Search results for "synthesis"
showing 10 items of 2844 documents
Highly convergent total synthesis of (+)-anaferine and (−)-dihydrocuscohygrine
2019
A unified and highly convergent total synthesis of anaferine and dihydrocuscohygrine alkaloids has been devised, taking advantage of the dual role of N-sulfinyl amines as nucleophilic nitrogen sources and chiral auxiliaries. A bidirectional cross metathesis reaction followed by a double intramolecular aza-Michael reaction led us to create the whole skeleton of the natural products in a very simple manner.
Dual Role of Vinyl Sulfonamides as N -Nucleophiles and Michael Acceptors in the Enantioselective Synthesis of Bicyclic δ-Sultams
2018
Identification of protein IT of the intestinal cytoskeleton as a novel type I cytokeratin with unusual properties and expression patterns.
1990
A major cytoskeletal polypeptide (Mr approximately 46,000; protein IT) of human intestinal epithelium was characterized by biochemical and immunological methods. The polypeptide, which was identified as a specific and genuine mRNA product by translation in vitro, reacted, in immunoblotting after SDS-PAGE, only with one of numerous cytokeratin (CK) antisera tested but with none of many monoclonal CK antibodies. In vitro, it formed heterotypic complexes with the type II CK 8, as shown by blot binding assays and gel electrophoresis in 4 M urea, and these complexes assembled into intermediate filaments (IFs) under appropriate conditions. A chymotrypsin-resistant Mr approximately 38,000 core fra…
High resolution 80Se(n,γ) cross section measurement at CERN n_TOF and development of the novel i-TED detection system
2022
El proceso (-s) de captura lenta de neutrones es responsable de la formación de la mitad de los elementos más pesados que el hierro en el universo. A pesar de la larga escala de tiempo de este proceso, la larga vida media de algunos isótopos inestables a lo largo del flujo de reacción del proceso-s crea puntos de ramificación que conducen a una división de la ruta de la nucleosíntesis. 79Se (t1/2 = 3.27 x 10^5 y) representa uno de los núcleos ramificados-s más relevantes y debatidos por dos razones principales. Por un lado, la existencia de estados excitados de baja energía en el 79Se, cuya población puede variar con la temperatura del medio estelar, hace que el patrón de abundancia local…
Overload breakdown in models for photosynthesis
2015
In many models of the Calvin cycle of photosynthesis it is observed that there are solutions where concentrations of key substances belonging to the cycle tend to zero at late times, a phenomenon known as overload breakdown. In this paper we prove theorems about the existence and non-existence of solutions of this type and obtain information on which concentrations tend to zero when overload breakdown occurs. As a starting point we take a model of Pettersson and Ryde-Pettersson which seems to be prone to overload breakdown and a modification of it due to Poolman which was intended to avoid this effect.
DEVELOPMENT OF ELECTROCHEMICAL MICROFLUIC DEVICES FOR THE TREATMENT OF WASTEWATERS AND THE SYNTHESIS OF CHEMICAL
ELECTROSYNTHESIS IN MICROFLUIDIC CELLS: PRELIMINARY INVESTIGATIONS
2013
Transcriptome analysis of Pseudomonas mediterranea and P. corrugata plant pathogens during accumulation of medium-chain-length PHAs by glycerol bioco…
2017
Pseudomonas corrugata and P. mediterranea are soil inhabitant bacteria, generally living as endophytes on symptomless plants and bare soil, but also capable of causing plant diseases. They share a similar genome size and a high proteome similarity. P. corrugata produces many biomolecules which play an important role in bacterial cell survival and fitness. Both species produce different medium-chain-length PHAs (mcl-PHAs) from the bioconversion of glycerol to a transparent film in P. mediterranea and a sticky elastomer in P. corrugata. In this work, using RNA-seq we investigated the transcriptional profiles of both bacteria at the early stationary growth phase with glycerol as the carbon sou…
Biosynthesis of ecdysones in isolated prothoracic glands and oenocytes of Tenebrio molitor in vitro.
1974
Abstract Isolated prothoracic glands from Tenebrio larvae synthesize in vitro α-ecdysone, but not β-ecdysone from 4-14C-cholesterol. Isolated abdominal oenocytes from the larvae synthesize mainly β-ecdysone, but only little α-ecdysone. When prothoracic glands and oenocytes are cultured together, the α-ecdysone derived from the prothoracic glands is oxidized by the oenocytes to β-ecdysone. The newly synthesized hormones are not stored in the cells, but are secreted into the medium if sufficient amounts of non-labelled hormones are present. If no unlabelled hormones are added to the culture medium, the newly formed hormones are converted to a large extent into polar conjugates.