Search results for "surface"
showing 10 items of 9345 documents
Immobilization of single-stranded DNA fragments to solid surfaces and their repeatable specific hybridization : covalent binding or adsorption ?
2004
Abstract The different steps of the immobilization process of single-stranded DNA (ssDNA) on surfaces by means of chemical grafting have been investigated using systematic measurements of grafting and hybridization densities by means of radioactive labelling. The immobilization by chemical grafting to a dense monomolecular layer of N-hydroxysuccinimidyl ester reactive functions attached to silica plates was performed from a dilute solution of amino-terminated oligonucleotides (10 μmol/l). The slow evaporation of the solvent allowed to increase the DNA grafting density by a factor of 10. A precise control of the rinsing process that followed the immobilization reaction allowed the discrimina…
Quantification of land-atmosphere exchanges of water, energy and carbon dioxide in space and time over the heterogeneous Barrax site
2008
International audience; To advance our understanding of land-atmosphere exchanges of water, energy and carbon dioxide (CO2) in space and time over heterogeneous land surfaces, two intensive field campaigns were carried out at the Barrax agricultural test site in Spain during 12-21 July 2004 (SPARC 2004) and 8-14 July 2005 (SEN2FLEX 2005) involving multiple field, satellite and airborne instruments for characterizing the state of the atmosphere, the vegetation and the soil from the visible to the microwave range of the spectrum. Part of the experimental area is a core site of area 25 km2, within which numerous crops are grown, on both irrigated and dry land, alongside fields of bare soil. Th…
Switch in Relative Stability between cis and trans 2-Butene on Pt(111) as a Function of Experimental Conditions: A Density Functional Theory Study
2018
International audience; The adsorption of cis and trans 2-butenes on Pt(111) has been studied as a function of hydrogen coverage OH by means of calculations based on density functional theory (DFT) with the inclusion of dispersion forces. All hydrogen coverages have been considered, from 0 to 1.00 monolayer (ML). For each case, the di-sigma and pi adsorption geometries of the olefins have been compared at a surface coverage of theta(C4H8) = 0.11 ML. Calculations of the Gibbs free energies of these systems have identified the most stable 2-butene isomer (cis or trans) as a function of coverage, temperature, and pressure. In particular, focus was placed on two sets of conditions, namely, one …
A critical size for emergence of nonbulk electronic and geometric structures in dodecanethiolate-protected Au clusters.
2014
We report on how the transition from the bulk structure to the cluster-specific structure occurs in n-dodecanethiolate-protected gold clusters, Au(n)(SC12)m. To elucidate this transition, we isolated a series of Au(n)(SC12)m in the n range from 38 to ∼520, containing five newly identified or newly isolated clusters, Au104(SC12)45, Au(∼226)(SC12)(∼76), Au(∼253)(SC12)(∼90), Au(∼356)(SC12)(∼112), and Au(∼520)(SC12)(∼130), using reverse-phase high-performance liquid chromatography. Low-temperature optical absorption spectroscopy, powder X-ray diffractometry, and density functional theory (DFT) calculations revealed that the Au cores of Au144(SC12)60 and smaller clusters have molecular-like elec…
Searches for anisotropies in the arrival directions of the highest energy cosmic rays detected by the Pierre Auger Observatory
2015
We analyze the distribution of arrival directions of ultra-high energy cosmic rays recorded at the Pierre Auger Observatory in 10 years of operation. The data set, about three times larger than that used in earlier studies, includes arrival directions with zenith angles up to $80^\circ$, thus covering from $-90^\circ$ to $+45^\circ$ in declination. After updating the fraction of events correlating with the active galactic nuclei (AGNs) in the V��ron-Cetty and V��ron catalog, we subject the arrival directions of the data with energies in excess of 40 EeV to different tests for anisotropy. We search for localized excess fluxes and for self-clustering of event directions at angular scales up t…
Acetone Vapor-Sensing Properties of Chitosan-Polyethylene Glycol Using Surface Plasmon Resonance Technique
2020
To non-invasively monitor and screen for diabetes in patients, there is need to detect low concentration of acetone vapor in the range from 1.8 ppm to 5 ppm, which is the concentration range of acetone vapor in diabetic patients. This work presents an investigation for the utilization of chitosan-polyethylene glycol (PEG)-based surface plasmon resonance (SPR) sensor in the detection of trace concentration acetone vapor in the range of breath acetone in diabetic subjects. The structure, morphology, and elemental composition of the chitosan-PEG sensing layer were characterized using FTIR, UV-VIS, FESEM, EDX, AFM, and XPS methods. Response testing was conducted using low concentration of aceto…
Geostatistical computing of acoustic maps in the presence of barriers
2009
Acoustic maps are the main diagnostic tools used by authorities for addressing the growing problem of urban acoustic contamination. Geostatistics models phenomena with spatial variation, but restricted to homogeneous prediction regions. The presence of barriers such as buildings introduces discontinuities in prediction areas. In this paper we investigate how to incorporate information of a geographical nature into the process of geostatistical prediction. In addition, we study the use of a Cost-Based distance to quantify the correlation between locations.
Coupled Surface Acoustic Wave Cavities
2020
Durante las últimas dos décadas, las ondas acústicas de superficie (SAW) que se propagan en estructuras periódicas han atraído una gran atención y han sido la base de un gran número de investigaciones.Las etiquetas SAW, por ejemplo, exploran la posibilidad de utilizar dispositivos activos o pasivos para codificar información y utilizarla en muchas aplicaciones, desde el control del tráfico hasta la seguridad o la identificación de piezas en las líneas transportadoras. Se utilizan diseños muy similares para aplicaciones de detección, especialmente de temperatura y masa. Además, se han realizado una gran cantidad de avances científicos en el estudio de los cristales fonónicos (PnC). Los PnC s…
Pull-off adhesion of hybrid glass-steel adhesive joints in salt fog environment
2016
The aim of this paper was to evaluate the durability behaviour of glass/steel adhesive joints exposed to salt fog environmental conditions for ten weeks, according to ASTM B117 standard. To this scope, pull-off mechanical tests were carried out in order to evaluate the performances evolution and damage phenomena of the adhesive joints during the ageing exposition. Two different types of adhesives were compared (i.e. epoxy and polyurethane ones). Moreover, the effects of the glass surface condition and the presence of a basalt mat layer within the adhesive thickness were evaluated. The mechanical performances were related with the occurred failure mechanisms. Epoxy-based joints showed higher…
Simulations on the mechanism of CNT bundle growth upon smooth and nanostructured Ni as well as θ-Al2O3 catalysts
2011
Abstract In the current study, we have performed ab initio DFT calculations on the gradually growing 2D periodic models of capped single-wall carbon nanotubes (SW CNTs) upon their perpendicular junctions with the Ni(111) substrate, in order to understand the peculiarities of the initial stage of their growth on either smooth or nanostructured catalytic particles. Appearance of the adsorbed carbon atoms upon the substrate follows from the dissociation of CVD hydrocarbon molecules, e.g., CH4: (CH4)ads → (CH)ads+3Hads and (CH)ads → Cads+Hads. (Since the effective growth of CNTs upon Ni nanoparticles occur inside the nanopores of amorphous alumina, we have also simulated analogous surface react…