Search results for "suns"
showing 10 items of 74 documents
Determination of UV-filters in sunscreens by HPLC.
2001
Simultaneous determination of six internationally authorised organic UV-filters in sunscreen formulations was performed by HPLC with UV spectrophotometric detection. The filters determined were: sulisobenzone, oxybenzone, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate and homosalate. A C18 stationary phase and a mobile phase of ethanol water acetic acid (70 : 29.5 : 0.5) were used with a flow rate of 0.5 mL/min. UV measurements were carried out at 313 nm. The time required for the analysis was 25 min and the limits of detection were between 0.2 and 2 mg/L, except for sulisobenzone, which gave a limit of detection of 20 mg/L. The procedure proposed provides an accurate, fast a…
Identification of the Biotransformation Products of 2-Ethylhexyl 4-(N,N-Dimethylamino)benzoate
2010
Nowadays, 2-ethylhexyl 4-(N,N-dimethylamino)benzoate (EDP) is one of the most widely used UV filters in sunscreen cosmetics and other cosmetic products. However, undesirable processes such as percutaneous absorption and biological activity have been attributed to this compound. The in vitro metabolism of EDP was elucidated in the present work. First of all, the phase I biotransformation was studied in rat liver microsomes and two metabolites, N,N-dimethyl-p-aminobenzoic acid (DMP) and N-monomethyl-p-aminobenzoic acid (MMP), were identified by GC-MS analysis. Secondly, the phase II metabolism was investigated by means of LC-MS. The investigated reactions were acetylation and glucuronidation …
A simple model for computing diffuse solar radiation
1989
In this paper a very simple model for predicting the daily diffuse solar radiation at any Italian location using as input few extensively measured meteorological parameters is proposed. In fact the daily diffuse radiation D, MJ.m−2.day−1, here is correlated with only the relative sunshine duration sS and the noon altitude of the sun on the 15th of the month hn, degrees, by the following equation: D=7(sS−(sinhn)1.55 . The validity of this formula is verified using monthly mean daily data from four Italian stations displaced at various latitudes or altitudes or geographical situations (inland or coastal site). The test results show that the deviations between the measured and the computed val…
Triplet stabilization for enhanced drug photorelease from sunscreen-based photocages
2021
[EN] Recently, sunscreen-based drug photocages have been introduced to provide UV protection to photoactive drugs, thus increasing their photosafety. Here, combined experimental and theoretical studies performed on a photocage based on the commercial UVA filter avobenzone (AB) and on the photosensitizing non-steroidal anti-inflammatory drug ketoprofen (KP) are presented unveiling the photophysical processes responsible for the light-triggered release. Particular attention is paid to solvent stabilization of the drug and UV filter excited states, respectively, which leads to a switching between the triplet excited state energies of the AB and KP units. Most notably, we show that the stabiliz…
Night, day, sunrise, sunset: do fish under snow and ice recognize the difference?
2008
1. Although boreal lakes are ice-covered for several months annually, little is known about the behaviour of fish under ice. To consider the reasons for diel vertical migrations (DVM) it is important to compare periods under ice as opposed to under open water. Echosounding provides a tool for non-intrusive continuous monitoring of fish, even in winter. 2. Changes in the vertical distribution of fish through six 48-h periods were monitored using a stationary, mounted echosounder that beamed vertically either from the bottom up or from the surface down from February to April, 2003. The up-beaming and down-beaming transducers were run alternately for 24 h each over the 48-h period. Standard ec…
Spanish Stock Returns: Where is the Weather Effect?
2003
Psychological studies support the existence of an influence of weather on mood. Saunders (1993) and Hirshleifer and Shumway (2001) argue that the weather could affect the behaviour of market traders and, therefore, it should be reflected in the stock returns. This paper investigates the possible relation between weather and market index returns in the context of the Spanish market. In 1989, this market changed its open outcry trading system into a computerised and decentralised trading system. Therefore, it is possible to check the influence of weather variables (sunshine hours and humidity levels) on index returns in an open outcry trading system, and to compare it with a screen traded env…
Uncertain sunset lives: British migrants facing Brexit in Spain
2020
One of the most concerned groups potentially impacted by the approval of Brexit in 2016 is that of the so-called “Brexpats”. This group of people is composed by at least 784,900 British citizens who are living in the European Union (EU), among which those settling in Spain are the most prominent. Spanish Brexpats are the largest British population outside the borders of the UK, except for in the Commonwealth territories. They have some peculiar characteristics, such as an advanced average age compared to other EU destinations; a large number of people living off the radar; geographical concentration within coastal areas; and a certain social isolation. In this context, the succession of new…
Cloudiness and Sunshine
1988
Records on mean monthly and annual cloudiness are contained in the climate tables (see Appendix). Despite regional gaps of data sources, the attempt was nevertheless made to work out some principal observations on cloudiness.
Expanding the application of stir bar sorptive-dispersive microextraction approach to solid matrices: Determination of ultraviolet filters in coastal…
2018
This work describes a new method for the determination of organic compounds in solid samples based on the equilibrium desorption of the analytes in an aqueous phase followed by stir bar sorptive-dispersive microextraction (SBSDME). Sand samples, contaminated with UV filters due to bathing and recreational activities, were dispersed in an aqueous medium by using a coated stir bar with CoFe2O4@oleic acid magnetic nanoparticles. The UV filters were physically desorbed from the surface of the sand particles and rapidly adsorbed on the hydrophobic coating of the nanoparticles, which were retrieved by means of their magnetism after stopping the stirring. In this manner, both preconcentration of t…
Validation of a very simple model for computing global solar radiation in the European, African, Asian and North American areas
1990
Abstract In a previous paper Coppolino has proposed a very simple model for predicting the monthly mean daily global solar radiation G (MJm −2 day −1 ) at any Italian location using as input only the sunshine duration s (hours) and the noon altitude of the sun on the 15th of the month h n (degrees). The correlation suggested is G = 7.8 s 0.5 (sin h n ) 1.15 . Herein the validity of this model is verified by extending its application to dat from 24 stations displaced at various latitudes, altitudes above sea level and geographical situations in the European, African, Asian and North American areas. Furthermore the validity of this model to fit the data of the tested stations is compared with…