Search results for "sun"
showing 10 items of 935 documents
A sequential-injection system for spectrophotometric determination of p -aminobenzoic acid in sunscreens.
2002
A sequential injection method is proposed for spectrophotometric determination of p-aminobenzoic acid (PABA) in cosmetic formulations. The method is based on diazotization of the analyte, coupling with 8-hydroxyquinoline, and the subsequent formation of a colored product. The experimental conditions used (coupling reagent, sandwich arrangement, volumes aspirated, propulsion flow rate, reaction coil length) were studied. Response of the sequential injection method were linearly dependent on concentrations up to 25 micro g mL(-1) and the detection limit was 2 micro g mL(-1). Throughput was 51 measurements per hour and a complete cycle, including three measurement per sample and a washing step…
Determination of edible oil parameters by near infrared spectrometry
2006
Abstract A chemometric method has been developed for the determination of acidity and peroxide index in edible oils of different types and origins by using near infrared spectroscopy (NIR) measurements. Different methods for selecting the calibration set, after an hierarchical cluster analysis, were applied. After discrimination of olive oils from maize, seed and sunflower, the prediction capabilities of partial least squares (PLS) multivariate calibration of NIR data were evaluated. Several preprocessing alternatives (first derivative, multiplicative scatter correction, vector normalization, constant offset elimination, mean centering and standard normal variate) were investigated by using…
Determination of water-soluble UV-filters in sunscreen sprays by liquid chromatography.
2002
Abstract Liquid chromatography was used for the determination of the three most used water-soluble UV filters, benzophenone-4 (BZ4), terephthalylidene dicamphor sulfonic acid (TDS), and phenylbenzimidazole sulphonic acid (PBS), in aqueous sunscreen sprays. A C 18 stationary phase and an isocratic mobile phase of EtOH–20 m M sodium acetate buffer of pH 4.6 (30:70, v/v) were used at a flow-rate of 0.5 ml min −1 . Mobile phase was also used as solvent for samples and standards. UV detection was at 313 nm. The analytical run took 5.5 min. The limits of detection were 0.5, 0.9 and 2 μg ml −1 for BZ4, TDS and PBS, respectively. The proposed method does not involve highly toxic solvents.
A solid-phase extraction and size-exclusion liquid chromatographic method for polyethylene glycol 25 p-aminobenzoic acid determination in urine: Vali…
2007
No previous publications about percutaneous absorption of polyethylene glycol 25 p-aminobenzoic acid (PEG-25 PABA) have been found in the literature and the expected levels to be found in human urine after sunscreens use are unknown. The method proposed here is suitable to determine PEG-25 PABA in the urine of sunscreens users in order to carry out studies on body accumulation/excretion. It is based on solid-phase extraction (SPE) with size-exclusion liquid chromatography determination. Solid-phase extraction allows the analyte to be retained and subsequently eluted for a clean-up, using a silica-based cartridge. The size-exclusion liquid chromatography of the eluted allows the rest of matr…
Determination of UV-filters in sunscreens by HPLC.
2001
Simultaneous determination of six internationally authorised organic UV-filters in sunscreen formulations was performed by HPLC with UV spectrophotometric detection. The filters determined were: sulisobenzone, oxybenzone, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate and homosalate. A C18 stationary phase and a mobile phase of ethanol water acetic acid (70 : 29.5 : 0.5) were used with a flow rate of 0.5 mL/min. UV measurements were carried out at 313 nm. The time required for the analysis was 25 min and the limits of detection were between 0.2 and 2 mg/L, except for sulisobenzone, which gave a limit of detection of 20 mg/L. The procedure proposed provides an accurate, fast a…
Identification of the Biotransformation Products of 2-Ethylhexyl 4-(N,N-Dimethylamino)benzoate
2010
Nowadays, 2-ethylhexyl 4-(N,N-dimethylamino)benzoate (EDP) is one of the most widely used UV filters in sunscreen cosmetics and other cosmetic products. However, undesirable processes such as percutaneous absorption and biological activity have been attributed to this compound. The in vitro metabolism of EDP was elucidated in the present work. First of all, the phase I biotransformation was studied in rat liver microsomes and two metabolites, N,N-dimethyl-p-aminobenzoic acid (DMP) and N-monomethyl-p-aminobenzoic acid (MMP), were identified by GC-MS analysis. Secondly, the phase II metabolism was investigated by means of LC-MS. The investigated reactions were acetylation and glucuronidation …
A simple model for computing diffuse solar radiation
1989
In this paper a very simple model for predicting the daily diffuse solar radiation at any Italian location using as input few extensively measured meteorological parameters is proposed. In fact the daily diffuse radiation D, MJ.m−2.day−1, here is correlated with only the relative sunshine duration sS and the noon altitude of the sun on the 15th of the month hn, degrees, by the following equation: D=7(sS−(sinhn)1.55 . The validity of this formula is verified using monthly mean daily data from four Italian stations displaced at various latitudes or altitudes or geographical situations (inland or coastal site). The test results show that the deviations between the measured and the computed val…
Digital skills e consapevolezza metacognitiva: prospettive di sviluppo professionale dei docenti universitari neoassunti
2021
La spinta all’innovazione verso ambienti di apprendimento caratterizzati da un uso intensivo della tecnologia, determinata dalla crisi pandemica, costituisce una questione strategica per lo sviluppo dell’alta formazione. In questa direzione, la formazione e professionalizzazione del docente universitario sul versante pedagogico-didattico-valutativo rappresenta un’azione rilevante con potenziale impatto sul sistema universitario nel suo complesso. Il focus specifico del presente contributo riguarda il ruolo della competenza metacognitiva del docente con particolare attenzione all’utilizzo delle tecnologie, delle strategie didattiche evidence-informed e di modalità innovative di valutazione. …
A property of connected Baire spaces
1997
Abstract We give a topological version of a classical result of F. Sunyer Balaguer's on a local characterization of real polynomials. This is done by studying a certain property on a class of connected Baire spaces, thus allowing us to obtain a local characterization of repeated integrals of analytic maps on Banach spaces.
Educació artística per sensibilitzar en diversitat sexual
2021
Aquesta investigació forma part del projecte "Sensibilització en igualtat de gènere i diversitat sexual mitjançant intervencions artístiques en contextos universitaris" (GV/2020/069). L'objectiu és reflexionar a partir de pràctiques artístiques, elaborant dissenys gràfics, tot incorporant qüestions d'educació en disseny des del taller de gràfica. Es presenta l'estudi de cas d'una intervenció als espais universitaris, ana-litzant el taller impartit a grups d'alumnat, fent servir instruments d'avaluació com diagnòstics, grups focals i treball creatiu, formant mestres conscients del respecte a la diversitat sexual i l'educació inclusiva. Entre els resultats, destacar la utilització del disseny…