Search results for "stacking"
showing 10 items of 215 documents
Unprecedented pressure-driven metallization and topological charge transport in an anion radical salt
2021
Abstract The hybrid inorganic/organic closed π -stacking and soft lattice of a copper anion radial (Copper-7,7,8,8-tetracyanoquinodimethane) renders its electrical conductivity and structural modifications, which are susceptible to temperature and pressure. The geometry of its metal-ligand construction contemplates the concept of topology with a charge-transfer instability. A pressure-induced ionic-neutral phase transition occurs and accompanies an anomalously large electrical conductivity, carries topological charges, and possesses a low energy gap smaller than the Coulomb gap. X-ray absorption spectroscopy of the metal establishes the high electrical conduction by the topological charges.…
Anisotropic photoluminescence of nonpolar ZnO epilayers and ZnO/Zn1 −xMgxO multiple quantum wells grown on LiGaO2 substrate
2020
Ministry of Science and Technology, Taiwan (104-2221-E-110-012-MY3, 107-2221-E-110-004-MY3); National Natural Science Foundation of China (51602309, U1605245).
Optical characterization of Mg-doped GaN films grown by metalorganic chemical vapor phase deposition
2000
Scanning electron microscopy, micro-Raman, and photoluminescence (PL) measurements are reported for Mg-doped GaN films grown on (0001) sapphire substrates by low-pressure metalorganic chemical vapor phase deposition. The surface morphology, structural, and optical properties of GaN samples with Mg concentrations ranging from 1019 to 1021 cm−3 have been studied. In the scanning micrographs large triangular pyramids are observed, probably due to stacking fault formation and three-dimensional growth. The density and size of these structures increase with the amount of magnesium incorporated in the samples. In the photoluminescence spectra, intense lines were found at 3.36 and 3.31 eV on the tr…
Interlayer exciton dynamics in van der Waals heterostructures
2019
Atomically thin transition metal dichalcogenides can be stacked to van der Waals heterostructures enabling the design of new materials with tailored properties. The strong Coulomb interaction gives rise to interlayer excitons, where electrons and holes are spatially separated in different layers. In this work, we reveal the time- and momentum-dependent elementary processes behind the formation, thermalization and photoemission of interlayer excitons for the exemplary MoSe2–WSe2 heterostructure. We identify tunneling of holes from MoSe2 to WSe2 on a ps timescale as the crucial process for interlayer exciton formation. We also predict a drastic reduction of the formation time as a function of…
Emission Enhancement by Intramolecular Stacking between Heteroleptic Iridium(III) Complex and Flexibly Bridged Aromatic Pendant Group
2019
Phosphorescent iridium(III) complexes suffer from a strong aggregation quenching, limiting their use in solution-processed or crystalline organic light-emitting diodes. Here we report how an intramolecular stacking between a flexibly bridged bulky aromatic pendant group and the core of nonionic heteroleptic complex can be exploited to minimize the negative effects of this drawback. The stacked conformation provides a rigid sterical shielding of the polar molecular surface, improving photoluminescence quantum yield of the complex both in solution and crystalline state.
Transmitter waveform and receiver transfer function modelling in time domain induced polarization
2012
SUMMARY In the computation of the forward response for Time Domain Induced Polarization the incomplete description of the transmitter waveform causes dramatic errors in the estimation of the magnitude and time characteristic of the IP phenomenon. Both the duration of the current pulse and the sequence of pulses used for the stacking procedure have a strong effect in the magnitude and shape of the IP decays. Furthermore, it is important to model low-pass filters of the receiver system, in order to extract all the information contained in the acquired data. For these reasons, a new 1D forward and inversion algorithms have been developed using the full time decay of the IP response and the rec…
Spin-layer locking of interlayer excitons trapped in moir\'e potentials
2019
Van der Waals heterostructures offer attractive opportunities to design quantum materials. For instance, transition metal dichalcogenides (TMDs) possess three quantum degrees of freedom: spin, valley index, and layer index. Further, twisted TMD heterobilayers can form moir\'e patterns that modulate the electronic band structure according to atomic registry, leading to spatial confinement of interlayer exciton (IXs). Here we report the observation of spin-layer locking of IXs trapped in moir\'e potentials formed in a heterostructure of bilayer 2H-MoSe$_2$ and monolayer WSe$_2$. The phenomenon of locked electron spin and layer index leads to two quantum-confined IX species with distinct spin-…
Close packing of clusters: Application toAl100
2003
The lowest energy configurations of close-packed clusters up to N=110 atoms with stacking faults are studied using the Monte Carlo method with Metropolis algorithm. Two types of contact interactions, a pair-potential and a many-atom interaction, are used. Enhanced stability is shown for N=12, 26, 38, 50, 59, 61, 68, 75, 79, 86, 100 and 102, of which only the sizes 38, 75, 79, 86, and 102 are pure FCC clusters, the others having stacking faults. A connection between the model potential and density functional calculations is studied in the case of Al_100. The density functional calculations are consistent with the experimental fact that there exist epitaxially grown FCC clusters starting from…
Compact-envelope bright solitary wave in a DNA double strand
2012
International audience; We study the nonlinear dynamics of a homogeneous DNA chain which is based on site-dependent finite stacking and pairing enthalpies. We introduce an extended nonlinear Schroedinger equation describing the dynamics of modulated waves in DNA model. We obtain envelope bright solitary waves with compact support as a solution. Analytical criteria of existence and stability of this solution are derived. The stability of bright compactons is confirmed by numerical simulations of the exact equations of the lattice. The impact of the fi nite stacking energy is investigated and we show that some of these compact bright solitary waves are very robust, while others decompose quic…
A real-space approach to the analysis of stacking faults in close-packed metals: G(r) modelling and Q-space feedback
2019
An R-space approach to the simulation and fitting of a structural model to the experimental pair distribution function is described, to investigate the structural disorder (distance distribution and stacking faults) in close-packed metals. This is carried out by transferring the Debye function analysis into R space and simulating the low-angle and high-angle truncation for the evaluation of the relevant Fourier transform. The strengths and weaknesses of the R-space approach with respect to the usual Q-space approach are discussed.