Search results for "structural"

Reproduction of Baltic cod, Gadus morhua (Actinopterygii: Gadiformes: Gadidae), in the Gotland Basin: Causes of annual variability

2015

Background. The Gotland Basin spawning ground is one of three main spawning areas of Baltic cod, Gadus morhua Linnaeus, 1758. The threshold water parameters for cod development are the salinity exceeding 11‰ and the oxygen level above 2 mL· L–1. Such conditions are only present when the 11‰ isohaline is above the 2 mL· L–1 isooxygen. In such situation the water volume between the isolines is called the “suitable reproduction volume”. When the position of the isolines is reversed, the salinity and the oxygen level of the water layer demarcated by them are below the required thresholds and as such the water is unsuitable for the cod development. We refer to it as the “unsuitable reproduction …

Synthesis and characterization of perfluoroalkyl-pyrenes embedded in a polymethylmethacrylate matrix

2012

One-pot synthesis of fluorinated 2-amino-pyrimidine-N-oxides. Competing pathways in the four-atom side-chain rearrangements of 1,2,4-oxadiazoles

2006

Abstract Trifluoromethylated 2-amino-pyrimidine N-oxides have been synthesized by reaction of the 3-amino-5-methyl-1,2,4-oxadiazole with trifluoromethyl-β-diketones in the presence of perchloric acid, followed by hydrolysis. In this ring-to-ring transformation an initial formation of (unisolated) 1,2,4-oxadiazole-pyrimidinium salts, and subsequent ring-opening at the oxadiazole moiety occurs. Isolation of 2-(hydroxyamino)-pyrimidine from the reaction mixture evidenced the presence of a competing pathway where the N(4) nitrogen of the oxadiazole is involved in the formation of a regioisomeric pyrimidinium salt. The effect of the trifluoromethyl group on the product distribution is discussed.…

The Effect of the Perceived Utility of a Management Control System with a Broad Scope on the Use of Food Waste Information and on Financial and Non-F…

2020

The purpose of this study is to analyse the effect of the perceived utility of a management control system with a broad scope on the use of food waste information and on financial and non-financial performances in restaurants. To collect data, a questionnaire was administered in Brazilian restaurants. Data from 206 restaurants were analysed with structural equation modelling, which was performed with SmartPLS software. The results reveal that a management control system of broad scope, which includes non-financial information, is oriented towards the future, and contains an external and long-term focus, assists in the use of information on food waste. In addition, the use of information abo…

Microstructure and characteristic properties of dogfish skin gelatin gels prepared by freeze/spray-drying methods

2020

International audience; The effects of two pretreatments (microwaves or oven-drying) on the dogfish (Squalus acanthias) skin as well as two drying processes (freeze-drying or spray-drying) on the extracted gelatins were studied. Thus six types of gelatins were obtained, three of which were freeze-dried (FG) and the others were spray-dried (SG), from the untreated skin (US), microwaves-pretreated skin (MS) and oven-pretreated skin (OS). The highest yield (8.67%) was obtained for the OSFG, while the lowest one (3.06%) was measured for the OSSG. Interestingly, all gelatins exhibited relatively high protein (84.02-89.53%), and low lipid (0.50-1.71%) and ash (3.05-7.17%) contents. In addition, g…

Recent advances in the application of microbial transglutaminase crosslinking in cheese and ice cream products: A review

2018

Microbial transglutaminase (MTGase) has been currently utilized to form new food structures and matrices with high physicochemical stability. Incorporation of this multi-functional enzyme into structural composition of milk protein-based products, such as cheese and ice cream, can not only be a successful strategy to improve their nutritional and technological characteristics through intramolecular cross-linking, but also to reduce the production cost by decreasing fat and stabilizer contents. The recent research developments and promising results of MTGase application in producing functional formulations of cheese and ice cream with higher quality characteristics are reviewed. New interest…

Coupling tyrosol, quercetin or ferulic acid and electron beam irradiation to cross-link chitosan–gelatin films: A structure–function approach

2015

International audience; Marine industry by-products, chitosan and fish gelatin, entrapping natural antioxidants (ferulic acid, quercetin and tyrosol) were used to prepare edible active films by casting. The films were composed of chitosan and fish gelatin (1:1 w:w) and incorporating antioxidants (∼50 mg/g). After solvent evaporation (drying), the films were irradiated at 60 kGy by electron beam. This treatment aims at investigating the coupled effect of irradiation with the presence of active compound on the structure and functional properties of the films. Electron Spin Resonance (ESR) unravelled free radical formation during irradiation in films containing ferulic acid or tyrosol which fa…

Inorganic phosphate is a trigger factor for Microbispora sp. ATCC-PTA-5024 growth and NAI-107 production

2014

Background NAI-107, produced by the actinomycete Microbispora sp. ATCC-PTA-5024, is a promising lantibiotic active against Gram-positive bacteria and currently in late preclinical-phase. Lantibiotics (lanthionine-containing antibiotics) are ribosomally synthesized and post-translationally modified peptides (RiPPs), encoded by structural genes as precursor peptides. The biosynthesis of biologically active compounds is developmentally controlled and it depends upon a variety of environmental stimuli and conditions. Inorganic phosphate (Pi) usually negatively regulates biologically-active molecule production in Actinomycetes, while it has been reported to have a positive control on lantibiotic…

Social capital in the international operations of family SMEs

2012

PurposeThe aim of this study is to discuss how social capital is developed in the internationalization process of small and medium‐sized family enterprises (family SMEs).Design/methodology/approachThis paper reports findings from an in‐depth multiple case study with four Finnish manufacturing family SMEs. The data were analyzed through the perspectives of structural holes, network closure, and the interplay between these two mechanisms.FindingsThe material in the paper demonstrated that family entrepreneurs had a large number of structural holes when launching international operations, but also after several years of running international operations. Instead of trying to span structural hol…

Histoire cachée du structuralisme : entre la métaphore organique et le point de vue

2019

The invisible history of structuralism: between “organic metaphor” and a “point of view”Abstract: Patrick Sériot’s reconstruction of an “invisible” and “unfamiliar” history of struc-turalism leads to conclusions about the importance of a comparative analysis of the historical-epistemological contexts of Russian and German-speaking research, as well as about the decisive role of the episteme of the 19th century in later linguistic theoretical constructions. This implies the idea of two structuralisms, two models of formal or structural orientation. The object of the first is a form or a structure as a logical organization and an expression of a certain “point of view”; the object of the seco…