Search results for "surface"
showing 10 items of 9345 documents
In situ measurements of background aerosol and subvisible cirrus in the tropical tropopause region
2002
[1] In situ aerosol measurements were performed in the Indian Ocean Intertropical Convergence Zone (ITCZ) region during the Airborne Polar Experiment-Third European Stratospheric Experiment on Ozone (APE-THESEO) field campaign based in Mahe, Seychelles between 24 February and 6 March 1999. These are measurements of particle size distributions with a laser optical particle counter of the Forward Scattering Spectrometer Probe (FSSP)-300 type operated on the Russian M-55 high-altitude research aircraft Geophysica in the tropical upper troposphere and lower stratosphere up to altitudes of 21 km. On 24 and 27 February 1999, ultrathin layers of cirrus clouds were penetrated by Geophysica directly…
Joint Subcarrier and Phase Shifts Optimization for RIS-aided Localization-Communication System
2022
Joint localization and communication systems have drawn significant attention due to their high resource utilization. In this paper, we consider a reconfigurable intelligent surface (RIS)-aided simultaneously localization and communication system. We first determine the sum squared position error bound (SPEB) as the localization accuracy metric for the presented localization-communication system. Then, a joint RIS discrete phase shifts design and subcarrier assignment problem is formulated to minimize the SPEB while guaranteeing each user’s achievable data rate requirement. For the presented non-convex mixed-integer problem, we propose an iterative algorithm to obtain a suboptimal solution …
Competition of electron-phonon mediated superconductivity and Stoner magnetism on a flat band
2018
The effective attractive interaction between electrons, mediated by electron-phonon coupling, is a well-established mechanism of conventional superconductivity. In metals exhibiting a Fermi surface, the critical temperature of superconductivity is exponentially smaller than the characteristic phonon energy. Therefore, such superconductors are found only at temperatures below a few kelvin. Systems with flat energy bands have been suggested to cure the problem and provide a route to room-temperature superconductivity, but previous studies are limited to only BCS models with an effective attractive interaction. Here we generalize Eliashberg's theory of strong-coupling superconductivity to syst…
Electron-phonon interaction in flat-band superconductivity
2017
Parhaiten tunnettu suprajohtavuuden syntymekanismi perustuu fononien välittämään vetovoimaan elektronien välillä. Tässä tutkielmassa tutkin fononien välittämää suprajohtavuutta systeemeissä, jossa elektronivyöt ovat tasomaisia. Tasovyöllä elektronien dispersio on erittäin heikko, jolloin tilatiheys on tavanomaista suurempi. Tämän takia suprajohtavuus tasovyöllä on tavanomaista voimakkaampi silloin kun elektronien välinen vetovoima on heikko. Eliashbergin teoria on elektroni–fononi-suprajohtavuuden teoria, joka ottaa luonnollisella tavalla fononien äärellisen nopeuden huomioon elektronien välisessä vuorovaikutuksessa. Pohjustuksena tasovyösuprajohtavuuteen perehdyn Eliashbergin teoriaan ensi…
The Role of Surface Acting in the Relationship between Job Stressors, General Health and Need for Recovery Based on the Frequency of Interactions at …
2022
The aim of the study was to verify whether the frequency of face-to-face interactions with the public at work can reveal differences in how people react to emotional regulation demands. In particular, we investigated the mediating role of surface acting (a strategy of dealing with emotional dissonance) in the relationship between two typical job stressors (workload and mental load) and two outcomes closely related to work-related well-being: employees’ general health and the need for recovery. Prior studies investigating the detrimental effects of emotional dissonance mostly focused on service workers. However, in light of a survey conducted by the European Agency for Safety and Health at W…
Antibacterial Activity of Positively and Negatively Charged Hematite (α-Fe2O3) Nanoparticles to Escherichia coli, Staphylococcus aureus and Vibrio fi…
2021
This research and work has been supported by the European Regional Development Fund within the Activity 1.1.1.2 “Post-doctoral Research Aid” of the Specific Aid Objective 1.1.1 (i.e., “to increase the research and innovative capacity of scientific institutions of Latvia and the ability to attract external financing, investing in human resources and infrastructure”) of the Operational Programme “Growth and Employment” (No. 1.1.1.2/VIAA/2/18/331).
Luminescence Properties of Non Bridging Oxygen Hole Centers at a Silica Surface
2008
[Ag67(SPhMe2)32(PPh3)8]3+: Synthesis, Total Structure, and Optical Properties of a Large Box-Shaped Silver Nanocluster
2016
Engineering the surface ligands of metal nanoparticles is critical in designing unique arrangements of metal atoms. Here, we report the synthesis and total structure determination of a large box-shaped Ag67 nanocluster (NC) protected by a mixed shell of thiolate (2,4-dimethylbenzenethiolate, SPhMe2) and phosphine (triphenylphosphine, PPh3) ligands. Single crystal X-ray diffraction (SCXRD) and electrospray ionization mass spectrometry (ESI-MS) revealed the cluster formula to be [Ag67(SPhMe2)32(PPh3)8]3+. The crystal structure shows an Ag23 metal core covered by a layer of Ag44S32P8 arranged in the shape of a box. The Ag23 core was formed through an unprecedented centered cuboctahedron, i.e.,…
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X=Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
2017
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…