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showing 10 items of 29383 documents
Magneto-optical properties of two-layer film systems based on Fe and Cr
2020
The results of the investigation of two-layer Fe/Cr systems using the magneto-optical Kerr effect (MOKE) are presented in this paper. The samples were obtained by thermal evaporation in a vacuum with a thickness of individual layers from 2 nm to 50 nm. It was found that the presence of the Cr layer significantly affects the values of the coercivity and the Kerr angle. At a substrate temperature of 450 K, the value of the coercivity is almost half that of the same sample obtained at room temperature of the substrate. In addition, the influence of the order of deposition of layers, as well as the effect of a thin gold protective layer on the parameters measured by the Kerr method, is shown. …
The effect of magnetocrystalline anisotropy on the domain structure of patterned Fe2CrSi Heusler alloy thin films
2013
The effects of magnetic anisotropy on domain structures in half-metallic Heusler alloy Fe2CrSi thin film elements were investigated using high resolution x-ray magnetic circular dichroism photoemission electron microscopy. The transition of the dominating contribution from the magnetocrystalline anisotropy to the shape anisotropy is observed in square-shaped elements when reducing the size below 2.0–2.5 μm. In particular, we identify in disk-shaped Heusler elements the vortex state as the ground state. The shape-anisotropy dominated, well-defined magnetization configuration shows the potential of the Fe2CrSi Heusler alloy for applications in vortex-core- or domain-wall-devices, where the hi…
High pressure theoretical and experimental analysis of the bandgap of BaMoO4, PbMoO4, and CdMoO4
2019
We have investigated the origin of the bandgap of BaMoO4, PbMoO4, and CdMoO4 crystals on the basis of optical absorption spectroscopy experiments and ab initio electronic band structure, density of states, and electronic localization function calculations under high pressure. Our study provides an accurate determination of the bandgaps Eg and their pressure derivatives d E g / dP for BaMoO4 (4.43 eV, −4.4 meV/GPa), PbMoO4 (3.45 eV, −53.8 meV/GPa), and CdMoO4 (3.71 eV, −3.3 meV/GPa). The absorption edges were fitted with the Urbach exponential model which we demonstrate to be the most appropriate for thick crystals with direct bandgaps. So far, the narrowing of the bandgap of distinct PbMoO4…
Ab initio calculations of structural, electronic and vibrational properties of BaTiO3 and SrTiO3 perovskite crystals with oxygen vacancies
2020
The first-principles (ab initio) computations of the structural, electronic, and phonon properties have been performed for cubic and low-temperature tetragonal phases of BaTiO3 and SrTiO3 perovskite crystals, both stoichiometric and non-stoichiometric (with neutral oxygen vacancies). Calculations were performed with the CRYSTAL17 computer code within the linear combination of atomic orbitals approximation, using the B1WC advanced hybrid exchange-correlation functional of the density-functional-theory (DFT) and the periodic supercell approach. Various possible spin states of the defective systems were considered by means of unrestricted (open shell) DFT calculations. It was demonstrated that…
Quasi-static behaviour and damage assessment of flax/epoxy composites
2015
Experimental investigations were conducted on flax and E-glass fibres reinforced epoxy matrix composites subjected to quasi-static loadings. Flax/epoxy samples having [0]12, [90]12, [0/90]3S and [±45]3S stacking sequences, with a fibre volume fraction of 43% have been tested under tension, compression and in-plane shear loadings. Overall, the compression strength of glass/epoxy was 76% greater than for the flax/epoxy composite. The damage evolution of flax/epoxy of [0/90]3S and [±45]3S samples has been evaluated in terms of transverse crack densities with respect to the load increment. The crack density exhibited a classical “S” shaped pattern for [0/90]3S and linearly for [±45]3S specimens…
Atomic, electronic and magnetic structure of an oxygen interstitial in neutron-irradiated Al2O3 single crystals
2020
This work has been carried out within the framework of the EUROfusion Consortium and has received funding from the Euratom research and training programme 2014-2018 and 2019-2020 under Grant Agreement No. 633053 and Enabling Research project: ENR-MFE19.ISSP-UL-02 “Advanced experimental and theoretical analysis of defect evolution and structural disordering in optical and dielectric materials for fusion application”. The views and opinions expressed herein do not necessarily reflect those of the European Commission. In addition, the research leading to these results has received funding from the Estonian Research Council grant (PUT PRG619).
Non-Linearity Extremum in Niobium Doped Potassium Tantalate
1997
We report non-linear dielectric measurements in the KTaO 3 :Nb system (x Nb ≤ 0.05). The non-linear susceptibility diverges at low temperatures and reaches maximum values in the intermediate range (0.0075 ≤ x Nb ≤ 0.02). To account for this extremum non linearity, we propose a model of temperature dependent clusters which fits with a number of experimental reports. We also suggest that this model may be applied to the related compounds SrTiO 3 :Ca and KTaO 3 :Na.
Effects of water removal on the structure and spin-crossover in an anilato-based compound
2021
The crucial role played by a crystallization water molecule in the spin crossover (SCO) temperature and its hysteresis is described and discussed in compound [NBu4][Fe(bpp)2][Cr(C6O4Br2)3]⋅2.5H2O (1), where bpp = 2,6-bis(pyrazol-3-yl)pyridine and (C6O4Br2)2− = dianion of the 3,6-dibromo-2,5-dihydroxy-1,4-benzoquinone. The compound has isolated [Fe(bpp)2]2+ cations surrounded by chiral [Cr(C6O4Br2)3]3− anions, NBu4+ cations, and a water molecule H-bonded to one of the non-coordinated N–H groups of one bpp ligand. This complex shows a gradual almost complete two-step spin transition centered at ca. 180 and 100 K with no hysteresis. The loss of the water molecules results in a phase transition…
Dynamics of quantum discord of two coupled spin-1/2’s subjected to time-dependent magnetic fields
2019
Abstract We describe the dynamics of quantum discord of two interacting spin-1/2’s subjected to controllable time-dependent magnetic fields. The exact time evolution of discord is given for various input mixed states consisting of classical mixtures of two Bell states. The quantum discord manifests a complex oscillatory behaviour in time and is compared with that of quantum entanglement, measured by concurrence. The interplay of the action of the time-dependent magnetic fields and the spin-coupling mechanism in the occurrence and evolution of quantum correlations is examined in detail.
High-frequency EPR study on Cu4Cu- and Co4Co-metallacrown complexes
2019
Abstract High-frequency/high-field electron paramagnetic resonance studies on two homonuclear 12-MC-4 metallacrown complexes Cu4Cu and Co4Co are presented. For Cu4Cu, our data imply axial-type g-anisotropy with g x = 2.03 ± 0.01 , g y = 2.04 ± 0.01 , and g z = 2.23 ± 0.01 , yielding g = 2.10 ± 0.02 . No significant zero field splitting (ZFS) of the ground state mode is observed. In Co4Co, we find a m S = ± 3 / 2 ground state with g = 2.66 . The data suggest large anisotropy D of negative sign.