-micrometric resonators. As an introduction, the first part of the manuscript presents the main phenomena involved in near-field optical microscopy and the used SNOM operation…
Chemical and dimensional evolution of cationic ions exchange resins in cement pastes
2013
Ion exchange resins (IERs) are widely used by the nuclear industry to decontaminate radioactive effluents. After use they are usually encapsulated in cementitious materials. However, the solidified waste forms can exhibit a strong expansion, possibly leading to cracking. Its origin is not well understood as well as the conditions when it occurs.In this work, the interactions between cationic resins in the Na+ or Ca2+ form and tricalcium silicate (C3S), Portland cement (CEM I) or Blastfurnace slag cement (CEM III/C) are investigated at an early age in order to gain a better understanding of the expansion process.The results show that during the hydration of a paste of C3S or CEM I containing…
Impact of konjac glucomannan on interactions aroma compound - potato starch in a hydrated gel
2016
The objective of this study is to demonstrate that the presence of konjac glucomannan (KGM) in a potato starch matrix enhances its physical stability without inhibiting the molecular encapsulation of aroma compounds by amylose. For that purpose, the two selected polysaccharides are from plant tubers, abundant in nature.Starch is known to interact with volatile compounds either by trapping in amorphous phase or by forming inclusion complexes. This phenomenon is called molecular encapsulation. However, at high water content, these starchy matrices exhibit syneresis that can be harmful to the stability of the aroma compounds trapping over time. KGM has the ability to form highly viscous soluti…
ultra-short pulse propagation at 160-Gb/s in dispersion managed optical fiber lines
2004
This thesis presents a study on ultra-short pulse propagation at 160-Gb/s in dispersion managed optical fiber lines. In a first part, we describe the experimental design of a SHG-FROG setup able to characterize high repetition rate pulse trains. Secondly, we demonstrate the efficiency of multiple four wave mixing phenomenon for the generation of a 160-GHz pulse train through the compression of a sinusoidal beat-signal. Then, in order to compare the experimental and theoretical results, we present the development of an optical fiber characterization benchtop based on modulational instability. In the last part of this thesis, we built and compare several recirculating loop setups. On the one …
Scattering resonances and Pseudospectrum : stability and completeness aspects in optical and gravitational systems
2022
The general context of this thesis is an effort to establish a bridge between gravitational andoptical physics, specifically in the context of scattering problems using as a guideline concepts andtools taken from the theory of non-self-adjoint operators. Our focus is on Quasi-Normal Modes(QNMs), namely the natural resonant modes of open leaky structures under linear perturbationssubject to outgoing boundary conditions. They also are referred to as scattering resonances.In the conservative self-adjoint case the spectral theorem guarantees the completeness andspectral stability of the associated normal modes. In this sense, a natural question in the non-self-adjoint setting refers to the char…
Incidence du passage obligatoire aux normes comptables IAS / IFRS sur le risque d'instabilité bancaire
2011
In this thesis, we study the economic consequences, in terms of instability, of the mandatory IAS/IFRS adoption in the banking industry. The thesis is organized as follows. In a first part (Chapter I), we develop a theoretical framework whose purpose is to understand the mechanisms through which the mandatory IAS/IFRS adoption by banks may influence the probability of occurrence of a banking crisis. At this stage, we show that several arguments, derived from the contractual and informational perspectives of accounting, can be mobilized in order to justify the hypothesis that the mandatory IAS/IFRS adoption has a positive or a negative influence on banking stability. The second part of the t…
Link between microbial diversity, stability of microbial communities and soil organic matter turnover
2014
Soil microbial communities act as important agents of the biological soil functioning, particularly through their involvements in the transformations of biogeochemical cycles (C, N, P…). In agro-ecosystems, the diversity of these communities is affected by perturbations associated to agricultural practices, and the significance of these modifications in terms of preservation of biological functioning and sustainability of agricultural systems has emerged as a central issue in the environmental sciences. Whereas the role of biodiversity has been well studied for macroorganisms, in particular for plants; the biodiversity/activity relationship is still largely unknown for soil microorganisms. …
La ratification en trompe-l'il du TSCG en France
2013
International audience
Synthesis of mesoporous silica nanoparticles (MSNs) and encapsulation of cisplatin for targeted cancer therapies
2014
The aim of this PhD thesis is to elaborate mesoporous silica nanoparticles (MSNs) able to sustain the release of cisplatin into the intracellular compartments of solid tumors. The parametric study shows that morphological, structural and textural properties of MSNs-MCM-41, synthesized by sol-gel reaction by using TEOS as a silica source and CTAB as a structure-directing agent, depend on pH, stirring speed, temperature and extraction process of CTAB. The synthesis atmosphere has to be controlled in order to avoid the presence of ethanol and carbonate species which are responsible of necks between particles generating unstable suspensions of MSNs.MSNs were functionalized in order to control t…
From equilibrium to chaos and back : methodological evaluation of research of the majority rule
2000
According to the canonical model situated at the heart of the " economic " - or, as the political scientists prefer to call it, rational-choice - theory of (democratic) politics, whenever the matter to be decided raises, or consists of, at least two distinct issues, it is generally impossible to reach a determinate decision by using the majority rule. This problem, referred to as that of disequilibrium, equilibrium instability, or even"chaos", was first underplayed and then deemed ominous to the point of seriously undermining the development prospects of the whole theory. However, more recently, the concern it was the source o f until the 1980s has given way to a state of renewed confidence…