Search results for "structural"
showing 10 items of 5047 documents
Thuoux and Saint-Pierre d’Argençon Sections (Subalpine Basin, Southeastern France): Case Studies of Ammonite Biostratigraphy for the Potential Candid…
2014
The Thuoux and Saint-Pierre d’Argencon sections (Subalpine Basin, southeastern France) display a thick silty–clayey sedimentation with abundant and diversified ammonite faunas, free of detectable hiatuses. The Callovian–Oxfordian boundary is biostratigraphically located between the Lamberti and the Mariae zones or, more precisely, between the Lamberti Subzone (paucicostatum horizon) and the Scarburgense Subzone (thuouxensis horizon). The mixing of Boreal–Sub-Boreal Cardioceratinae and Sub-Mediterranean–Tethyan Hecticoceratinae, Peltoceratinae, and Perisphinctinae in this basin allows reliable worldwide correlations that enhance the choice of the Thuoux and Saint-Pierre d’Argencon sections a…
Proposal for the Thuoux section as a candidate for the GSSP of the base of the Oxfordian stage.
2012
20 pages; International audience; The Thuoux section, located in South-Eastern Basin of France (coordinates: 44°30'55"E; 5°42'25"N), is a section that satisfies numerous demanding criteria as reference section (GSSP) for the base of the Oxfordian stage. Sedimentation was continuous in that the abundant ammonitic fauna yields no detectable hiatuses. The stratigraphic boundary is located between the Lamberti Zone and the Mariae Zone or more precisely between the Paucicostatum horizon (MARCHAND, 1979) and the Thuouxensis horizon (FORTWENGLER & MARCHAND, 1994a). In this section, there is a perfect mixing bet-ween Boreal ammonites (Cardioceratinae) whose species are used as stratigraphic markers…
Variations in Jurassic echinoid biodiversity at ammonite zone levels: Stratigraphical and palaeoecological significance
2020
After a relatively low but stable phase of taxonomic diversity during the Lias (Lower Jurassic), echinoids diversity strongly increases from Aalenian (Dogger-Middle Jurassic) to Kimmeridgian (Malm-Late Jurassic) and a conspicuous crisis takes place in Tithonian times, before the end of the Jurassic. During these major phases, minor decreases in diversity correspond with regressions (sea-level falls), mainly in the Middle Bathonian (Middle Jurassic). From the Aalenian to Callovian, the average duration of irregular echinoid species is about 3.8 m.y. whereas it is about 5.5 m.y. for the regular ones; the later value corresponding to the average duration of a Jurassic. From Callovian to Tithon…
Albian ammonites of the Benguela Basin (Angola): a biostratigraphic framework.
2007
20 pages; The study of the Albian ammonite fauna of the sedimentary series in the Benguela Basin (Angola) allows a major revision of the biostratigraphy of the south Atlantic area. The new biostratigraphic approach allows the recognition of 17 horizons distributed in 8 subzones correlated with the ammonite zonation of the Tethyan Province. The Lower Albian is characterized by the Douvilleiceras inaequinodum Subzone (including the D. mammillatum aequinodum Horizon). The Middle Albian is represented by the Oxytropidoceras (Mirapelia) buarquianum Subzone (subdivided into O. (M.) buarquianum and O. (M.) sergipense horizons). The Upper Albian is characterized by the Dipoloceras sp. Subzone (defi…
Settlement down again patterns of a carbonated platform following up a sedimentary crisis : example of the middle-late Jurassic boundary in the south…
2004
Abstract Following a sedimentary crisis which begins in the late Lower Callovian and spans all the early Oxfordian, the settlement down patterns of a platform with carbonated sedimentation are analysed in a southeastern area of the Paris Basin (fig. 1). Ten lithostratigraphic units (reefal formations, associated bioclastic facies and marly distal lateral facies ; fig. 2) are defined (fig. 3). New ammonite and brachiopod faunas, collected in situ, allow to date accurately the sedimentary units with a precision matching an ammonite subzone of the standard bio-chronostratigraphic scale (fig. 4) of the middle-late Oxfordian (from the Parandieri Subzone, at the base of the Transversarium Zone, t…
Ammonium ion mediated resorcarene capsules: ESI-FTICRMS study on gas-phase structure and ammonium ion affinity of tetraethyl resorcarene and its per-…
2003
AbstractThe ammonium ion binding affinities of tetraethyl resorcarene (1) and its per-methylated derivative (2) were studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Ten different ammonium ions were tested as guests for the resorcarenes. A strong tendency for complex formation was observed with all ammonium ions of size and charge distribution suitable for noncovalent interactions with the cavities of the resorcarene hosts 1 and 2. Although differences in ammonium ion affinities were observed between 1 and 2 due to the dissimilar conformations, the overall tendency was that increase in the degree of substitution and the length of ca…
Keyhole limpet haemocyanin: negative staining in the presence of trehalose
1995
Abstract Samples of unpurified and purified haemocyanin from the giant keyhole limpet Megathura crenulata have been studied by transmission electron microscopy (TEM) using mixtures of trehalose with the negative stains, uranyl acetate and ammonium molybdate. Trehalose is a known protein preservative during air and freeze drying, UV irradiation and high temperatures, and therefore offers the possibility of protecting proteins during the drying of negatively-stained specimens and their subsequent electron microscopical study. Evidence is presented that trehalose possesses satisfactory stability within the electron beam during conventional room temperature, negative-staining studies. The combi…
Crystallization of the altitude adapted hemoglobin of guinea pig.
2009
Hemoglobin is the versatile oxygen carrier in the blood of vertebrates and a key factor for adaptation to live in high altitudes. Several structural changes are known to account for increased oxygen affinity in hemoglobin of altitude adapted animals such as llama and barheaded goose. Guinea pigs are adapted to live in high altitudes in the Andes and consequently their hemoglobin has an increased oxygen affinity. However, the structural changes responsible for the adaptation of guinea pig hemoglobin are unknown. Here we report the crystallization of guinea pig hemoglobin in the presence of 2.6 M ammonium sulfate and a preliminary analysis of the crystals. Crystals diffract up to a resolution…
The earliest tupilakosaurid amphibian with diplospondylous vertebrae from the Late Permian of southern France
2007
5 pages; International audience; A well-preserved vertebral column from the Late Permian of Southern France (Lopingian, La Lieude Formation, Lodève Basin) is described. It is composed of diplospondylous vertebrae and is most comparable with the temnospondyl Tupilakosaurus previously known from the Early Triassic of Greenland and Russia. This new specimen therefore represents the earliest occurrence of a diplospondylous tupilakosaur, and extends the geographic range of the group to Western Europe. It is an aquatic temnospondyl that used the anguilliform undulatory mode of swimming.
How self-assembly of amphiphilic molecules can generate complexity in the nanoscale
2015
Abstract Given the importance of nanomaterials and nanostructures in modern technology, in the past decades much effort has been directed to set up efficient bottom up protocols for the piloted self-assembly of molecules. However, molecules are generally disinclined to adopt the desired structural organization because they behave according to their own specific intermolecular interactions. Thus, only some selected classes of chemical compounds are capable to lead to useful self-assembled structures. Amphiphiles, simultaneously possessing polar and apolar moieties within their molecular architecture, can give a wide scenario of possible intermolecular interactions: polar–polar, polar–apolar,…